Method for producing catalyst for olefin polymerization

Patent metadata

Field	Value
Publication number	US-12331138-B2
Application number	US-201615773278-A
Country	US
Kind code	B2
Filing date	Oct 28, 2016
Priority date	Nov 24, 2015
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

It is intended to provide a method for producing a catalyst for olefin polymerization which exhibits excellent catalytic activity in a polymerization treatment and permits production of a polymer excellent in stereoregularity, melt flowability, etc., even when the polymerization catalyst is prepared in an inert gas atmosphere by using a solid catalytic component comprising an electron-donating compound other than a phthalic acid ester. The method for producing a catalyst for olefin polymerization comprises performing a pre-contact treatment of bringing a solid catalytic component (A) comprising a magnesium atom, a titanium atom, a halogen atom and an electron-donating compound having no phthalic acid ester structure, a specific organoaluminum compound (B) and an external electron-donating compound (C) into contact with each other at a temperature of lower than 15° C. for a time of 30 minutes or shorter in the absence of the olefin.

First claim

The invention claimed is:

1. A method for forming a catalyst for olefin polymerization and copolymerizing olefins utilizing the catalyst, the method comprising:
(1) forming a solid catalytic component (A) by bringing components consisting of a dialkoxy magnesium compound (a), a titanium halogen compound (b), an electron-donating compound (c) having no phthalic acid ester structure, and optionally a polysiloxane, into contact with each other; and
forming the catalyst by performing a pre-contact treatment of bringing:
the formed solid catalytic component (A),
an organoaluminum compound (B) which is triethyl aluminum, and
an external electron-donating compound (C)
into contact with each other under an inert gas atmosphere at a temperature of 13° C. or lower for a time in a range from 5 seconds to 20 minutes in the absence of the olefin to produce the catalyst that is directly usable to catalyze olefin polymerization,
wherein the dialkoxy magnesium compound (a) is diethoxy magnesium,
wherein the titanium halogen compound (b) is titanium tetrachloride,
wherein the electron-donating compound (c) having no phthalic acid ester structure is at least one compound selected from the group consisting of 2-benzyloxy ethyl phenyl carbonate, 2-ethoxyethyl-1-methyl carbonate, and 2-ethoxyethyl-1-ethyl carbonate,
wherein the external electron-donating compound (C) is cyclohexylmethyldimethoxysilane; and
(2) copolymerizing the olefins in a presence of the solid catalytic component (A),
wherein the method is performed without washing the solid catalytic component (A) during and after the step (1).

2. The method according to claim 1 , wherein the treatment temperature of the pre-contact treatment is −15° C. to 10° C.

3. The method according to claim 1 , wherein in forming the solid catalyst component (A), the components consisting of the dialkoxy magnesium compound (a), the titanium halogen compound (b), the electron-donating compound (c) having no phthalic acid ester structure, and optionally the polysiloxane are allowed to react at a temperature of 40° C. to 130° C. after being brought into contact with each other.

4. The method according to claim 1 , wherein the forming of the solid catalyst component (A) consists of:
(i) suspending the magnesium compound (a) in an inert organic solvent to obtain a suspension,
(ii) bringing the titanium halogen compound (b) into contact with the suspension,
(iii) bringing the electron-donating compound (c) having no phthalic acid ester structure into contact with the suspension at a temperature of from −20° C. to 130° C., step (iii) being performed before or after step (ii) and
(iv) optionally after step (iii), bringing the polysiloxane into contact with the magnesium compound (a), the titanium halogen compound (b), and the electron-donating compound (c).

5. The method according to claim 1 , wherein the treatment time of the pre-contact treatment is 3 minutes or shorter.

Assignees

• Toho Titanium Co Ltd

Inventors

• Kono Hiroyuki
• Masuyama Takahiro
• Marui Shinta
• Uozumi Toshiya

Classifications

• C08F2410/00

  Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst · CPC title

• C08F10/00

  Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond · CPC title

• C08F4/52

  selected from boron, aluminium, gallium, indium, thallium or rare earths (C08F4/14 takes precedence) · CPC title

• C08F110/06 Primary

  Propene · CPC title

• C08F4/14 Primary

  Boron halides or aluminium halides; Complexes thereof with organic compounds containing oxygen · CPC title