Bis(fluorosulfonyl)imide compound and method for producing same

Patent metadata

Field	Value
Publication number	US-12319571-B2
Application number	US-202017613460-A
Country	US
Kind code	B2
Filing date	May 1, 2020
Priority date	May 23, 2019
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

Provided is a compound represented by Formula (1) below.

M a X b Y c   (1)

(In Formula (1), M represents metal other than alkali metal, X represents —N(SO 2 F) 2 , Y represents a coordinating solvent, and a, b, and c are positive numbers.)

First claim

The invention claimed is:

1. A compound comprising a structure represented by Formula (1) below:
M a X b Y c   (1),

where M represents metal other than alkali metal, X represents —N(SO 2 F) 2 , Y represents a coordinating solvent, and a, b, and c are positive numbers; and
the coordinating solvent Y includes at least one type selected from a carbonate-based solvent, an ether-based solvent, an ester-based solvent, and a sulfone-based solvent.

2. The compound of claim 1 , wherein
the metal M includes at least one metal type selected from group 2, 10 to 13 metals in a periodic table.

3. The compound of claim 1 , wherein
the metal M includes group 2 metal in the periodic table.

4. The compound of claim 1 , wherein
the coordinating solvent Y includes at least one type selected from linear carbonate, cyclic carbonate, linear aliphatic ether, cyclic ether, linear ester, cyclic ester, and cyclic sulfone.

5. The compound of claim 1 , wherein
a water content is 5000 mass ppm or less.

6. The compound of claim 1 , wherein
a ratio among a, b, and c is a/b/c=1/2 to 3/1 to 8.

7. The compound of claim 1 , wherein
the metal M is magnesium,
the coordinating solvent Y includes at least one type selected from dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, ethylene carbonate, propylene carbonate, butylene carbonate, 1,2-dimethoxyethane, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, tetrahydrofuran, 2-methyltetrahydrofuran, 1,4-dioxane, 1,3-dioxolane, methyl acetate, ethyl acetate, ethyl propionate, propyl propionate, γ-butyrolactone, valerolactone, and sulfolane,
a water content is 5000 mass ppm or less, and
a ratio among a, b, and c is a/b/c=1/2 to 3/1 to 8.

8. A method for producing the compound of claim 1 , comprising:
a reaction step of causing salt of the metal M causing no water in reaction and bis(fluorosulfonyl)imide to react with each other under a presence of a coordinating solvent.

9. The production method of claim 8 , further comprising:
a ligand substitution step of obtaining, by means of a coordinating solvent Y1, a compound that the coordinating solvent Y is Y1 in Formula (1) at the reaction step and subsequently substituting at least part of the coordinating solvent Y1 with a coordinating solvent Y2.

10. The production method of claim 9 , wherein
the coordinating solvent Y1 is a nitrile-based solvent, and the coordinating solvent Y2 is at least one type selected from a carbonate-based solvent, an ether-based solvent, an ester-based solvent, and a sulfone-based solvent.

11. The production method of claim 8 , wherein
the salt of the metal M is at least one type selected from halide, sulfate, nitrate, phosphate, chlorate, chromate, formate, acetate, and trifluoromethanesulfonate.

12. The production method of claim 8 , wherein 0.3 to 1.5 equivalent of the salt of the metal M is used for the bis(fluorosulfonyl)imide.

13. The production method of claim 8 , wherein
at the reaction step, the reaction is made with a moisture amount of 5000 mass ppm or less in a reaction system.

14. The production method of claim 8 , further comprising:
a step of recrystallizing the generated compound represented by Formula (1).

15. A compound comprising a structure represented by Formula (1) below:
M a X b Y c   (1),

where M represents metal other than alkali metal, X represents —N(SO 2 F) 2 , Y represents a coordinating solvent, and a, b, and c are positive numbers;
a water content is 5000 mass ppm or less; and
the metal M includes at least one metal type selected from group 2 to 11, 13 to 15 metals in a periodic table,
wherein a ratio among a, b, and c is a/b/c=1/2 to 3/1 to 8.

16. The compound of claim 15 , wherein
the metal M includes group 2 metal in the periodic table.

17. The compound of claim 15 , wherein
the coordinating solvent Y includes at least one type selected from a nitrile-based solvent, a carbonate-based solvent, an ether-based solvent, an ester-based solvent, and a sulfone-based solvent.

18. The compound of claim 15 , wherein
the coordinating solvent Y includes at least one type selected from aliphatic nitrile, linear carbonate, cyclic carbonate, linear aliphatic ether, cyclic ether, linear ester, cyclic ester, and cyclic sulfone.

19. The compound of claim 15 , wherein
the metal M is magnesium,
the coordinating solvent Y includes at least one type selected from acetonitrile, dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate, ethylene carbonate, propylene carbonate, butylene carbonate, 1,2-dimethoxyethane, diethylene glycol dimethyl ether, triethylene glycol dimethyl ether, tetrahydrofuran, 2-methyltetrahydrofuran, 1,4-dioxane, 1,3-dioxolane, methyl acetate, ethyl acetate, ethyl propionate, propyl propionate, γ-butyrolactone, valerolactone, and sulfolane.

Assignees

• Nippon Catalytic Chem Ind

Inventors

• ONODA Chie
• Kobatake Takayuki
• Katsuyama Hiromoto

Classifications

• C07F3/02

  Magnesium compounds · CPC title

• C07C255/03

  Mononitriles · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/0567

  characterised by the additives · CPC title