Alkaline anion exchange membranes derived from diphenylethylene and co-monomer feedstock

Patent metadata

Field	Value
Publication number	US-12303880-B2
Application number	US-202418594586-A
Country	US
Kind code	B2
Filing date	Mar 4, 2024
Priority date	Oct 22, 2018
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

The anion exchange membranes exhibit enhanced chemical stability and ion conductivity when compared with traditional styrene-based alkaline anion exchange membranes. A copolymer backbone is polymerized from a reaction medium that includes a diphenylalkylene and an alkadiene. The copolymer includes a plurality of pendant phenyl groups. The diphenyl groups on the polymer backbone are functionalized with one or more haloalkylated precursor substrates. The terminal halide from the precursor substrate can then be substituted with a desired ionic group. The diphenylethylene-based alkaline anion exchange membranes lack the α-hydrogens sharing tertiary carbons with phenyl groups from polystyrene or styrene-based precursor polymers, resulting in higher chemical stability. The ionic groups are also apart from each other by about 3 to 6 carbons in the polymer backbone, enhancing ion conductivity. These membrane are advantageous for use in fuel cells, electrolyzers employing hydrogen, ion separations, etc.

First claim

What is claimed is:

1. An ion exchange membrane material comprising:
a polymer according to Formula I:

wherein each R β includes an butadiene, isoprene, hydrogenated butadiene, hydrogenated isoprene, or combinations thereof; and each R1 includes an alkylated substrate including a hydrocarbyl group and at least one ionic group.

2. The ion exchange membrane material according to claim 1 , wherein the ionic groups include one or more ammonium groups, one or more multication hydrocarbyl chains, or combinations thereof.

3. The ion exchange membrane material according to claim 1 , wherein the polymer includes the structure according to Formula II:

wherein each R1 includes an alkylated substrate including a hydrocarbyl group and at least one ionic group; and each R2 is R1, H, or combinations thereof.

4. The ion exchange membrane material according to claim 3 , wherein x is between about 0.8 to about 0.9.

5. The ion exchange membrane material according to claim 3 , wherein R1 groups are substantially evenly distributed long the polymer.

6. The ion exchange membrane material according to claim 3 , wherein each R1 includes the structure according to Formula III:

Assignees

• Rensselaer Polytech Inst

Inventors

• Lee Sangwoo
• Bae Chulsung
• Briem Musashi J
• Park Sungmin

Classifications

• C08J5/2287

  After-treatment · CPC title

• C08F2810/00

  Chemical modification of a polymer · CPC title

• C08F212/32

  containing two or more rings · CPC title

• C02F1/469

  by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis · CPC title

• B01J47/12

  characterised by the use of ion-exchange material in the form of ribbons, filaments, fibres or sheets, e.g. membranes (electrodialysis or electro-osmosis B01D61/42) · CPC title