Metal oxide-based SCR catalyst composition

Patent metadata

Field	Value
Publication number	US-12318762-B2
Application number	US-202117997750-A
Country	US
Kind code	B2
Filing date	May 14, 2021
Priority date	May 14, 2020
Publication date	Jun 3, 2025
Grant date	Jun 3, 2025

Abstract

The present disclosure provides SCR catalyst compositions capable of reducing nitrogen oxide (NO x ) emissions in engine exhaust. The catalyst compositions include a reducible metal oxide support containing ceria, one or more transition metal oxides as a redox promotor; and an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof as an acidic promotor. The redox promotor and the acid promotor are both supported on the reducible metal oxide support. Further provided are SCR catalyst articles coated with such compositions, processes for preparing such catalyst compositions and articles, an exhaust gas treatment system including such catalyst articles, and methods for reducing NO x in an exhaust gas stream using such catalyst articles and systems.

First claim

What is claimed is:

1. A selective catalytic reduction (SCR) catalyst composition for the abatement of nitrogen oxides (NO x ), the catalyst composition comprising:
a reducible metal oxide support comprising ceria;
a redox promotor comprising one or more transition metal oxides; and
an acidic acid promotor comprising an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof, wherein the redox promotor and the acid promotor are supported on the reducible metal oxide support, and the acid promotor is niobium (V) oxide (Nb 2 O 5 ), present in an amount of about 6% to about 10% by weight on an oxide basis, based on the total weight of the catalyst composition.

2. The catalyst composition of claim 1 , wherein the reducible metal oxide support comprises ceria in an amount ranging from about 20% to about 100% by weight of the reducible metal oxide support on an oxide basis.

3. The catalyst composition of claim 1 , wherein the reducible metal oxide support further comprises zirconia, alumina, silica, titania, baria, niobia, tin oxide, yttrium oxide, an oxide of a rare earth metal, or a combination thereof.

4. The catalyst composition of claim 1 , wherein both the redox promotor and the acid promotor are impregnated onto the reducible metal oxide support.

5. The catalyst composition of claim 1 , wherein at least a portion of the redox promotor and at least a portion of the acid promotor are supported on the reducible metal oxide support in the form of a mixed metal oxide.

6. The catalyst composition of claim 1 , wherein the redox promotor is impregnated onto the reducible metal oxide, and at least a portion of the acid promotor is disposed on the redox promotor.

7. The catalyst composition of claim 1 , wherein the acidic acid promotor is present in an amount ranging from about 2% to about 20% by weight, based on the total weight of the catalyst composition.

8. The catalyst composition of claim 1 , wherein the redox promotor is present in an amount ranging from about 0.2% to about 10% by weight, based on the total weight of the catalyst composition.

9. The catalyst composition of claim 1 , wherein:
the reducible metal oxide support comprises at least about 20% ceria by weight of the reducible metal oxide support;
the redox promotor comprises an oxide of copper, an oxide of manganese, or both, wherein each oxide present is in an amount ranging from about 0.5% to about 10% by weight on an oxide basis, based on the total weight of the catalyst composition, and optionally, an oxide of iron in an amount ranging from about 0.1% to about 10% by weight on an oxide basis, based on the total weight of the catalyst composition.

10. The catalyst composition of claim 9 , wherein the oxide of iron is Fe 2 O 3 is present in an amount ranging from about 2% to about 8% by weight on an oxide basis, based on the total weight of the catalyst composition.

11. The catalyst composition of claim 1 , further comprising a non-reducible refractory metal oxide support selected from alumina, zirconia, titania, silica, and combinations thereof.

12. The catalyst composition of claim 1 , wherein an ammonia storage capacity of the catalyst composition, as measured by temperature programmed desorption (TPD) with NH 3 adsorption temperature at 40° C., is less than about 200 μmoles per gram of catalyst composition.

