Method for producing a composite insulating mineral construction element

Patent metadata

Field	Value
Publication number	US-12304872-B2
Application number	US-202118044932-A
Country	US
Kind code	B2
Filing date	Sep 17, 2021
Priority date	Sep 18, 2020
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

A method for producing a composite insulating mineral construction element includes filling the cavity of a construction element including at least one cavity delimited by at least one inner wall at least partially having a water absorption rate of more than 5 g/(m 2 ·s) at 10 minutes according to standard NF EN 772-11 of August 2011 with a foamed cement slurry including a cement being an hydraulic binder including a proportion of at least 50% by weight of calcium oxide CaO and silicone dioxide SiO 2 , a metal salt selected from an aluminium, magnesium or iron salt and mixtures thereof, and a cellulose ether; and leaving the foamed cement slurry to set within the cavity resulting in the formation of a mineral foam, wherein the foamed cement slurry includes from 0.01 to 0.2% by weight of cellulose ether, relative to the weight of cement.

First claim

The invention claimed is:

1. A method for producing a composite insulating mineral construction element comprising the following steps:
a) filling a cavity of a construction element comprising at least one cavity delimited by at least one inner wall at least partially having a water absorption rate of more than 5 g/(m 2 ·s) at 10 minutes according to standard NF EN 772-11 of August 2011 with a foamed cement slurry comprising a cement being an hydraulic binder comprising a proportion of at least 50% of calcium oxide CaO and silicon dioxide SiO 2 , a metal salt selected from an aluminium, magnesium or iron salt and mixtures thereof, and a cellulose ether;
b) leaving the foamed cement slurry to set within the cavity resulting in the formation of a mineral foam;
wherein the foamed cement slurry comprises from 0.01 to 0.2% by weight of cellulose ether, relative to the weight of cement.

2. The method according to claim 1 , wherein the foamed cement slurry comprises 0.01 to 0.1% by weight of cellulose ether, relative to the weight of cement.

3. The method according to claim 1 , wherein the cellulose ether is a an anionic cellulose ether or a nonionic cellulose ether or a mixture thereof.

4. The method according to claim 3 , wherein the anionic cellulose ether is carboxymethyl cellulose (CMC), carboxymethyl hydroxyethyl cellulose (CMHEC), carboxymethyl hydroxy-propyl cellulose (CMHPC), sulfoethyl methyl hydroxyethyl cellulose (SEMHEC) or sulfoethyl methyl hydroxypropyl cellulose (SEMHPC).

5. The method according to claim 3 , wherein the nonionic cellulose ether is hydroxyethyl cellulose (HEC), hydroxypropyl cellulose (HPC), methyl cellulose (MC), methyl hydroxypropyl cellulose (MHPC), methyl hydroxyethyl cellulose (MHEC), ethyl hydroxyethyl cellulose (EHEC) or methyl ethyl hydroxyethyl cellulose (MEHEC).

6. The method according to claim 1 , wherein the cellulose ether is a cellulose ether having a viscosity level comprised between 100 mPa·s to 5000 mPa·s.

7. The method according to claim 6 , wherein the cellulose ether has a viscosity level ranging between 300 mPa·s to 1500 mPa·s.

8. The method according to claim 1 , wherein the cellulose ether is a cellulose ether with delayed solubility.

9. The method according to claim 1 , wherein the foamed cement slurry comprises 0.05% to 5% by weight of metal salt, relative to the weight of cement.

10. The method according to claim 9 , wherein the foamed cement slurry comprises 0.15% to 1.5% by weight of metal salt, relative to the weight of cement.

11. The method according to claim 1 wherein the metal salt is a salt of aluminium.

12. The method according to claim 11 , wherein the salt of aluminium is aluminium sulphate.

13. The method according to claim 1 , wherein the foamed cement slurry used in step a) is obtained by a process comprising:
(i) separately preparing a cement slurry and an aqueous foam;
(ii) contacting the cement slurry with the aqueous foam to obtain a foamed cement slurry;
wherein:
the cement slurry of step (i) comprises the metal salt,
and
the cellulose ether is comprised within the cement slurry of step (i) and/or is within the aqueous foam of step (i) and/or is added to the foamed cement slurry obtained in step (ii).

14. The method according to claim 13 , wherein the cement slurry of step (i) comprises cement and water with a weight water/cement ratio ranging between 0.25 to 0.5.

15. The method according to claim 13 , wherein the method comprises a step (iii) of adding a mixture comprising metal salt, cellulose ether and water in the foamed cement slurry obtained in step (ii).

16. The method according to claim 1 , wherein the mixture comprises cellulose ether in the form of particles having an average particle size of 125 μm or less.

17. The method according to claim 1 , wherein the mineral foam obtained after step b) has one or many of the following features:
the mineral foam has a density of less than 600 m 3 /kg;
the mineral foam comprises from 0.01% to 0.2% by weight of cellulose ether;
the mineral foam comprises 0.15% to 5% by weight relative to the weight of cement.

18. The method according to claim 1 , wherein the mineral construction element is selected from a concrete block, a brick, a double wall, a sandwich panel, a 3D construction wall.

19. A method comprising utilizing a combination of a metal salt and a cellulose ether as defined in claim 1 with a cement being an hydraulic binder comprising a proportion of at least 50% by weight of calcium oxide CaO and silicone dioxide SiO 2 for improving the stability of a foamed cement slurry when it comes into contact with a material having a water absorption rate of more than 5 g/(m 2 ·s) at 10 minutes according to standard NF EN 772-11 of August 2011.

20. A composite insulating mineral construction element obtained by the method according to claim 1 .

Assignees

• Holcim Technology Ltd

Inventors

• Tintillier Patrick
• Perez Nicolas
• Serre Florence

Classifications

• E04B1/7604

  fillings for cavity walls · CPC title

• C04B2201/30

  for heat transfer properties such as thermal insulation values, e.g. R-values · CPC title

• C04B2201/20

  for the density · CPC title

• C04B2111/40

  Porous or lightweight materials · CPC title

• C04B2111/00698

  for cavity walls · CPC title