Rapidly solidified aluminum-rare earth element alloy and method of making the same

Patent metadata

Field	Value
Publication number	US-12305267-B2
Application number	US-201815901759-A
Country	US
Kind code	B2
Filing date	Feb 21, 2018
Priority date	Feb 22, 2017
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

Disclosed herein are embodiments of rapidly solidified alloys that comprise aluminum, a rare earth element, one or more additional alloying elements, such as aluminum, and an optional additive component. The alloy embodiments exhibit a unique microstructure as compared to microstructures obtained from other alloys that are not rapidly cooled. The disclosed aluminum-rare earth element alloys also exhibit improved mechanical properties without the need for post-processing heat treatments and further do not exhibit substantial coarsening.

First claim

We claim:

1. A method, comprising:
combining aluminum with (i) 0.1 wt % to 8 wt % of an additional alloying element selected from magnesium, zinc, titanium, manganese, zirconium, vanadium, scandium, copper, or nickel, or one or more of magnesium, zinc, titanium, manganese, zirconium, vanadium, and scandium in combination with copper or in combination with nickel; (ii) at least one rare earth component selected from lanthanum, cerium, mischmetal, or a combination thereof; and (iii) 0.1 wt % to 2 wt % of an additive component selected from iron, strontium, boron, manganese, titanium, chromium, cobalt, carbon, or a combination thereof to form an aluminum-based alloy composition; wherein the aluminum-based alloy composition does not comprise both copper and nickel in combination; and
performing a cooling step, wherein the mixed aluminum-based alloy composition is cooled at an average cooling rate range from greater than 100 K/s to 10 8 K/s to provide an aluminum-based alloy comprising an aluminum matrix phase, an Al 11 X 3 intermetallic phase where X is one of lanthanum, cerium, or mischmetal, or a combination thereof, and (i) a semi- to fully-eutectic phase with a maximum spacing between morphologic features of the semi- to fully-eutectic phase being no greater than 8 μm; or (ii) a phase comprising laths and/or rods, wherein the aluminum matrix phase, the Al 11 X 3 intermetallic phase, and the semi- to fully-eutectic phase, or the phase comprising laths and/or rods are obtained without a heat treatment; provided that the cooling step does not comprise continuous cast rolling to cool the mixed aluminum-based alloy composition.

2. The method of claim 1 , wherein the average cooling rate ranges from 1000 K/s to 10 5 K/s.

3. The method of claim 1 , wherein the average cooling rate ranges from greater than 10 5 K/s to 10 8 K/s.

4. The method of claim 1 , wherein the aluminum-based alloy comprises 8 wt % to 12 wt % of the at least one rare earth component and wherein the at least one rare earth component is cerium.

5. The method of claim 1 , wherein the aluminum-based alloy comprises an Al 13 (Mg,Ce) 2 phase, an Al 12 CeMg 6 phase, an FCC matrix phase comprising aluminum and cerium, or any combination of such phases.

6. The method of claim 1 , wherein the aluminum-based alloy consists essentially of 12 wt % cerium, 0.4 wt % magnesium, 1 wt % iron, and a balance of aluminum.

7. The method of claim 1 , wherein the semi- to fully-eutectic phase has a maximum spacing between morphologic features ranging from greater than 0 μm to less than or equal to 5 μm.

8. The method of claim 1 , wherein the method does not comprise a post-processing heat treatment.

9. The method of claim 1 , wherein the aluminum-based alloy does not exhibit substantial coarsening of the semi- to fully-eutectic microstructure such that an increase in average spacing of lamellae and/or particles within the semi- to fully-eutectic microstructure does not occur after being exposed to processing temperatures of 150° C. to 500° C. for 1500 hours.

10. The method of claim 1 , wherein the aluminum-based alloy composition consists of aluminum, the additional alloying element, the at least one rare earth component, the additive component, and trace impurities.

11. The method of claim 1 , wherein the average cooling rate ranges from greater than 100 K/s to less than 1000 K/s.

Assignees

• Ut Battelle Llc
• Univ Tennessee Res Found
• Univ Iowa State Res Found Inc
• Eck Ind Incorporated
• L Livermore Nat Security Llc

Inventors

• Rios Orlando
• Mccall Scott
• Ott Ryan
• Sims Zachary Cole
• Kesler Michael
• Henderson Hunter B
• Mcguire Michael
• Weiss David

Classifications

• C22C1/11

  Making amorphous alloys · CPC title

• B22D21/007

  with low melting point, e.g. Al 659 degrees C, Mg 650 degrees C · CPC title

• C22C21/06

  with magnesium as the next major constituent · CPC title

• C22F1/047

  of alloys with magnesium as the next major constituent · CPC title

• C22C21/00

  Alloys based on aluminium · CPC title