Device system and method having sintering flue gas CO catalytic heat exchange and medium-and-low-temperature SCR denitration connected in series

Patent metadata

Field	Value
Publication number	US-12303828-B2
Application number	US-202218730414-A
Country	US
Kind code	B2
Filing date	Aug 8, 2022
Priority date	May 30, 2022
Publication date	May 20, 2025
Grant date	May 20, 2025

Abstract

Disclosed in the present invention are a device system and method having sintering flue gas CO catalytic heat exchange and medium-and-low-temperature SCR denitration connected in series. In the device system, a CO catalytic heat storage and exchange device is arranged to completely replace an original heat exchanger arranged after a raw desulfurized flue gas pipe. The method comprises respectively carrying out first CO catalytic conversion and second CO catalytic conversion on sintering flue gas and denitrated flue gas by means of the CO catalytic heat storage and exchange device, thereby increasing CO conversion efficiency and reducing overall resistance of the system. In addition, the present invention takes both CO pollution control and carbon emission reduction into consideration and thus has good economic benefits and a good application prospect.

First claim

What is claimed is:

1. A method for sintering flue gas having CO catalytic heat exchange in series with medium/low-temperature SCR denitration, which is performed with a device system for sintering flue gas having CO catalytic heat exchange in series with medium/low-temperature SCR denitration;
the device system comprises a CO catalytic regenerative heat exchange device, an ammonia spray device, and a medium/low-temperature SCR denitration reaction device which are sequentially connected along the flow direction of raw flue gas;
a sintering flue gas inlet of the CO catalytic regenerative heat exchange device is directly connected to a desulfurized raw flue gas pipeline;
a purified flue gas outlet of the medium/low-temperature SCR denitration reaction device is connected to a denitrated flue gas inlet of the CO catalytic regenerative heat exchange device;
a CO heat-regenerative catalyst comprises a cordierite honeycomb ceramic heat-regenerative framework and an active component which is arranged on the cordierite honeycomb ceramic heat-regenerative framework
the cordierite honeycomb ceramic heat-regenerative framework has a porosity of 0.5-0.7;
the method comprises the following steps:
(1) subjecting sintering flue gas to the CO catalytic regenerative heat exchange device to perform a first CO catalytic conversion and heat the sintering flue gas to obtain heated flue gas;
(2) mixing the heated flue gas with an ammonia source by the ammonia spray device, and then introducing into the medium/low-temperature SCR denitration reaction device to perform an SCR denitration reaction to obtain denitrated flue gas; a temperature of the heated flue gas which is introduced into the ammonia spray device in step (2) is 220-280° C., and a complete reaction temperature of the CO heat-regenerative catalyst in the CO catalytic regenerative heat exchange device is 180-220° C.; and
(3) introducing the denitrated flue gas into the CO catalytic regenerative heat exchange device to perform heat exchange cooling and a second CO catalytic conversion to obtain purified sintering flue gas;
using heat release from CO catalytic oxidation to replace heat supplement of hot blast furnace fuel and a heat exchanger device;
wherein at the stage where the process of step (1) is being started up, the heated flue gas is subjected a hot blast furnace device for heat supplement before introduced to the ammonia spray device;
for the flue gas with a flow rate of 850000 Nm 3 /h, the total system pressure drop is less than or equal to 1900 Pa; the consumption of blast furnace gas is less than or equal to 50000 m 3 in 30 days; the NO x concentration in the purified flue gas is less than or equal to 40 mg/m 3 , and the CO concentration in the purified flue gas is less than or equal to 500 mg/m 3 .

2. The method according to claim 1 , wherein the CO catalytic regenerative heat exchange device comprises a heat exchange device shell, and the CO heat-regenerative catalyst and a heat exchange element which are provided inside the heat exchange device shell;
a guide bearing inside a central axis of the CO catalytic regenerative heat exchange device, and the CO heat-regenerative catalyst and the heat exchange element are allowed to rotate around the guide bearing.

3. The method according to claim 2 , wherein the heat exchange element is arranged lower than the CO heat-regenerative catalyst.

4. The method according to claim 1 , wherein an SCR denitration catalyst is arranged in the medium/low-temperature SCR denitration reaction device.

5. The method according to claim 1 , wherein a CO concentration in the sintering flue gas is 6000-12000 mg/Nm 3 .

6. The method according to claim 5 , wherein the CO concentration in the sintering flue gas is 8000-12000 mg/Nm 3 .

7. The method according to claim 1 , wherein a catalyst for the SCR denitration reaction in step (2) comprises a vanadium-tungsten-titanium catalyst and/or a vanadium-molybdenum-titanium catalyst.

8. The method according to claim 1 , wherein a catalyst for the SCR denitration reaction in step (2) is V 2 O 5 —WO 3 /TiO 2 and/or V 2 O 5 —MoO 3 /TiO 2 .

Assignees

• Inst Process Eng Cas

Inventors

• Zhu Tingyu
• Liu Xiaolong
• Zou Yang

Classifications

• B01J23/30

  Tungsten · CPC title

• B01J21/16

  Clays or other mineral silicates · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title

• B01D2259/65

  Employing advanced heat integration, e.g. Pinch technology · CPC title

• B01D2259/124

  Liquid reactants · CPC title