Aqueous adhesive for rubber and aqueous adhesive for ball

Patent metadata

Field	Value
Publication number	US-12319845-B2
Application number	US-202017625389-A
Country	US
Kind code	B2
Filing date	Jul 27, 2020
Priority date	Aug 2, 2019
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

An aqueous adhesive for rubber includes rubber latex and an ammonium-salt-based vulcanization acceleration aid. An amount of the ammonium-salt-based vulcanization acceleration aid contained in the aqueous adhesive is preferably not less than 0.01% by weight and not greater than 5.0% by weight in terms of solid content. An aqueous adhesive for a ball includes rubber latex as a main component. A content of an inorganic filler in the aqueous adhesive is not greater than 0.1% by weight in terms of solid content. A ball 2 includes a hollow core 4 obtained by crosslinking a rubber composition that contains a vulcanizing agent. The core 4 is formed of two hemispherical half cores. The two half cores are adhered to each other by using the aqueous adhesive for a ball.

First claim

The invention claimed is:

1. An aqueous adhesive for a ball, the aqueous adhesive comprising rubber latex as a main component, wherein
a content of an inorganic filler is less than 0.1% by weight in terms of solid content,
a pH of the aqueous adhesive is not lower than 7.0 and not higher than 12.0, and
the aqueous adhesive further comprises ammonia.

2. The aqueous adhesive according to claim 1 , wherein the rubber latex is natural rubber latex and/or synthetic rubber latex.

3. The aqueous adhesive according to claim 1 , which has at least one of the following features (i) and (ii):
(i) a sulfur content is not less than 0.5% by weight and not greater than 18.0% by weight in terms of solid content;
(ii) a viscosity measured at 23±1° C. by using a Brookfield rotational viscometer is not less than 20 cps and not greater than 20,000 cps.

4. The aqueous adhesive according to claim 1 , further comprising a sulfenamide-based vulcanization accelerator, wherein
the sulfenamide-based vulcanization accelerator is a compound represented by general formula R 1 —S—N(—R 2 )—R 3 , where R 1 , R 2 , and R 3 each independently represent a hydrogen atom, linear, branched or cyclic C3 to C20 alkyl group, alkyl ether group, alkylphenyl group, nitrogen-containing heterocyclic group, sulfur-containing heterocyclic group, or nitrogen-and-sulfur-containing heterocyclic group.

5. The aqueous adhesive according to claim 4 , wherein an amount of the sulfenamide-based vulcanization accelerator is not less than 0.01% by weight and not greater than 5.0% by weight in terms of solid content.

6. The aqueous adhesive according to claim 1 , wherein the inorganic filler is one or more selected from the group consisting of silica, carbon black, calcium carbonate, calcium hydroxide, mica, magnesium hydroxide, diatomaceous earth, titanium oxide, zinc oxide, bismuth oxide, barium sulfate, talc, magnesium carbonate, and alumina.

7. A production method for producing the aqueous adhesive according to claim 1 , the production method comprising:
adding a dispersant to water and preparing a dispersion medium;
putting and mixing an additive to be blended with rubber latex, in the dispersion medium, and thereafter adjusting a pH through addition of ammonia water such that the pH is not lower than 8.0 and not higher than 12.0, to obtain a slurry of the additive, and
adding the slurry of the additive obtained in the slurry obtaining step to the rubber latex, and mixing the slurry and the rubber latex.

8. A ball comprising a hollow core obtained by crosslinking a rubber composition that contains a vulcanizing agent, wherein
the core is formed of two hemispherical half cores, and
the two half cores are adhered to each other by using the aqueous adhesive according to claim 1 .

9. The aqueous adhesive according to claim 1 , wherein a viscosity measured at 23±1° C. by using a Brookfield rotational viscometer is not less than 20 cps and not greater than 120 cps.

10. An aqueous adhesive for a ball, the aqueous adhesive comprising rubber latex as a main component, wherein
a content of an inorganic filler is not greater than 0.1% by weight in terms of solid content,
a pH of the aqueous adhesive is not lower than 7.0 and not higher than 12.0,
the aqueous adhesive further comprises ammonia, and
a viscosity measured at 23±1° C. by using a Brookfield rotational viscometer is not less than 20 cps and not greater than 120 cps.

Assignees

• Sumitomo Rubber Ind

Inventors

• Hyodo Takehiko
• Taguchi Masanori
• Tanaka Hiroaki
• Suzuki Fumiya
• Niwa Kunio
• Shiga Kazuyoshi
• Sakurai Yuko
• Mimura Kohei

Classifications

• C09J2407/00

  Presence of natural rubber · CPC title

• C08K2003/2296

  of zinc · CPC title

• C08K2003/2237

  of titanium · CPC title

• C08K5/44

  Sulfenamides · CPC title

• C08K5/19

  Quaternary ammonium compounds · CPC title