Method for starting up an argon separation column of an apparatus for air separation by cryogenic distillation and unit for implementing the method

Patent metadata

Field	Value
Publication number	US-12313336-B2
Application number	US-202117211756-A
Country	US
Kind code	B2
Filing date	Mar 24, 2021
Priority date	Apr 2, 2020
Publication date	May 27, 2025
Grant date	May 27, 2025

Abstract

A unit for producing argon by cryogenic distillation, suitable for connection to a double air separation column consisting of first and second columns interconnected thermally, comprises an argon separation column surmounted with a top condenser and a denitrogenation column, means for withdrawing an argon-rich and nitrogen-depleted product (LAR) at the bottom of the denitrogenation column, means for connecting the top of the argon separation column to the denitrogenation column, means for sending a top gas from the argon separation column to the atmosphere, means for withdrawing a nitrogen-rich fluid from the top of the denitrogenation column, an analyser for measuring the nitrogen content at the top of the argon separation column, and means for opening and closing the means for connecting the top of the argon separation column to the denitrogenation column depending on the nitrogen content detected by the analyser.

First claim

What is claimed is:

1. A method for starting up a column for separating argon by cryogenic distillation, the method comprising the steps of:
sending an argon-enriched fluid coming directly or indirectly from a double air separation column to an argon separation column, wherein the double air separation column comprises a first column and a second column, which are interconnected thermally;
measuring a nitrogen content at a top of the argon separation column,
wherein during start-up of the column:
a. sending a top gas from the argon separation column to the atmosphere, upon a determination that the nitrogen content at the top of the argon separation column is above a first threshold, and
b. sending the top gas from the argon separation column to a denitrogenation column for separation therein upon a determination that the nitrogen content at the top of the argon separation column is below a second threshold, which is lower than or equal to the first threshold; and withdrawing an argon-rich fluid product from the denitrogenation column.

2. The method according to claim 1 , wherein during start-up, upon a determination that the nitrogen content at the top of the argon separation column is above the first threshold, the method further comprises the step of sending no gas for separation to the denitrogenation column.

3. The method according to claim 1 , wherein during start-up, upon a determination that the nitrogen content at the top of the argon separation column is below the second threshold, the method further comprises the step of sending no gas from the top of the argon separation column to the atmosphere.

4. The method according to claim 1 , wherein the nitrogen content at the top of the argon separation column is measured by means of an analyzer configured to analyze the concentration of nitrogen in a range from 10 ppm to 100% N 2 in a mixture of oxygen, nitrogen and argon.

5. The method according to claim 1 , wherein the second threshold is lower than the first threshold.

6. The method according to claim 1 , wherein the second threshold is equal to the first threshold.

7. A method for regulating a separation apparatus comprising a method for starting up the apparatus according to claim 1 , wherein during start-up, the method comprises measuring the nitrogen content at the top of the argon separation column with an analyzer, and operating phases other than at the start-up, measuring the nitrogen content of a gas feeding the argon separation column with the analyzer.

Assignees

• Air Liquide

Inventors

• Trueba Antonio
• Bednarski David
• Saulnier Bernard

Classifications

• F25J2290/60

  Details about pipelines, i.e. network, for feed or product distribution · CPC title

• F25J2290/00

  Other details not covered by groups F25J2200/00 - F25J2280/00 · CPC title

• F25J2280/10

  Control for or during start-up and cooling down of the installation · CPC title

• F25J2250/20

  Boiler-condenser with multiple exchanger cores in parallel or with multiple re-boiling or condensing streams · CPC title

• F25J2215/04

  Recovery of liquid products · CPC title