Operation method for hydrogen production device, and hydrogen production device

Patent metadata

Field	Value
Publication number	US-12330941-B2
Application number	US-202017440500-A
Country	US
Kind code	B2
Filing date	Mar 27, 2020
Priority date	Mar 27, 2019
Publication date	Jun 17, 2025
Grant date	Jun 17, 2025

Abstract

When the product gas producing operation is stopped, a stand-by operation is executed in which a product gas filling up a reforming processing unit is circulated, in a state in which an adsorbent of adsorption towers is maintained in a state in which adsorption target components are desorbed, and the heating of a reformer by a heating burner is maintained, and when the stand-by operation is stopped and the product gas producing operation is started, initial operation processing is executed in which immediately after the start, a source gas and steam are supplied to the reformer to produce a reformed gas, and the reformed gas from the reforming processing unit supplied to the adsorption towers to produce the product gas, and then the product gas producing operation in which the product gas is collected in a product gas tank is executed.

First claim

The invention claimed is:

1. An operation method for a hydrogen production device, wherein the hydrogen production device comprises:
a reforming processing unit provided with a compressor for a source gas supply for supplying the source gas that contains a hydrogen component, and a reformer for performing a steam reforming processing on the source gas in a state in which the reformer is heated to a reforming temperature by a heating burner to obtain a reformed gas that contains hydrogen components;
a pressure swing adsorption unit provided with a plurality of adsorption towers configured to perform a pressure swing adsorption operation of adsorbing, using an adsorbent, adsorption target components other than the hydrogen components from the reformed gas to produce a product gas, and discharging the adsorption target components as off-gas;
a product gas tank configured to collect the product gas; and
an off-gas supply path configured to supply the off-gas as a burning fuel to the heating burner,
the operation method comprising:
executing, with the hydrogen production device, a product gas producing operation of supplying the source gas and steam to the reformer to produce the reformed gas, and
supplying the reformed gas from the reforming processing unit to the adsorption towers to produce the product gas,
wherein a stand-by operation is executed in which the product gas filling up the reforming processing unit is circulated in the form of returning to the compressor through a return line, in a state in which a gas supply line from the reforming processing unit to the pressure swing adsorption unit is blocked, wherein the adsorbent of the adsorption towers is maintained in a state in which the adsorption target components are desorbed, and wherein the supply of the steam is stopped and the heating of the reformer by the heating burner is maintained, and
wherein, when the stand-by operation is stopped and the product gas producing operation is started, initial operation processing is executed in which immediately after the start, the source gas and steam are supplied to the reformer to produce the reformed gas, and the reformed gas from the reforming processing unit is supplied to the adsorption towers to produce the product gas, wherein if the hydrogen component concentration of the produced product gas is less than a set value, the product gas is discarded, and wherein if the hydrogen component concentration of the produced product gas is greater than or equal to the set value, the product gas producing operation in which the product gas is collected in the product gas tank is executed.

2. The operation method for the hydrogen production device according to claim 1 ,
wherein when the product gas producing operation is stopped, a purge operation is executed in which steam purge processing and product gas purge processing are sequentially performed, the steam purge processing supplies the product gas from the product gas tank to the reformer using the compressor, and supplies the reformed gas from the reforming processing unit to the plurality of adsorption towers, which perform the pressure swing adsorption operation, while maintaining a state in which the reformer is heated by the heating burner and the steam is supplied to the reformer, and the product gas purge processing supplies the product gas from the product gas tank to the reformer using the compressor, and supplies the product gas from the reforming processing unit to the adsorption towers, in a state in which the supply of the steam is stopped and the heating of the reformer by the heating burner is maintained.

3. The operation method for the hydrogen production device according to claim 2 ,
wherein the pressure swing adsorption operation is such that an operation cycle is repeatedly executed at each of the plurality of adsorption towers where operation phases of the plurality of adsorption towers are varied from each other, the operation cycle including an adsorption process of supplying the reformed gas to the corresponding adsorption tower to produce the product gas, a pressure reduction process of discharging the internal gas of the corresponding adsorption tower, a regeneration process of regenerating the adsorbent of the plurality of adsorption towers, which perform the pressure swing adsorption operation, and a pressure increasing process of supplying the product gas to the inside of the corresponding adsorption tower, and
wherein in the initial operation processing, time for performing the operation cycle with respect to the amount of source gas that is supplied by the compressor is less than time for performing the product gas producing operation.

4. The operation method for the hydrogen production device according to claim 1 ,
wherein the pressure swing adsorption operation is such that an operation cycle is repeatedly executed at each of the plurality of adsorption towers where operation phases of the plurality of adsorption towers are varied from each other, the operation cycle including an adsorption process of supplying the reformed gas to the corresponding adsorption tower to produce the product gas, a pressure reduction process of discharging the internal gas of the corresponding adsorption tower, a regeneration process of regenerating the adsorbent of the plurality of adsorption towers, which perform the pressure swing adsorption operation, and a pressure increasing process of supplying the product gas to the inside of the corresponding adsorption tower, and
wherein in the initial operation processing, time for performing the operation cycle with respect to the amount of source gas that is supplied by the compressor is less than time for performing the product gas producing operation.

Assignees

• Osaka Gas Co Ltd

Inventors

• MATSUO Hinako
• ASONUMA Hidaka
• Ikeda Koichiro

Classifications

• C01B2203/1657

  the product being hydrogen · CPC title

• C01B2203/1609

  Shutting down the process · CPC title

• C01B2203/1604

  Starting up the process · CPC title

• C01B2203/148

  involving a recycle stream to the feed of the process for making hydrogen or synthesis gas · CPC title

• C01B2203/1235

  Hydrocarbons · CPC title