Porous interconnected corrugated carbon-based network (ICCN) composite

Patent metadata

Field	Value
Publication number	US-12308167-B2
Application number	US-202318467964-A
Country	US
Kind code	B2
Filing date	Sep 15, 2023
Priority date	Nov 18, 2014
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A porous interconnected corrugated carbon-based network (ICCN) composite and methods for making the same are disclosed. The porous ICCN composite is made up of a plurality of carbon layers that are interconnected and expanded apart from one another to form a plurality of pores. Metallic nanoparticles are disposed within the plurality of pores. In one embodiment, a light exposure only based method for producing the porous ICCN composite is disclosed. In another embodiment a light exposure plus an electrodeposition method for producing the porous ICCN composite is disclosed. In yet another exemplary embodiment, a capacitor having a first electrode and a second electrode separated from the first electrode by a dielectric wherein at least one of the first electrode and the second electrode is formed from the porous ICCN composite is disclosed.

First claim

What is claimed is:

1. An electrode comprising:
a porous interconnected corrugated carbon-based network (ICCN) composite that comprises:
a plurality of carbon layers that are interconnected and expanded apart from one another to form a plurality of pores, and
metallic nanoparticles,
wherein a portion of the plurality of pores has an average minor axis diameter of at least about 75 nanometers.

2. The electrode of claim 1 , wherein a portion of the metallic nanoparticles is nanoflowers or nanoflakes.

3. The electrode of claim 2 , wherein the portion of the metallic nanoparticles is MnO 2 .

4. The electrode of claim 1 , wherein a percentage of surface area coverage of the metallic nanoparticles on the plurality of carbon layers is at least 15%.

5. The electrode of claim 1 , wherein a percentage of surface area coverage of the metallic nanoparticles on the plurality of carbon layers is at least 30%.

6. The electrode of claim 1 , wherein a percentage of surface area coverage of the metallic nanoparticles on the plurality of carbon layers is at least 70%.

7. The electrode of claim 1 , wherein a percentage of surface area coverage of the metallic nanoparticles on the plurality of carbon layers is at least 90%.

8. The electrode of claim 1 , wherein the average minor axis diameter is at most about 550 nanometers.

9. The electrode of claim 1 , wherein at least a portion of adjacent carbon layers of the plurality of carbon layers is separated by at least 2 nanometers.

10. The electrode of claim 1 , wherein at least a portion of the carbon layers of the plurality carbon layers has a thickness of one carbon atom.

11. The electrode of claim 1 , wherein the metallic nanoparticles comprise metal oxide particles.

12. The electrode of claim 11 , wherein the metal oxide particles are particles of manganese dioxide (MnO 2 ), ruthenium dioxide (RuO 2 ), cobalt oxide (Co 3 O 4 ), nickel oxide (NiO), iron oxide (Fe 2 O 3 ), copper oxide (CuO), molybdenum trioxide (MoO 3 ), vanadium pentoxide (V 2 O 5 ), nickel hydroxide (Ni(OH) 2 ), or any combination thereof.

13. The electrode of claim 1 , wherein an electrical conductivity of the plurality of carbon layers is greater than about 0.1 siemens/meter.

14. The electrode of claim 1 , wherein a total surface area per unit mass of the plurality of carbon layers is about 1500 square meters per gram to about 1620 square meters per gram.

15. The electrode of claim 1 , wherein a percentage of surface area coverage of the metallic nanoparticles on the plurality of carbon layers is at least about 50%.

16. The electrode of claim 1 , wherein the electrode comprises a plurality of extending electrode digits.

17. The electrode of claim 1 , wherein the electrode has a volumetric capacitance of at least about 300 F/cm 3 .

18. The electrode of claim 1 , wherein the electrode has an areal capacitance of at least about 0.3 F/cm 2 .

19. The electrode of claim 1 , wherein a resistance of the electrode is substantially the same after about 1000 cycles of bending.

20. A method of producing a porous interconnected corrugated carbon-based network (ICCN) composite comprising:
a. forming the porous ICCN comprising a plurality of carbon layers that are interconnected and expanded apart from one another to form a plurality of pores;
b. submerging the porous ICCN into an aqueous solution having a metal precursor; and
c. converting the metal precursor to a metal nanoparticle using an electric current and light exposure.

Assignees

• Univ California

Inventors

• El-Kady Maher F
• Kaner Richard B
• Hwang Jee Youn

Classifications

• Y02T10/70

  Energy storage systems for electromobility, e.g. batteries · CPC title

• H01G11/02

  using combined reduction-oxidation reactions, e.g. redox arrangement or solion · CPC title

• H01G11/70

  characterised by their structure · CPC title

• C01B32/194

  After-treatment · CPC title

• C01B32/184 Primary

  Preparation · CPC title