Bioactive modification of poly(vinyl alcohol) with surface topography and biochemical cues for vascular graft
US-2016361462-A1 · Dec 15, 2016 · US
US12325569B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12325569-B2 |
| Application number | US-202217574792-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 13, 2022 |
| Priority date | Jul 17, 2019 |
| Publication date | Jun 10, 2025 |
| Grant date | Jun 10, 2025 |
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There is provided a water-soluble film containing polyvinyl alcohol resin, wherein a ratio RSm (LD/TD) is 1.2 or greater and 2.5 or less, where the RSm (LD/TD) is the ratio of an average length RSm (LD) of roughness curve elements on at least one film surface in the longitudinal direction to an average length RSm (TD) of roughness curve elements on the same film surface in the transverse direction. This allows provision of a water-soluble film that can be suitably used for manufacturing a package with excellent uniformity of seal strength, even for manufacturing a package with excellent uniformity of seal strength during high-speed sealing; and a package using the film.
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The invention claimed is: 1. A water-soluble film containing polyvinyl alcohol resin, wherein a ratio RSm (LD/TD) is 1.2 or greater and 2.5 or less, where the RSm (LD/TD) is the ratio of an average length RSm (LD) of roughness curve elements on at least one film surface in a longitudinal direction to an average length RSm (TD) of roughness curve elements on the same film surface in a transverse direction. 2. The water-soluble film according to claim 1 , wherein the film surface comprises a plurality of convex shapes. 3. The water-soluble film according to claim 1 , wherein the film surface comprises a plurality of convex shapes having an average aspect ratio of 2 or greater and 10 or less. 4. The water-soluble film according to claim 1 , wherein the film surface comprises a plurality of convex shapes having an average height of 0.5 μm or greater and 5 μm or less. 5. The water-soluble film according to claim 1 , wherein the film surface comprises a plurality of convex shapes having an average width of 10 μm or greater and 50 μm or less, and an average length of 30 μm or greater and 100 μm or less. 6. The water-soluble film according to claim 1 , wherein the film surface comprises a plurality of convex shapes that are provided through transfer during film formation. 7. The water-soluble film according to claim 1 , wherein the film surface comprises a plurality of convex shapes that are provided through embossing. 8. The water-soluble film according to claim 1 , wherein a front/back ratio Ra (M/G) of an arithmetic average roughness Ra of the film surface is 2 or greater and 10 or less. 9. The water-soluble film according to claim 1 , wherein the film surface having the RSm (LD/TD) of 1.2 or greater and 2.5 or less comprises a matte surface. 10. A package in which a water-soluble film is used for storing chemicals, wherein the water-soluble film contains polyvinyl alcohol resin, and a ratio RSm (LD/TD) is 1.2 or greater and 2.5 or less, where the RSm (LD/TD) is the ratio of an average length RSm (LD) of roughness curve elements on at least one film surface in a longitudinal direction to an average length RSm (TD) of roughness curve elements on the same film surface in a transverse direction. 11. The package according to claim 10 , wherein the film surface comprises a plurality of convex shapes. 12. The package according to claim 10 , wherein the film surface comprises a plurality of convex shapes having an average aspect ratio of 2 or greater and 10 or less. 13. The package according to claim 10 , wherein the film surface comprises a plurality of convex shapes having average height of 0.5 μm or greater and 5 μm or less. 14. The package according to claim 10 , wherein the film surface comprises a plurality of convex shapes having an average width of 10 μm or greater and 50 μm or less, and an average length of 30 μm or greater and 100 μm or less. 15. The package according to claim 10 , wherein the film surface comprises a plurality of convex shapes that are provided through transfer during film formation. 16. The package according to claim 10 , wherein the film surface comprises a plurality of convex shapes that are provided through embossing. 17. The package according to claim 10 , wherein the film surface having a front/back ratio Ra (M/G) of an arithmetic average roughness Ra of 2 or greater and 10 or less. 18. The package according to claim 10 , wherein the film surface having the RSm (LD/TD) of 1.2 or greater and 2.5 or less comprises a matte surface. 19. The package according to claim 18 , wherein an outer surface of the package comprises a glossy surface. 20. The package according to claim 18 , wherein the chemicals include at least one selected from the group consisting of pesticides, cleaners, and disinfectants.
Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title
Manufacture of films or sheets · CPC title
Wide strips, e.g. films, webs · CPC title
water-soluble · CPC title
Polymers of vinyl acetate, e.g. PVAc, i.e. polyvinyl acetate · CPC title
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