Curable composition and synthetic leather

Patent metadata

Field	Value
Publication number	US-12304992-B2
Application number	US-202017639064-A
Country	US
Kind code	B2
Filing date	Sep 4, 2020
Priority date	Sep 4, 2019
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A curable composition including:a component (a): a polycarbonate polyol having a hydroxyl value of 40 to 75 mgKOH/g;a component (b): a polycarbonate polyol having a hydroxyl value of 100 to 280 mgKOH/g; anda component (c): a polyisocyanate having an average number of functional groups per molecule, of 2 to 6.

First claim

The invention claimed is:

1. A curable composition comprising:
a component (a): a polycarbonate polyol having a hydroxyl value of 50 to 75 mgKOH/g;
a component (b): an aliphatic polycarbonate polyol having a hydroxyl value of 138 to 280 mgKOH/g; and
a component (c): a polyisocyanate having an average number of functional groups per molecule, of 2 to 6.

2. The curable composition according to claim 1 , wherein the polycarbonate polyol of the component (a) and the component (b) each has a repeating unit represented by the following formula (1) and a terminal hydroxyl group:

wherein R 1 is a divalent aliphatic or alicyclic hydrocarbon having 2 to 15 carbon atoms, where the R 1 for the component (a) and the component (b) may be the same or different, wherein R 1 for component (b) is aliphatic.

3. The curable composition according to claim 1 , wherein the polycarbonate polyol of the component (a) and the component (b) each comprises a structure represented by the following formula (A):

wherein each R 11 is a divalent linear, branched or cyclic aliphatic hydrocarbon group having 2 or more and 20 or less carbon atoms, or an aromatic hydrocarbon group for component (a), a plurality of R 11 (s) may be the same as or different from each other, and n11 is an integer of 1 or more;
where the R 11 and the n11 for the component (a) and the component (b) may be the same or different.

4. The curable composition according to claim 2 , wherein 50% by mol or more of the repeating unit represented by the formula (1) of the component (a) and the component (b) each comprises at least two repeating units selected from the following formula (2), formula (3), and formula (4),

where the at least two repeating units for the component (a) and the component (b) may be the same or different.

5. The curable composition according to claim 1 , comprising 40% by mass or less of an inert organic solvent based on a total amount of the curable composition.

6. The curable composition according to claim 1 , comprising 50% by mass or less of a polyester polyol based on a total amount of the curable composition.

7. Synthetic leather produced from the curable composition according to claim 1 .

Assignees

• Asahi Chemical Ind

Inventors

• Masubuchi Tetsuo
• Hoshino Eriko

Classifications

• D06N3/147

  characterised by the isocyanates used · CPC title

• D06N3/121

  with polyesters, polycarbonates, alkyds (oils D06N3/16) · CPC title

• C08G18/8016

  Masked aliphatic or cycloaliphatic polyisocyanates · CPC title

• D06N2211/28

  Artificial leather · CPC title

• D06N2209/143

  Inert, i.e. inert to chemical degradation, corrosion resistant · CPC title