PVC composition, polymer composite article formed therewith, and method of preparing same

Patent metadata

Field	Value
Publication number	US-12312462-B2
Application number	US-202017630312-A
Country	US
Kind code	B2
Filing date	Aug 6, 2020
Priority date	Aug 7, 2019
Publication date	May 27, 2025
Grant date	May 27, 2025

Abstract

A polyvinyl chloride (PVC) composition and a method for preparing a polymer composite article. The composition comprises (A) a mineral filler in an amount of from 7.5 to 75 wt. %. The composition also comprises (B) a polyvinyl chloride polymer in an amount of from 20 to 92 wt. %. Further, the composition comprises (C) a polydiorganosiloxane in an amount of from greater than 0 to 5 wt. %; the (C) polydiorganosiloxane being a compound of unit formula: (R 2 R′SiO 1/2 ) a (R 3 SiO 1/2 ) b (R 2 SiO 2/2 ) c (RR′SiO 2/2 ) d , where each R is an independently selected monovalent hydrocarbon group of 1 to 18 carbon atoms that is free of aliphatic unsaturation, each R′ is an independently selected alkenyl group of 2 to 18 carbon atoms, subscript a is 0 to 2, subscript b is 0 to 2, a quantity (a+b)=2, subscript c≥0, subscript d≥0, a quantity (a+d)≥1, and a quantity (a+b+c+d) is sufficient to give the polydiorganosiloxane a viscosity of 2,000 mPa·s to 60,000 mPa·s at 25° C. measured at 0.1 to 50 RPM on a Brookfield DV-III cone & plate viscometer with #CP-52 spindle. The ranges for components (A)-(C) are based on the total weight of components (A), (B) and (C) in the composition.

First claim

What is claimed is:

1. A polyvinyl chloride (PVC) composition for preparing a polymer composite article, said composition comprising:
(A) a mineral filler in an amount of from 7.5 to 75 wt. %;
(B) a polyvinyl chloride polymer in an amount of from 20 to 92 wt. %, wherein said (B) PVC polymer comprises a polyvinyl; and
(C) a polydiorganosiloxane in an amount of from greater than 0 to 5 wt. %, wherein the (C) polydiorganosiloxane is a compound of unit formula: (R 2 R′SiO 1/2 ) a (R 3 SiO 1/2 ) b (R 2 SiO 2/2 ) c (RR′SiO 2/2 ) d , where each R is an independently selected monovalent hydrocarbon group of 1 to 18 carbon atoms that is free of aliphatic unsaturation, each R′ is an independently selected alkenyl group of 2 to 18 carbon atoms, subscript a is 0 to 2, subscript b is 0 to 2, a quantity (a+b)=2, subscript c≥0, subscript d≥0, a quantity (a+d)≥1, and a quantity (a+b+c+d) is sufficient to give the polydiorganosiloxane a viscosity of 2,000 mPa·s to 60,000 mPa·s at 25° C. measured at 0.1 to 50 RPM on a Brookfield DV-III cone & plate viscometer with #CP-52 spindle;
each based on the total weight of components (A), (B) and (C) in said composition.

2. The composition of claim 1 , where in the (C) polydiorganosiloxane is a bis-alkenyl-terminated polydiorganosiloxane of formula (I):

where each R is an independently selected monovalent hydrocarbon group of 1 to 18 carbon atoms that is free of aliphatic unsaturation, each R′ is an independently selected alkenyl group of 2 to 18 carbon atoms, and subscript x has a value sufficient to give the polydiorganosiloxane a viscosity of 2,000 mPa·s to 60,000 mPa's measured at 25° C. at 0.1 to 50 RPM on a Brookfield DV-III cone & plate viscometer with #CP-52 spindle.

3. The composition of claim 2 , where each R is an alkyl group of 1 to 12 carbon atoms, each R′ is an alkenyl group of 1 to 12 carbon atoms, subscript x has a value sufficient to give the polydiorganosiloxane a viscosity of 2,000 mPa·s to 10,000 mPa·s, and the (C) polydiorganosiloxane is present in an amount of 1 wt. % to 4 wt. %.

4. The composition of claim 3 , where in the (C) polydiorganosiloxane, each R is an alkyl group of 1 to 6 carbon atoms, and each R′ is an alkenyl group of 1 to 6 carbon atoms.

5. The composition of claim 2 , wherein in the (C) polydiorganosiloxane, each R is selected from the group consisting of methyl, ethyl, propyl, and butyl, and each R′ is selected from the group consisting of vinyl, allyl, butenyl, and hexenyl.

6. The composition of claim 1 , wherein: (i) said (A) mineral filler is present in an amount of from 10 to 65 wt. %; (ii) said (B) polyvinyl chloride polymer is present in an amount of from 35 to 90 wt. %; and (iii) said (C) polydiorganosiloxane is present in an amount of from 0.1 to 2.5 wt. %.

7. The composition of claim 1 , wherein: (i) said (A) mineral filler is present in an amount of from 49.5 to 60 wt. %; (ii) said (B) polyvinyl chloride polymer is present in an amount of from 40 to 49.5 wt. %; and (iii) said (C) polydiorganosiloxane is present in an amount of from 0.5 to 1 wt. %.

8. The composition of claim 1 , wherein the mineral filler is selected from calcium carbonate, talc, and combinations thereof.

9. The composition of claim 1 , further comprising one or more additives selected from a colorant, a blowing agent, a UV and/or light stabilizer, a process aid, a preservative, a biocide, a flame retardant and/or smoke suppressant, an impact modifier; a heat stabilizer, and a lubricant.

10. A method of preparing the composition of claim 1 , said method comprising:
combining (A) said mineral filler, (B) said polyvinyl chloride polymer, and (C) said polydiorganosiloxane, thereby preparing the composition.

11. A method of preparing a polymer composite article, said method comprising:
preparing the polymer composite article from the composition of claim 1 .

12. The method of claim 11 , wherein the method comprises:
combining the (A) mineral filler, the (B) polyvinyl chloride polymer, and the (C) polydiorganosiloxane at an elevated temperature under mixing to give a flowable mixture; and
forming the polymer composite article from the flowable mixture.

13. The method of claim 12 , wherein: (i) the (C) polydiorganosiloxane is a liquid when combining the flowable mixture with the (C) polydiorganosiloxane.

14. The method of claim 10 , wherein: (i) preparing the polymer composite article from the composition further comprises forming the composition into a desired shape; (ii) preparing the polymer composite article from the composition comprises extruding the composition; (iii) preparing the polymer composite article from the composition comprises molding the composition; or (iv) any combinations of (i) to (iii).

15. The method of claim 10 carried out in an extruder, wherein: (i) an extrusion processing temperature of the composition in the extruder is reduced as compared to an extrusion processing temperature of a mixture of the (A) mineral filler and the (B) polyvinyl chloride polymer without the (C) polydiorganosiloxane; and/or (ii) a torque of the extruder is reduced when mixing the composition as compared to a torque of the extruder when extruding a mixture of the (A) mineral filler and the (B) PVC polymer without the (C) polydiorganosiloxane.

16. A polymer composite article prepared by the method of claim 10 .

Assignees

• Rohm & Haas
• Dow Silicones Corp
• Dow Global Technologies Llc

Inventors

• Guo Hailan
• Nerkar Manoj
• Vuong Sharon M
• Chorvath Igor

Classifications

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title

• C08J2483/04

  Polysiloxanes · CPC title

• C08J2327/06

  Homopolymers or copolymers of vinyl chloride · CPC title

• B29C48/50

  Details of extruders · CPC title

• B29C48/001

  Combinations of extrusion moulding with other shaping operations · CPC title