Water-soluble film and packaging

Patent metadata

Field	Value
Publication number	US-12319798-B2
Application number	US-202117505981-A
Country	US
Kind code	B2
Filing date	Oct 20, 2021
Priority date	Apr 23, 2019
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

There is provided a water-soluble film containing polyvinyl alcohol resin, wherein the ratio of fluorine element to the total amount of elements (F1S) found at the time of analyzing a first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 25 mol % or less; and ratio of the fluorine element to the total amount of elements (F1B) found at the time of analyzing a surface 0.1 μm deep from the first surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less. As a result, a water-soluble film having excellent detachability from the support, as well as excellent transparency and sealing property, and a packaging body for chemicals may be provided using this film.

First claim

The invention claimed is:

1. A water-soluble film comprising:
polyvinyl alcohol resin,
wherein the ratio of fluorine element to the total amount of elements (F1S) found at the time of analyzing a first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 23 mol % or less,
the ratio of the fluorine element to the total amount of elements (F1B) found at the time of analyzing a surface 0.1 μm deep from the first surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less,
the ratio of fluorine element to the total amount of elements (F2S) found at the time of analyzing a second surface opposite the first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 23 mol % or less, and
a difference between the F1S and the F2S does not exceed 22 mol %.

2. The water-soluble film according to claim 1 , wherein
the ratio of fluorine element to the total amount of elements (F2B) found at the time of analyzing a surface 0.1 μm deep from the second surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less.

3. The water-soluble film according to claim 2 , wherein the difference between the F1S and the F2S is 2.5 mol % or greater and does not exceed 22 mol %.

4. The water-soluble film according to claim 1 , wherein the fluorine element is contained in a fluorine-containing surfactant having a molecular weight of 10,000 or less.

5. The water-soluble film according to claim 4 , wherein the fluorine-containing surfactant is at least one type selected from a group consisting of fluoroalkyl alcohol, fluoroalkyl carboxylate, fluoroalkyl sulfate ester, fluoroalkyl sulfonate, fluoroalkyl phosphoric ester salt, fluoroalkyl phosphonate, fluoroalkyl phosphonous salt, and fluoroalkyl ammonium salt.

6. The water-soluble film according to claim 5 , wherein the fluorine-containing surfactant is at least one type selected from a group consisting of fluoroalkyl alcohol, fluoroalkyl phosphoric ester salt, and fluoroalkyl sulfonate.

7. The water-soluble film according to claim 4 , comprising a layer containing the polyvinyl alcohol resin without the fluorine-containing surfactant.

8. The water-soluble film according to claim 4 , comprising a layer containing the fluorine-containing surfactant without the polyvinyl alcohol resin.

9. A packaging body comprising:
a water-soluble film including polyvinyl alcohol resin,
wherein the packaging body is configured to store a chemical,
the ratio of fluorine element to the total amount of elements (F1S) found at the time of analyzing a first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 23 mol % or less,
the ratio of the fluorine element to the total amount of elements (F1B) found at the time of analyzing a surface 0.1 μm deep from the first surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less,
the ratio of fluorine element to the total amount of elements (F2S) found at the time of analyzing a second surface opposite the first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 23 mol % or less, and
a difference between the F1S and the F2S does not exceed 22 mol %.

10. The packaging body according to claim 9 , wherein the chemical is a pesticide, a detergent, or a disinfectant.

11. The packaging body according to claim 9 , wherein the chemical is in a liquid state.

12. The packaging body according to claim 9 , wherein the ratio of fluorine element to the total amount of elements (F2B) found at the time of analyzing a surface 0.1 μm deep from the second surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less.

13. The packaging body according to claim 12 , wherein a difference between the F1S and the F2S is 2.5 mol % or greater and does not exceed 22 mol %.

14. The packaging body according to claim 9 , wherein the fluorine element is contained in a fluorine-containing surfactant having a molecular weight of 10,000 or less.

15. The packaging body according to claim 14 , wherein the fluorine-containing surfactant is at least one type selected from a group consisting of fluoroalkyl alcohol, fluoroalkyl carboxylate, fluoroalkyl sulfate ester, fluoroalkyl sulfonate, fluoroalkyl phosphoric ester salt, fluoroalkyl phosphonate, fluoroalkyl phosphonous salt, and fluoroalkyl ammonium salt.

16. The packaging body according to claim 15 , wherein the fluorine-containing surfactant is at least one type selected from a group consisting of fluoroalkyl alcohol, fluoroalkyl phosphoric ester salt, and fluoroalkyl sulfonate.

17. A water-soluble film comprising:
polyvinyl alcohol resin,
wherein the ratio of fluorine element to the total amount of elements (F1S) found at the time of analyzing a first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 25 mol % or less,
wherein the ratio of the fluorine element to the total amount of elements (F1B) found at the time of analyzing a surface 0.1 μm deep from the first surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less,
wherein the ratio of fluorine element to the total amount of elements (F2S) found at the time of analyzing a second surface opposite the first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 25 mol % or less,
wherein the ratio of fluorine element to the total amount of elements (F2B) found at the time of analyzing a surface 0.1 μm deep from the second surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less, and
wherein a difference between the F1S and the F2S is 2.5 mol % or greater.

18. A packaging body comprising:
a water-soluble film including polyvinyl alcohol resin,
wherein the packaging body is configured to store a chemical,
wherein the ratio of fluorine element to the total amount of elements (F1S) found at the time of analyzing a first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 25 mol % or less,
wherein the ratio of the fluorine element to the total amount of elements (F1B) found at the time of analyzing a surface 0.1 μm deep from the first surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less,
wherein the ratio of fluorine element to the total amount of elements (F2S) found at the time of analyzing a second surface opposite the first surface of the water-soluble film through X-ray Photoelectron Spectroscopy is 1 mol % or greater and 25 mol % or less; and the ratio of fluorine element to the total amount of elements (F2B) found at the time of analyzing a surface 0.1 μm deep from the second surface through X-ray Photoelectron Spectroscopy is 0.5 mol % or less, and
wherein a difference between the F1S and the F2S is 2.5 mol % or greater.

19. A method of forming the water-soluble film of claim 1 , comprising the step of coating a support with a fluorine-containing surfactant, and flow-casting a film forming solution containing the polyvinyl alcohol resin in film form on the resulting coated support, wherein the fluorine element is contained in the fluorine-containing surfactant having a molecular weight of 10,000 or less.

20. The method according to claim 19 , wherein the support is coated with the fluorine-containing surfactant by continuously coating the support with a solution of the fluorine-containing surfactant or an aqueous dispersion of the fluorine-containing surfactant, and drying the re

Assignees

• Kuraray Co

Inventors

• Okamoto Minoru
• Shimizu Sayaka
• Kazeto Osamu

Classifications

• C11D17/043

  Liquid or thixotropic (gel) compositions · CPC title

• C08K5/521

  Esters of phosphoric acids, e.g. of H3PO4 · CPC title

• C08K5/42

  Sulfonic acids; Derivatives thereof · CPC title

• C08K5/05

  Alcohols; Metal alcoholates · CPC title

• C08J2329/04

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title