Process for producing continuous graphene fibers from functionalized graphene sheets
US-2019345647-A1 · Nov 14, 2019 · US
US12304158B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12304158-B2 |
| Application number | US-202117907679-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 31, 2021 |
| Priority date | Mar 31, 2020 |
| Publication date | May 20, 2025 |
| Grant date | May 20, 2025 |
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Provided herein is a method for aligning discontinuous fibres comprising: providing a stream of discontinuous fibres in a dispersion medium; applying a shear stress to the dispersion medium to align at least a portion of the discontinuous fibres; and disposing the at least a portion of the aligned discontinuous fibres on a substrate thereby providing a layer of substantially aligned discontinuous fibres. Also provided are discontinuous fibres aligned by such method and a composite material formed from the aligned discontinuous fibres.
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The claims defining the invention are as follows: 1. A method for aligning discontinuous fibres comprising: providing a stream of discontinuous fibres in a dispersion medium; applying a shear stress to the dispersion medium using a shearing element to align at least a portion of the discontinuous fibres, wherein the shearing element has an inlet for receiving the stream of discontinuous fibres in a dispersion medium and an outlet, wherein the shearing element comprises a first region having at least one ramp surface on a first plane having an angle between about 5 to about 90 degrees relative to the direction of the stream of discontinuous fibres for aligning at least a portion of the discontinued fibres and a second region having at least two convergent surfaces on a second plane for aligning at least a portion of the discontinued fibres, wherein the angle between the first plane and the second plane is between about 5 to about 90 degrees; and disposing the at least a portion of the aligned discontinuous fibres on a substrate thereby providing a layer of substantially aligned discontinuous fibres. 2. The method of claim 1 , further comprising passing the stream of discontinuous fibres through a force field to align at least a portion of the discontinuous fibres. 3. The method of claim 1 , wherein the first region and second region independently applies shear stress to align at least a portion of the discontinuous fibres. 4. The method of claim 1 , wherein the first region and second region sequentially applies shear stress to the dispersion medium to align at least a portion of the discontinuous fibres. 5. The method of claim 1 , wherein the shear stress applied to the dispersion medium of the first region is less than the shear stress applied to the dispersion medium of the second region. 6. The method of claim 1 , further comprising providing homogeneously dispersed discontinuous fibres in a dispersion medium prior to providing the stream of discontinuous fibres. 7. The method of claim 1 , wherein the dispersion medium comprises discontinuous fibres in an amount of from about 0.001% to about 35% w/w. 8. The method of claim 2 , wherein the force field is selected from the group consisting of a magnetic field, an electric field, an electromagnetic field and combinations thereof. 9. A carbon fibre reinforced polymer (CFRP) composite comprising discontinuous fibres aligned by the method of claim 1 . 10. A fibre aligning apparatus comprising: a shearing element for applying a shear stress to a dispersion medium having an inlet adapted for receiving a stream of discontinuous fibres in a dispersion medium and an outlet, wherein the shearing element comprises a first region having at least one ramp surface on a first plane having an angle between about 5 to about 90 degrees relative to the direction of the stream of discontinuous fibres for aligning at least a portion of the discontinued fibres and a second region having at least two convergent surfaces on a second plane for aligning at least a portion of the discontinued fibres, wherein the angle between the first plane and the second plane is between about 5 to about 90 degrees; such that in use, the stream of discontinuous fibres undergoes shear stress thereby providing substantially aligned discontinuous fibres. 11. The fibre aligning apparatus according to claim 10 , further comprising a force field element associated with the shearing element for aligning at least a portion of the discontinuous fibres such that in use, the stream of discontinuous fibres undergoes shear stress and interact with a force field of the force field element thereby providing substantially aligned discontinuous fibres. 12. The fibre aligning apparatus according to claim 11 , wherein the force field element is a magnetic field generator, electric field generator or an electromagnetic field generator. 13. The fibre aligning apparatus according to claim 10 , wherein the at least one ramp surface is substantially planar, convex or concave. 14. The fibre aligning apparatus according to claim 10 , wherein the ramp surface has a radius of curvature of between about 2 to 60 degrees. 15. The fibre aligning apparatus according to claim 10 , wherein the at least two convergent surfaces are independently substantially planar, convex or concave. 16. The fibre aligning apparatus according to claim 10 , wherein each convergent surface independently has a radius of curvature of between about 2 to 60 degrees. 17. The fibre aligning apparatus according to claim 11 , wherein the shearing element and force field element are positioned sequentially. 18. The fibre aligning apparatus according to claim 11 , wherein the shearing element and force field element are co-located. 19. The fibre aligning apparatus according to claim 11 , wherein the shearing element and force field element are integrally connected. 20. The fibre aligning apparatus according to claim 11 , wherein the force field element is selected from the group consisting of a magnet, charged plates, electromagnet and combinations thereof.
Component parts, details or accessories; Auxiliary operations {, e.g. feeding or storage of prepregs or SMC after impregnation or during ageing} · CPC title
Aligning or orienting the fibres · CPC title
electrostatic, electric, or magnetic · CPC title
designed to produce a jet, spray, or other discharge of particular shape or nature, e.g. in single drops, {or having an outlet of particular shape}(B05B1/26, B05B1/28, B05B1/34 take precedence) · CPC title
Carbon fibres · CPC title
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