Mat made of glass fibers or polyolefin fibers used as a separator in a lead-acid battery

Patent metadata

Field	Value
Publication number	US-12308469-B2
Application number	US-202117230003-A
Country	US
Kind code	B2
Filing date	Apr 14, 2021
Priority date	Apr 12, 2012
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

Embodiments of the invention provide methods and apparatuses for enhancing electron flow within a battery, such as a lead-acid battery. In one embodiment, a battery separator may include a conductive surface or layer upon which electrons may flow. The battery separator may include a fiber mat that includes a plurality of electrically insulative fibers. The battery separator may be positioned between electrodes of the battery to electrically insulate the electrodes. The battery separator may also include a conductive material disposed on at least one surface of the fiber mat. The conductive material may contact an electrode of the battery and may have an electrical conductivity that enables electron flow on the surface of the fiber mat.

First claim

What is claimed is:

1. A battery separator comprising:
a mat including a plurality of electrically insulative glass fibers, the mat being configured to separate a positive electrode and a negative electrode of a battery to electrically insulate the positive and negative electrodes; and
a conductive material disposed on one surface of the mat to form a conductive layer on the surface of the mat, wherein the conductive material contacts at least one of the positive or negative electrodes of the battery, wherein the conductive material enables electron flow on the surface of the mat, and wherein the conductive material is a separate material from an active material of the positive electrode and an active material of the negative electrode;
wherein the conductive layer is a coating on individual electrically insulative glass fibers of the mat.

2. The battery separator of claim 1 , wherein the surface of the mat includes a catalyst, and wherein the conductive material consists of metal ions grown on the surface of the mat via the catalyst.

3. The battery separator of claim 1 , wherein the conductive material is a material that is deposited on the surface of the mat via chemical vapor deposition.

4. The battery separator of claim 1 , wherein the conductive material is a material that is spray coated onto the surface of the mat.

5. The battery separator of claim 4 , wherein the spray coating comprises a mixture of the conductive material and a binder.

6. The battery separator of claim 1 , wherein the conductive material comprises one or more materials selected from the group consisting of:
conductive polymers;
nanocarbons;
a metal;
copper;
titanium;
vanadium;
graphite; and
graphene.

7. A lead-acid battery comprising:
a positive electrode;
a negative electrode; and
a mat separating the positive electrode and the negative electrode so as to electrically insulate the positive and negative electrodes, the fiber mat comprising:
a plurality of electrically insulative glass fibers; and
a conductive material disposed on one surface of the mat to form a conductive layer on the surface of the mat, wherein the conductive material is a separate material from an active material of the positive electrode and an active material of the negative electrode;
wherein the conductive layer is a coating on individual electrically insulative glass fibers of the mat.

8. The lead-acid battery of claim 7 , wherein the surface of the mat includes a catalyst, and wherein the conductive material consists of metal ions grown on the surface of the mat via the catalyst.

9. The lead-acid battery of claim 7 , wherein the conductive material is a material that is deposited on the surface of the mat via chemical vapor deposition.

10. The lead-acid battery of claim 7 , wherein the conductive material is a material that is spray coated onto the surface of the mat.

11. The lead-acid battery of claim 7 , wherein the conductive material comprises a plurality of conductive polymers.

12. The lead-acid battery of claim 7 , further comprising a microporous membrane disposed on a surface of the mat opposite the conductive material.

13. The method of claim 7 , wherein applying the conductive material to the opposite surface of the fiber mat comprises spray coating the conductive material onto the opposite surface of the fiber mat.

14. A method of forming a conductive surface on a battery separator, the method comprising:
providing a fiber mat, the fiber mat comprising:
a plurality of electrically insulative glass fibers; and
a binder that bonds the electrically insulative fibers together;

positioning a polymeric microporous membrane on one surface of the fiber mat; and
coating at least some of the electrically insulative glass fibers with a conductive material to form a conductive layer on an opposite surface of the fiber mat, the conductive layer having an electrical resistance of less than about 100,000 ohms per square to enable electron flow on the opposite surface of the fiber mat;
wherein the conductive material is a separate material from an active material of a positive electrode and an active material of a negative electrode.

15. The method of claim 14 , wherein applying the conductive material to the opposite surface of the fiber mat comprises:
applying a catalyst to the opposite surface of the fiber mat; and
growing metal ions on the opposite surface of the fiber mat.

16. The method of claim 14 , wherein applying the conductive material to the opposite surface of the fiber mat comprises depositing the conductive material on the opposite surface of the mat via chemical vapor deposition.

Assignees

• Johns Manville

Inventors

• Nandi Souvik
• Guo Zhuhua
• Asrar Jawed
• Dietz Iii Albert G

Classifications

• H01M50/417

  Polyolefins · CPC title

• H01M50/451

  comprising layers of only organic material and layers containing inorganic material · CPC title

• H01M50/454

  comprising a non-fibrous layer and a fibrous layer superimposed on one another · CPC title

• H01M50/457

  comprising three or more layers · CPC title

• H01M50/437

  Glass · CPC title