13. The catalyst composition of claim 1 , wherein after aging at 650° C. for 50 hours in air in the presence of 10% water vapor, the conversion of nitrogen oxides (NO x ) in a gas stream at 200° C. is greater than about 70% when the catalyst composition is tested under the following conditions: at an exhaust gas hourly volume-based space velocity of 250,000 h −1 , the exhaust gas comprising a gas mixture of 500 ppm NO, 500 ppm NH 3 , 10% O 2 , 5% CO 2 , 5% H 2 O and the balance N 2 .

14. A selective catalytic reduction (SCR) catalyst article to abate nitrogen oxides (NO x ), the SCR catalyst article comprising a substrate having a SCR catalyst composition disposed on at least a portion thereof,
wherein the SCR catalyst composition comprises:
a reducible metal oxide support comprising ceria;
a redox promotor comprising one or more transition metal oxides; and
an acidic acid promotor comprising an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof, wherein the redox promotor and acid promotor are supported on the reducible metal oxide support, and the acid promotor is niobium (V) oxide (Nb 2 O 5 ), present in an amount of about 6% to about 10% by weight on an oxide basis, based on the total weight of the catalyst composition.

15. The SCR catalyst article of claim 14 , wherein the substrate is a honeycomb substrate.

16. An exhaust gas treatment system comprising the SCR catalyst article according to claim 14 , positioned downstream from and in fluid communication with an internal combustion engine that produces an exhaust gas stream.

17. The exhaust gas treatment system of claim 16 , wherein the SCR catalyst article is in a close coupled position, the exhaust gas treatment system further comprising a conventional SCR catalyst article positioned downstream from and in fluid communication with the SCR catalyst article, the conventional SCR catalyst article comprising a copper- or iron-promoted zeolite.

18. The exhaust gas treatment system of claim 17 , comprising a first urea injector disposed upstream from and in fluid communication with the SCR catalyst article, and a second urea injector disposed downstream from the SCR catalyst article, and upstream from and in fluid communication with the conventional SCR catalyst article.

19. A method of treating an exhaust gas stream, the method comprising contacting the exhaust gas stream from an internal combustion engine with the catalyst article of claim 14 , for a time and at a temperature sufficient to reduce the level of nitrogen oxides (NO x ) in the exhaust gas stream.

20. A method for preparing a selective catalytic reduction (SCR) catalyst composition comprising a reducible metal oxide support comprising ceria, a redox promotor comprising one or more transition metal oxides, and an acidic acid promotor comprising an oxide of niobium, tungsten, silicon, or a combination thereof, wherein the redox promotor and the acid promotor are supported on the reducible metal oxide support, and the acid promotor is niobium (V) oxide (Nb 2 O 5 ), present in an amount of about 6% to about 10% by weight on an oxide basis, based on the total weight of the catalyst composition, the method comprising:
contacting the reducible metal oxide support with a redox promotor precursor and an acidic acid promotor precursor; and
calcining the reducible metal oxide support.

21. The method of claim 20 , wherein contacting comprises sequentially impregnating the reducible metal oxide support first with the redox promotor precursor, followed by a second impregnation with the acidic acid promotor precursor.

22. The method of claim 20 , wherein contacting comprises sequentially impregnating the reducible metal oxide support first with the acidic acid promotor precursor, followed by a second impregnation with the redox promotor precursor.

23. The method of claim 20 , wherein contacting comprises co-impregnating the reducible metal oxide support with the redox promotor precursor and the acidic acid promotor precursor.

24. The method of claim 21 , wherein calcining comprises calcining the reducible metal oxide support af

Assignees

• Basf Corp
• Univ Central Florida Res Found Inc
• Basf Mobile Emissions Catalysts Llc
• Univ Of Central Flordia Research Foundation Inc

Inventors

• Liu Fudong
• Li Yuejin
• Xie Shaohua

Classifications

• B01J35/57

  Honeycombs · CPC title

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• F01N2610/1453

  Sprayers or atomisers; Arrangement thereof in the exhaust apparatus · CPC title

• F01N2610/02

  the substance being ammonia or urea · CPC title

• F01N2370/04

  Zeolitic material · CPC title