Internal configuration for redox-based heat storage systems

Patent metadata

Field	Value
Publication number	US-12298084-B2
Application number	US-202117906306-A
Country	US
Kind code	B2
Filing date	Mar 19, 2021
Priority date	Mar 19, 2020
Publication date	May 13, 2025
Grant date	May 13, 2025

Abstract

The invention is directed to a system for energy storage comprising a chemical combustion reactor comprising a reactor segment that comprises at least two porous active fixed beds that are separated by an inactive insulating layer which are at least partially surrounded by an insulating mantle. The active beds comprise a metal and/or oxide thereof.

First claim

The invention claimed is:

1. A system for energy storage comprising a chemical combustion reactor ( 1 ) wherein a flow path ( 2 ) is provided in a longitudinal direction of said reactor, said reactor comprising a reactor segment ( 3 ) that comprises at least two porous active fixed beds ( 4 ) placed in the flow path, said porous active fixed beds comprising a metal and/or oxide thereof, wherein said at least two porous active fixed beds ( 4 ) comprising a metal and/or oxide thereof are configured for said metal and/or oxide thereof to undergo oxidation and reduction reactions, wherein said porous active fixed beds are separated by a porous inactive insulating layer ( 5 ), and wherein said porous active fixed beds and said porous inactive insulating layer are at least partially directly surrounded by an insulating mantle ( 6 ) in the longitudinal direction of said reactor, wherein said insulating mantle is surrounded by a reactor wall.

2. System according to claim 1 , wherein said reactor segment ( 3 ) comprises a support structure ( 7 ) that is longitudinally aligned in the direction of said reactor and comprised between said porous inactive insulating layer and said reactor wall, wherein said support structure comprises a fixation element ( 8 ) that is adapted for supporting said at least two porous active beds ( 4 ).

3. System according to claim 1 , further comprising one or more heaters ( 9 ), located in the chemical combustion reactor ( 1 ) such that they said one or more heaters are thermally connected to at least one of said porous active fixed beds ( 4 ).

4. System according to claim 1 , further comprising a temperature sensor ( 10 ), located in the chemical combustion reactor ( 1 ) and adapted to measure a representative temperature of at least one of said porous active fixed beds ( 4 ).

5. System according to claim 1 , wherein both reduction and oxidation reactions of said metal and/or oxide thereof are exothermic.

6. System according to claim 1 , wherein said metal and/or oxide thereof comprises a metal element selected from the group consisting of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Zr, Sn and combinations thereof.

7. System according to claim 1 , wherein said porous active fixed beds ( 4 ) further comprise platinum and/or palladium.

8. System according to claim 1 , wherein said porous active fixed beds ( 4 ) individually have a porosity between 40-85%, expressed as the percentage void based on the total volume occupied by the active bed.

9. System according to claim 1 , wherein said porous insulating layer ( 5 ) comprises an inactive material with lower thermal conductivity than said metal and/or oxide thereof.

10. System according to claim 1 , wherein said porous insulating layer ( 5 ) has a porosity of up to 90%, expressed as the percentage void of the total volume occupied by the insulating layer.

11. System according to claim 1 , wherein said insulating mantle ( 6 ) comprises a compressible material that after compression at least partially decompresses to its initial shape, and wherein said insulating mantle has a higher gas-flow resistance than each of said active beds.

12. A cartridge ( 11 ) for use in the system according to claim 1 , comprising a reactor segment ( 3 ), and a support structure for supporting said reactor segment, wherein said cartridge is adapted to be removable from and stackable within the chemical combustion reactor ( 1 ).

13. Method for storing energy in the system according to claim 1 , said method comprising providing a reducing gas stream, the reducing gas stream being a reducing gas stream comprising hydrogen gas, and leading said reducing gas stream into the chemical combustion reactor ( 1 ) and allowing the reducing gas stream to react with a metal oxide in the chemical combustion reactor to reduce the metal oxide.

14. Method for discharging energy from the system according to claim 1 , said method comprising providing an oxidizing gas stream, the oxidizing gas stream comprising oxygen gas, and leading said oxidizing gas stream into the chemical combustion reactor ( 1 ) and allowing the oxidizing gas stream to react with a metal in the chemical combustion reactor to oxidize the metal.

15. System according to claim 1 , wherein said reactor segment ( 3 ) comprises a support structure ( 7 ), wherein said support structure comprises a fixation element ( 8 ) that is adapted for supporting at least said porous active fixed beds ( 4 ) and said insulating layer ( 5 ) in the chemical combustion reactor ( 1 ).

16. System according to claim 1 , further comprising one or more heaters ( 9 ) located in the chemical combustion reactor ( 1 ) such that said one or more heaters are thermally connected to at least one of the porous active fixed beds ( 4 ), wherein said one or more heaters comprise a heating element penetrating the porous active fixed bed it is thermally connected to.

17. System according to claim 1 , further comprising a temperature sensor ( 10 ), located in the chemical combustion reactor ( 1 ) and adapted to measure a representative temperature of at least one of the porous active fixed beds ( 4 ), wherein said temperature sensor comprises a sensor element penetrating the porous active fixed bed for which the temperature sensor is adapted to measure the temperature of.

18. System according to claim 1 , wherein said porous insulating layer ( 5 ) comprises an inactive material that comprises stainless steel.

19. System according to claim 1 , wherein said insulating mantle ( 6 ) comprises a compressible material that, after compression, completely decompresses to its initial shape, and wherein said insulating mantle has a higher gas-flow resistance than each of said active beds.

20. System according to claim 1 , wherein said metal and/or oxide thereof comprises copper.

Assignees

• TNO

Inventors

• Van Vliet Laurens Daniël
• Mohana Martin
• Veronezi Figueiredo Roberta
• Bodis Pavol
• Cuypers Ruud
• Geers Leonard Ferdinand Gerard
• Kalkman Arie Jacobus

Classifications

• B01J2208/00495

  using insulating materials or refractories · CPC title

• B01J2208/00398

  inside the reactor bed · CPC title

• B01J8/0496

  Heating or cooling the reactor · CPC title

• B01J8/0453

  the beds being superimposed one above the other · CPC title

• Y02E60/14

  Thermal energy storage · CPC title