Method for producing platelet-shaped pigments

Patent metadata

Field	Value
Publication number	US-12305041-B2
Application number	US-202118032440-A
Country	US
Kind code	B2
Filing date	Sep 21, 2021
Priority date	Oct 20, 2020
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A method is provided for producing platelet-shaped pigments, including the steps of: providing a film structure which has a carrier substrate, a water-soluble release layer and a pigment material layer; mechanically disrupting the pigment material layer, which is present in the film structure, at specific locations; soaking the film structure with aqueous solution; subjecting the film structure to a mechanical force so that the pigment material layer is detached from the carrier substrate as a plurality of pigments according to the ruptures present at the specific locations.

First claim

The invention claimed is:

1. A method for producing platelet-shaped pigments, comprising the steps of:
a) providing a film structure which comprises a carrier substrate, a water-soluble release layer and a pigment material layer;
b) mechanically disrupting the pigment material layer present in the film structure, at specific locations;
c) soaking the film structure with aqueous solution by spraying using misting nozzles;
d) subjecting the film structure to mechanical force, so that the pigment material layer is detached from the carrier substrate as a multiplicity of pigments in accordance with ruptures that are present at specific locations.

2. The method of claim 1 , wherein the pigment material layer is a thin-layer system having an optically variable effect.

3. The method of claim 1 , wherein the aqueous solution in step c) contains at least 90 wt % of water, with the remaining fraction comprising wetting agents and/or organic solvents.

4. The method of claim 1 , wherein the mechanical disrupting in step b) takes place by means of a printing mechanism having an anilox roll, a gravure cylinder or a nickel cylinder.

5. The method of claim 1 , wherein the mechanical disrupting in step b) takes place such that the film structure is diverted with tensile stress over an edge breaker, including an elongate body disposed perpendicular to the running direction of the film structure, with the elongate body having a round or triangular or tetragonal cross section.

6. The method of claim 5 , wherein the mechanical disrupting in step e) step b) takes place by means of a printing mechanism having an anilox roll, a gravure cylinder or a nickel cylinder;
wherein the mechanical disrupting in step b) takes place by means of a printing mechanism as a prestructuring measure and additionally thereto such that the film structure is diverted under tensile stress over an edge breaker, including an elongate body disposed perpendicular to the running direction of the film structure.

7. The method of claim 1 , wherein the soaking of the film structure with aqueous solution in step c) takes place within a wet chamber, with a transport path established for the film structure in the wet chamber being an extended, serpentine transport path brought about by deflecting rolls.

8. The method of claim 1 , wherein the subjecting of the film structure to mechanical force in step d) is realized by the use of ultrasound and/or by the use of brushes and/or by the use of a feltboard or by the use of a felt-covered roll and/or by the use of high-pressure nozzles.

9. The method of claim 1 , wherein the water-soluble release layer is based on a material selected from the group consisting of polyvinylpyrrolidone, modified starch, polyacrylic acid, polyethylene glycol, hydroxypropylcellulose, hydroxyethylcellulose, casein, gum arabic, carboxymethylcellulose, polyvinyl alcohol, dextrin, or a mixture of two or more of the aforesaid substances.

10. The method of claim 1 , wherein the water-soluble release layer has an applied weight in a range from 0.05 to 20 g/m2.

11. The method of claim 1 , wherein the water-soluble release layer has a layer thickness in a range from 0.05 to 20 μm.

12. The method of claim 1 , wherein the pigment material layer is color-flopping thin-layer element which conveys a different perceived color to a viewer at different viewing angles, and optionally has an additionally present magnetic layer for the magnetic orientation of the pigment.

13. The method of claim 12 , wherein the color-flopping thin-layer element has a reflective layer, a dielectric spacer layer and an absorber layer and is formed with a symmetrical multilayer arrangement, with the symmetrical multilayer arrangement having the following layer sequence, in which optionally there is an additionally present magnetic layer included: absorber layer-dielectric spacer layer-reflective layer-dielectric spacer layer-absorber layer.

14. The method of claim 13 , wherein the color-flopping thin-layer element is formed with a symmetrical multilayer arrangement, with the symmetrical multilayer arrangement having the layer sequence Cr/SiO2/Al/SiO2/Cr or the layer sequence Al/SiO2/Al/SiO2/Al or the layer sequence Cr/SiO2/Al/FeSi/Al/SiO2/Cr.

Assignees

• Giesecke & Devrient Currency Technology Gmbh

Inventors

• Scherer Maik Rudolf Johann
• Scherer Kai Herrmann
• Sobol Michael
• Wetter Sebastian
• Frohlich Florian
• Heim Manfred
• Gegenfurtner Thomas
• Rauch Andreas
• Vogt Norbert
• Quirino Ivo

Classifications

• C09C2220/00

  Methods of preparing the interference pigments · CPC title

• C09C2200/10

  Interference pigments characterized by the core material · CPC title

• B32B43/006

  Delaminating · CPC title

• C09C3/041

  Grinding · CPC title

• C09C1/0015

  Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings · CPC title