Sizing agent composition, carbon fiber material and composite material

Patent metadata

Field	Value
Publication number	US-12320061-B2
Application number	US-202217831816-A
Country	US
Kind code	B2
Filing date	Jun 3, 2022
Priority date	Jun 3, 2021
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

The present application relates to a sizing agent composition, a carbon fiber material and a composite material. The sizing agent composition includes a first composition solution and a second composition solution, and those solutions respectively has specific compound. The sizing agent comprising the composition has an excellent bonding property with a carbon fiber, and further the sizing agent can efficiently enhance heat resistance, wear resistance and processability of the carbon fiber material. The carbon fiber material sized with the sizing agent has a high adhesion property with specific resin material, therefore producing the composite material with high processability.

First claim

What is claimed is:

1. A sizing agent composition, comprising:
a first composition solution, including a polyamic acid, wherein the polyamic acid is formed by subjecting a dianhydride compound and a diamine compound to a reaction, and a viscosity of the first composition solution is 10 cp to 5000 cp; and
a second composition solution, including a polyphenylene ether compound, wherein a molecular weight of the polyphenylene ether compound is 1,000 to 40,000, and a weight ratio of the polyamic acid and the polyphenylene ether compound is 0.1 to 10.

2. The sizing agent composition of claim 1 , wherein the polyphenylene ether compound is an aqueous compound.

3. The sizing agent composition of claim 1 , wherein the first composition solution and the second composition solution are both aqueous solutions.

4. The sizing agent composition of claim 3 , wherein the polyamic acid and the polyphenylene ether compound are respectively dispersed in the first composition solution and the second composition solution.

5. The sizing agent composition of claim 1 , further comprising:
a polyepoxide compound, wherein based on a total amount of the polyamic acid and the polyphenylene ether compound as 100 parts by weight, an amount of the polyepoxide compound is 1 part by weight to 10 parts by weight.

6. The sizing agent composition of claim 5 , wherein the polyepoxide compound is polymerized from ethylene oxide and/or propylene oxide.

7. The sizing agent composition of claim 1 , wherein the sizing agent composition excludes epoxy resin compounds.

8. A carbon fiber material, comprising:
a carbon fiber; and
a sizing agent, covering the carbon fiber, wherein the sizing agent comprises a sizing agent composition of claim 1 .

9. The carbon fiber material of claim 8 , wherein the sizing agent composition further comprises a polyepoxide compound, and based on a total amount of a polyamic acid and a polyphenylene ether compound in the sizing agent composition as 100 parts by weight, an amount of the polyepoxide compound is 1 part by weight to 10 parts by weight.

10. The carbon fiber material of claim 8 , wherein when the carbon fiber material is heated to an imidization temperature, a polyamic acid in the sizing agent composition is reacted to form a polyimide.

11. The carbon fiber material of claim 10 , wherein the imidization temperature is not lower than 340° C.

12. The carbon fiber material of claim 8 , wherein the sizing agent is an aqueous product.

13. The carbon fiber material of claim 8 , wherein a concentration of the sizing agent is 0.2 wt % to 5 wt %.

14. The carbon fiber material of claim 8 , wherein a sizing ratio of the carbon fiber material is 0.5% to 4%.

15. The carbon fiber material of claim 8 , wherein a heat loss ratio of the carbon fiber material at 400° C. is not larger than 1.2%.

16. A composite material, comprising:
a resin matrix, including polyether ether ketone (PEEK), polyether ketone ketone (PEKK) and/or polyaryl ether ketone (PAEK); and
a carbon fiber material of claim 8 , dispersed in the resin matrix.

17. The composite material of claim 16 , wherein an interfacial shear strength of the carbon fiber material to the resin matrix is not less than 20 MPa.

Assignees

• Formosa Plastics Corp

Inventors

• Lin Sheng-Shiun
• Li Yu-Sheng
• Chung Ching-Cheng
• Chou Cheng-Chun
• Hwang Long-Tyan

Classifications

• D06M2200/40

  Reduced friction resistance, lubricant properties; Sizing compositions · CPC title

• D06M2101/40

  Fibres of carbon · CPC title

• D06M23/14

  Processes for the fixation or treatment of textile materials in three-dimensional [3D] forms · CPC title

• D06M15/71

  Cooling; Steaming or heating, e.g. in fluidised beds; with molten metals · CPC title

• D06M15/55

  Epoxy resins · CPC title