Method for manufacturing a decorative foil and a panel comprising such foil

Patent metadata

Field	Value
Publication number	US-12296608-B2
Application number	US-202017427846-A
Country	US
Kind code	B2
Filing date	Jan 30, 2020
Priority date	Feb 5, 2019
Publication date	May 13, 2025
Grant date	May 13, 2025

Abstract

A method for manufacturing a decorative foil may involve providing a thermoplastic carrier layer. An ink receiving layer may be provided to the carrier layer. A decorative pattern may be formed on the carrier layer by performing a digital printing operation wherein droplets of aqueous inks having a volume smaller than 100 pL are jet to the carrier layer, more particularly to the ink receiving. The ink receiving layer may comprise a binding agent, preferably different from an acrylic copolymer, and/or silica.

First claim

The invention claimed is:

1. A method for manufacturing a decorative foil, the method comprising:
providing a thermoplastic carrier layer;
providing an ink receiving layer to the carrier layer; and
forming a decorative pattern on the carrier layer by performing a digital printing operation wherein droplets of an aqueous ink having a volume smaller than 100 pL are jet to the ink receiving layer;
wherein the ink receiving layer comprises a binding agent; and
wherein the aqueous ink comprises a terpolymer of vinyl chloride, vinyl acetate and ethylene as a binding agent.

2. The method of claim 1 , wherein the binding agent of the ink receiving layer is the same as the binding agent of the aqueous ink.

3. The method of claim 1 , wherein the ink receiving layer comprises silica pigments having a BET value lower than 350 m 2 /g.

4. The method of claim 1 , wherein the ink receiving layer comprises from 25% to 75% by weight of silica pigments.

5. The method of claim 1 , wherein the ink receiving layer comprises pigments and binder with a pigment to binder ratio of 0.85 or more.

6. The method of claim 1 , wherein the ink receiving layer has a pH of less than 6.

7. The method of claim 1 , wherein the ink receiving layer comprises a cationic flocculating agent.

8. The method of claim 1 , wherein the ink receiving layer comprises citric acid.

9. The method of claim 1 , wherein providing the ink receiving layer to the carrier layer comprises,
a first substep wherein a first substance including pigment and binder is applied to the carrier layer, and
a second substep wherein a second substance including at least binder is applied to the carrier layer and the pigment to binder ratio of the second substance applied in the second substep is lower than the pigment to binder ratio of the first substance applied in the first substep.

10. The method of claim 1 , wherein the ink receiving layer comprises at least a cationic binding agent.

11. The method of claim 1 , wherein the ink receiving layer comprises a waterborne aliphatic polyurethane dispersion as the binding agent.

12. The method of claim 1 , wherein the ink receiving layer comprises silica pigments having a d50 particle size as determined by the laser light scattering granulometry technique, according to 13320-1, lower than 5.5 micrometer.

13. The method of claim 1 , wherein the ink receiving layer comprises silica gel or fumed silica.

14. A method for manufacturing a decorative panel, having a substrate, a decorative pattern provided on a carrier layer and a transparent wear layer, the method comprising:
performing the method of claim 1 to provide a decorative foil; and
laminating the wear layer on top of the decorative foil.

Assignees

• Unilin Bv

Inventors

• Clement Benjamin
• Ledegen Sam

Classifications

• B41M5/5281

  Polyurethanes or polyureas · CPC title

• B41M5/5218

  characterised by inorganic additives, e.g. pigments, clays · CPC title

• B41M5/0064

  on plastics, horn, rubber, or other organic polymers · CPC title

• B41M5/0047

  by ink-jet printing · CPC title

• B32B2451/00

  Decorative or ornamental articles · CPC title