Antifouling oligomerization catalyst systems

Patent metadata

Field	Value
Publication number	US-12331004-B2
Application number	US-202117383669-A
Country	US
Kind code	B2
Filing date	Jul 23, 2021
Priority date	Jan 7, 2016
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

According to one embodiment, a catalyst system that reduces polymeric fouling may comprise at least one titanate compound, at least one aluminum compound, and at least one antifouling agent or a derivative thereof. The antifouling agent may comprise a structure comprising a central aluminum molecule bound to an R1 group, bound to an R2 group, and bound to an R3 group. One or more of the chemical groups R1, R2, and R3 may be antifouling groups comprising the structure —O((CH 2 ) n O) m R4, where n is an integer from 1 to 20, m is an integer from 1 to 100, and R4 is a hydrocarbyl group. The chemical groups R1, R2, or R3 that do not comprise the antifouling group, if any, may be hydrocarbyl groups.

First claim

What is claimed is:

1. A catalyst system that reduces polymeric fouling, the catalyst system comprising:
at least one titanate compound;
at least one aluminum compound; and
at least one antifouling agent or a dimer, trimer, oligomer, polymer, isomer, or hydrolysate of the antifouling agent, where the antifouling agent comprises the structure:

where R1 and R2 are antifouling groups comprising the structure —O((CH 2 ) n O) m R4, and where R3 is a hydrocarbyl group, and where:
n is an integer from 1 to 20;
m is an integer from 1 to 100; and
R4 is a hydrocarbyl group.

2. The catalyst system of claim 1 , where n is from 1 to 5.

3. The catalyst system of claim 1 , where m is from 1 to 20.

4. The catalyst system of claim 1 , where R4 has from 1 to 100 carbon atoms.

5. The catalyst system of claim 1 , further comprising an ether compound.

6. The catalyst system of claim 5 , where the ether compound is tetrahydrofuran, a dioxane, or tetrahydropyran.

7. The catalyst system of claim 1 , where at least one of the titanate compounds is an alkyl titanate.

8. The catalyst system of claim 7 , where the alkyl titanate has the structure Ti(OR) 4 , where R is a branched or straight chain alkyl radical comprising from 2 to 8 carbon atoms.

9. The catalyst system of claim 7 , where the alkyl titanate is chosen from tetraethyl titanate, tetraisopropyl titanate, tetra-n-butyl titanate, or 2-tetraethylhexyl titanate.

10. The catalyst system of claim 1 , where at least one of the aluminum compounds has the structure AlR′ 3 or AlR′ 2 H, where R′ is a branched or straight chain alkyl radical comprising from 2 to 8 carbon atoms.

11. The catalyst system of claim 1 , where at least one of the aluminum compounds is chosen from triethylaluminum, tripropylaluminum, tri-iso-butylaluminum, trihexylaluminum, or an aluminoxane.

12. The catalyst system of claim 1 , where a molar ratio of total titanate compound to total aluminum compound is from 1:10 to 1:1.5.

13. The catalyst system of claim 1 , where a molar ratio of total titanate compound to total antifouling agent is from 1:5 to 1:0.01.

14. The catalyst system of claim 1 , where a molar ratio of total titanate compound to total ether compound is from 1:10 to 1:0.

15. A catalyst system that reduces polymeric fouling, the catalyst system comprising:
at least one titanate compound;
at least one aluminum compound;
at least one ether compound; and
at least one antifouling agent or a dimer, trimer, oligomer, polymer, isomer, or hydrolysate of the antifouling agent, where the antifouling agent comprises the structure:

where R1 and R2 are antifouling groups comprising the structure —O((CH 2 ) n O) m R4, and where R3 is a hydrocarbyl group, and where:
n is an integer from 1 to 20;
m is an integer from 1 to 100; and
R4 is a hydrocarbyl group
a molar ratio of total titanate compound to total ether compound is from 1:10 to 1:0.

16. The catalyst system of claim 15 , where at least one of the aluminum compounds has the structure AlR′ 3 or AlR′ 2 H, where R′ is a branched or straight chain alkyl radical comprising from 2 to 8 carbon atoms.

17. The catalyst system of claim 15 , where a molar ratio of total titanate compound to total aluminum compound is from 1:10 to 1:1.5.

18. The catalyst system of claim 15 , where a molar ratio of total titanate compound to total antifouling agent is from 1:5 to 1:0.01.

Assignees

• Saudi Arabian Oil Co
• Sumitomo Chemical Co

Inventors

• Khawaji Motaz
• Al Yami Hussain
• Shaikh Sohel
• Xu Wei
• Sogo Kenji

Classifications

• C07C2531/22

  Organic complexes · CPC title

• C07C2531/14

  of aluminium or boron · CPC title

• B01J2531/46

  Titanium · CPC title

• B01J2231/20

  Olefin oligomerisation or telomerisation · CPC title

• B01J31/2208

  Oxygen, e.g. acetylacetonates · CPC title