Method for producing densified cellulosic composite material

Patent metadata

Field	Value
Publication number	US-12320065-B2
Application number	US-201816608835-A
Country	US
Kind code	B2
Filing date	Apr 12, 2018
Priority date	Apr 26, 2017
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

The present invention provides a method for obtaining densified material comprising the steps of
a. providing lignocellulosic material,
b. delignification of the lignocellulosic material providing a delignified material, wherein the delignification step is performed in such a way that the lignin of the lignocellulosic material is almost completely removed and wherein the structural integrity of the lignocellulosic material is maintained in the delignified material,
c. densification of the delignified material providing a densified material.
Furthermore, a densified material is provided. The fibers and fibrils are maintained in the structural directionality of the raw material and that the cellulosic material is whitish.

First claim

The invention claimed is:

1. A method for obtaining densified material comprising the steps of
a. providing lignocellulosic material, wherein the lignocellulosic material is wood,
b. delignification of said lignocellulosic material providing a delignified wood material, wherein the delignification step comprises treating the lignocellulosic material with hydrogen peroxide and acetic acid, wherein the delignification step is performed in such a way that the lignin of said lignocellulosic material is almost completely removed and until the characteristic color of the lignocellulosic material is lost, and wherein the structural integrity of said lignocellulosic material is maintained in said delignified material,
c. compressing the delignified material thereby producing a densified wood material, wherein the densified material is characterized in that the density of the densified material is 400 to 1200 kg/m 3 .

2. The method according to claim 1 , wherein the delignification step comprises an incubation of the infiltrated lignocellulosic material at a temperature between 20° C. and 90° C.

3. The method according to claim 1 , wherein the densification is performed stepwise.

4. The method according to claim 1 , wherein the densification is performed with additional lateral vibration.

5. The method according to claim 1 , wherein the densification is performed in radial or tangential direction.

6. The method according to claim 1 , wherein at least two units of said delignified material are combined in a way that the fibers of said units are in parallel orientation or in various orientations to each other before the densification step is applied.

7. The method according to claim 1 , wherein the lignocellulosic material is softwood or hardwood.

8. The method according to claim 1 , wherein at least one resin, thermoset or thermoplastic, is added after step b and before step c.

9. The method according to claim 1 , wherein an additional modification step, is performed before and/or after step b.

10. The method according to claim 1 , wherein the delignification step comprises treating the lignocellulosic material with hydrogen peroxide and acetic acid provided at a volumetric ratio of 1:1.

11. The method according to claim 1 , wherein the delignification step comprises an incubation of the infiltrated lignocellulosic material at a temperature between 60° C. to 90° C.

12. The method according to claim 1 , wherein the delignification step comprises an incubation of the infiltrated lignocellulosic material at a temperature between 75° C. to 85° C.

13. The method according to claim 1 , wherein the densification is performed by applying a compression force in intervals until a predefined or the maximum degree of densification of the delignified material is obtained.

14. The method according to claim 1 , wherein the densification is performed with lateral vibration characterized by a frequency between 1 Hz and 1000 Hz.

15. The method according to claim 1 , wherein the densification is performed in radial direction.

16. The method according to claim 1 , wherein at least one of epoxide or thermoplastic suspension, is added after step b and before step c.

17. The method according to claim 1 , wherein a polymerization, mineralization, metallization or a combination thereof, is performed before and/or after step b.

Assignees

• Eth Zuerich
• Empa Eidgenoessische Mat & Forschungsanstalt

Inventors

• Schnider Thomas
• Burgert Ingo
• Segmehl Jana
• Keplinger Tobias

Classifications

• D21J3/00

  Manufacture of articles by pressing wet fibre pulp, or papier-mâché, between moulds · CPC title

• D21C3/006

  with compounds not otherwise provided for · CPC title

• B27N5/00

  Manufacture of non-flat articles · CPC title

• B27N3/02

  from particles · CPC title

• B27N1/00

  Pretreatment of moulding material · CPC title