Self-regenerable fibrous adsorbent for heavy metal adsorption

Patent metadata

Field	Value
Publication number	US-12330961-B2
Application number	US-202218064736-A
Country	US
Kind code	B2
Filing date	Dec 12, 2022
Priority date	Apr 20, 2022
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

The present disclosure relates to a self-regenerable fibrous adsorbent for heavy metal adsorption, which is capable of adsorbing heavy metal ions in water, growing them into crystals and desorbing the grown heavy metal crystals on its own, and a method for preparing the same. The self-regenerable fibrous adsorbent for heavy metal adsorption according to the present disclosure is a fibrous polymer consisting of PAN and PMMA, wherein amine functional groups are immobilized on the surface of the PAN and hydroxyl groups (—OH) are immobilized on the surface of the PMMA.

First claim

What is claimed is:

1. A self-regenerable fibrous adsorbent for heavy metal adsorption, which is a fibrous polymer consisting of a first polymer material and a second polymer material, wherein
heavy metal-adsorbing functional groups are immobilized on the surface of the first polymer material and heavy metal crystal-desorbing functional groups are immobilized on the surface of the second polymer material, and
heavy metal ions in water are adsorbed by the heavy metal-adsorbing functional groups of the first polymer material and grow into crystals, and the heavy metal crystals are desorbed by the heavy metal crystal-desorbing functional groups of the second polymer material when they grow to a predetermined size or larger.

2. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 1 , wherein
the heavy metal-adsorbing functional group is an amine functional group, and
the heavy metal crystal-desorbing functional group is any of a hydroxyl group, a methyl group, a carbonyl group, a carboxyl group and a phosphate group.

3. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 1 , wherein the first polymer material is a material that can immobilize amine functional groups, and the second polymer material is a material that cannot adsorb heavy metal ions in water.

4. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 1 , wherein the first polymer material is any of polyisopropylacrylamide, polyaryleneamine, poly(glycidyl methacrylate) and polyacrylonitrile.

5. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 1 , wherein the second polymer material is any of polychloroprene, polyisoprene, polyisobutylene, polybutadiene, SBS rubber, polyamide, a natural polymer, an initial synthetic polymer, polypropylene, polyvinyl chloride, polyethylene, polystyrene, nylon, polyester and phenol resin.

6. A self-regenerable fibrous adsorbent for heavy metal adsorption, which is a fibrous polymer consisting of PAN and PMMA, wherein amine functional groups are immobilized on the surface of the PAN and hydroxyl groups (—OH) are immobilized on the surface of the PMMA.

7. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 6 , wherein heavy metal ions in water are adsorbed by the amine functional group of the PAN and grow into crystals, and the heavy metal crystals are desorbed by the hydroxyl groups (—OH) of the PMMA when they grow to a predetermined size or larger.

8. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 6 , wherein the amine functional groups are formed from substitution of the nitrile groups (—C≡N) of the PAN, and the hydroxyl groups (—OH) are formed from hydrolysis of the carbonyl groups (—C═O) of the PMMA.

9. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 6 , wherein the fibrous polymer comprises 7 wt % or less of PMMA based on the total weight of the fibrous polymer.

10. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 6 , wherein the fibrous polymer has a diameter of smaller than 1.5 mm.

11. The self-regenerable fibrous adsorbent for heavy metal adsorption according to claim 6 , wherein the amine functional group is a functional group comprising an amine group (—NH 2 ) that can adsorb heavy metal ions.

Assignees

• Korea Inst Sci & Tech

Inventors

• Choi Jae Woo
• Jung Kyung-Won
• Jung Youngkyun

Classifications

• C02F1/62

  Heavy metal compounds · CPC title

• C02F2101/20

  Heavy metals or heavy metal compounds · CPC title

• B01J20/345

  using a particular desorbing compound or mixture (elution or regeneration of stationary phases in liquid chromatography B01D15/08) · CPC title

• C02F1/288 Primary

  using composite sorbents, e.g. coated, impregnated, multi-layered · CPC title

• B01J20/3208

  Polymeric carriers, supports or substrates · CPC title