Positive electrode material, electrochemical device containing same, and electronic device
US-11984579-B2 · May 14, 2024 · US
US12334536B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12334536-B2 |
| Application number | US-202418629202-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 8, 2024 |
| Priority date | Mar 5, 2020 |
| Publication date | Jun 17, 2025 |
| Grant date | Jun 17, 2025 |
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A positive electrode material includes secondary particles formed from primary particles. The positive electrode material satisfies the following relational expression: 15%≤(Dv50a−Dv50b)/Dv50b≤80%, where Dv50a represents Dv50 directly measured by a laser particle size analyzer for the positive electrode material without ultrasonic treatment, Dv50b represents Dv50 measured by the laser particle size analyzer for the positive electrode material after ultrasonic treatment, and Dv50 represents a particle size of the positive electrode material at a cumulative volume of 50% in a volume-based particle size distribution as measured by starting from small particle sizes. The secondary particles of the positive electrode material that meets the foregoing condition can form soft agglomerates, so that the electrochemical device is of high cycle performance and high safety performance.
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What is claimed is: 1. A positive electrode material, comprising: secondary particles, wherein the secondary particles comprise primary particles; and the positive electrode material satisfies the following relational expression: 15 % ≤ ( Dv 50 a - Dv 50 b ) / Dv 50 b ≤ 80 % ; wherein, Dv50a represents Dv50 directly measured by a laser particle size analyzer for the positive electrode material without ultrasonic treatment, Dv50b represents Dv50 measured by the laser particle size analyzer for the positive electrode material after ultrasonic treatment, and Dv50 represents a particle size of the positive electrode material at a cumulative volume of 50% in a volume-based particle size distribution as measured by starting from small particle sizes; the secondary particles further comprise a material layer, the material layer is disposed on at least a part of a surface of the secondary particles, and the material layer comprises at least one of elements B, P, Al, Zr, C, or S; wherein the positive electrode material has at least one of the following characteristics: 15 % ≤ ( Dv 10 a - Dv 10 b ) / Dv 10 b ≤ 80 % ; ( a ) 15 % ≤ ( Dv 90 a - Dv 90 b ) / Dv 90 b ≤ 80 % ; and ( b ) 10 % ≤ ( Dv 99 a - Dv 99 b ) / Dv 99 b ≤ 500 % ; ( c ) wherein, Dv10a represents Dv10 directly measured by the laser particle size analyzer for the positive electrode material without ultrasonic treatment, Dv10b represents Dv10 measured by the laser particle size analyzer for the positive electrode material after ultrasonic treatment, Dv90a represents Dv90 directly measured by the laser particle size analyzer for the positive electrode material without ultrasonic treatment, Dv90b represents Dv90 measured by the laser particle size analyzer for the positive electrode material after ultrasonic treatment, Dv99a represents Dv99 directly measured by the laser particle size analyzer for the positive electrode material without ultrasonic treatment, Dv99b represents Dv99 measured by the laser particle size analyzer for the positive electrode material after ultrasonic treatment, Dv10 represents a particle size of the positive electrode material at a cumulative volume of 10% in the volume-based particle size distribution as measured by starting f
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