Flux-cored wire and welding method

Patent metadata

Field	Value
Publication number	US-12296411-B2
Application number	US-202017620211-A
Country	US
Kind code	B2
Filing date	Jun 9, 2020
Priority date	Jun 20, 2019
Publication date	May 13, 2025
Grant date	May 13, 2025

Abstract

A flux-cored wire comprising a flux which is a core and a hoop which is an outer skin or sheath is described. The flux includes a strong deoxidizing metal element containing Mg and Al, and a fluoride powder. At least 60 mass % of a strong deoxidizing metal powder related to the strong deoxidizing metal element has a grain size of at most 150 μm. At least 60 mass % of the fluoride powder has a grain size of at most 75 μm. The flux is present at a concentration of 10-30 mass % relative to a total mass of the flux-cored wire. The flux-cored wire also requires a specific composition of elements.

First claim

The invention claimed is:

1. A flux-cored wire comprising a flux and a hoop, the flux forming a core, the hoop forming a sheath, wherein:
the flux comprises strong deoxidizing metal elements (flux) and at least one fluoride powder, and the strong deoxidizing metal elements (flux) include Mg and Al,
a total content of the strong deoxidizing metal elements (flux) is 15 to 35 mass % relative to a total mass of the flux,
at least a portion of the Mg and the Al of the strong deoxidizing metal elements (flux) is present as a strong deoxidizing metal powder, and the strong deoxidizing metal powder is at least one of a metal powder or an alloy powder,
60 mass % or more of the strong deoxidizing metal powder has a particle size of less than or equal to 150 μm,
a total content of the at least one fluoride powder is 10 to 45 mass % relative to the total mass of the flux,
60 mass % or more of the at least one fluoride powder has a particle size of less than or equal to 75 μm,
the flux is present in an amount of 10 to 30 mass %, relative to a total mass of the flux-cored wire, and
the flux-cored wire comprises, relative to the total mass of the flux-cored wire:
C: 0.5 mass % or less;
Si: 0.05 to 1.0 mass %;
Al: 1.0 to 3.5 mass %;
Mn: 1.0 to 3.0 mass %;
Mg: 0.3 to 0.9 mass %;
a total of at least one fluoride, in an amount F calculated in terms of fluorine: 0.30 to 1.20 mass %; and
a total of strong deoxidizing metal elements (wire) : 2.2 mass % or greater.

2. The flux-cored wire according to claim 1 , wherein the flux-cored wire further comprises, relative to the total mass of the flux-cored wire:
Ni: 15 mass % or less;
Mo: 5.0 mass % or less;
W: 3.0 mass % or less;
Nb: 5.0 mass % or less;
V: 5.0 mass % or less;
Cr: 30 mass % or less;
Ti: 3.0 mass % or less;
Zr: 2.0 mass % or less;
O: 0.05 mass % or less;
N: 0.05 mass % or less;
S: 0.05 mass % or less;
P: 0.05 mass % or less;
B: 0.05 mass % or less;
Cu: 5.0 mass % or less;
Ba: 5.0 mass % or less;
a total of at least one alkali metal element: 3.0 mass % or less;
Ca: 3.0 mass % or less;
a total of at least one rare earth metal: 0.5 mass % or less; and
Fe: 40 mass % or greater.

3. The flux-cored wire according to claim 1 , wherein the fluoride powder is at least one powder of a compound selected from the group consisting of BaF 2 , SrF 2 , Na 3 AlF 6 , NaF, MgF 2 , and CaF 2 .

4. The flux-cored wire according to claim 2 , wherein the fluoride powder is at least one powder of a compound selected from the group consisting of BaF 2 , SrF 2 , Na 3 AlF 6 , NaF, MgF 2 , and CaF 2 .

5. The flux-cored wire according to claim 1 , wherein
a water content (WC) is 0.010 to 0.100 mass % relative to the total mass of the flux-cored wire, and
the water content (WC) and the total content of the strong deoxidizing metal elements (wire) satisfy a relationship of
105≤(the total content of the strong deoxidizing metal elements (wire) /WC)≤170.

6. The flux-cored wire according to claim 1 , wherein the content of Al and the content of Mg, relative to the total mass of the flux-cored wire, satisfy a relationship of
0.35≤(2×Mg/0.6×Al≤1.50.

7. The flux-cored wire according to claim 1 , wherein the strong deoxidizing metal elements (flux) further comprise at least one element selected from the group consisting of Zr, Ti, and Ca, and
wherein the contents of Mg, Al, Zr, Ti, and Ca, relative to the total mass of the flux-cored wire, satisfy a relationship of 5≤{(Mg+Al/(Zr+Ti+Ca)}≤70.

8. The flux-cored wire according to claim 1 , wherein the flux further comprises Ni in the form of at least one selected from the group consisting of elemental Ni, Cu—Ni, Fe—Ni, and Ni—Mg.

9. A gas shielded arc welding method, comprising welding with the flux-cored wire according to claim 1 at a welding current of greater than 200 A in a shielding gas atmosphere.

10. The gas shielded arc welding method according to claim 9 , wherein the welding is performed in a welding position, and the welding position is at least one of an overhead position or a vertical position.

11. The gas shielded arc welding method according to claim 9 , wherein the shielding gas comprises 70 vol % or more Ar.

12. The gas shielded arc welding method according to claim 9 , wherein the shielding gas comprises 70 vol % or more CO 2 .

Assignees

• Kobe Steel Ltd

Inventors

• Ishizaki Keito
• Yashima Takashi
• Izutani Shun

Classifications

• C22C38/58

  with more than 1.5% by weight of manganese · CPC title

• C22C38/50

  with titanium or zirconium · CPC title

• C22C38/48

  with niobium or tantalum · CPC title

• C22C38/44

  with molybdenum or tungsten · CPC title

• C22C38/42

  with copper · CPC title