Isotopologue or isotope enrichment via preferential condensation of isotopologues or isotopes under non-equilibrium gas-surface collision conditions

Patent metadata

Field	Value
Publication number	US-12296299-B2
Application number	US-202217728453-A
Country	US
Kind code	B2
Filing date	Apr 25, 2022
Priority date	Apr 30, 2021
Publication date	May 13, 2025
Grant date	May 13, 2025

Abstract

Provided are apparatus and methods for enriching and separating isotopologues or isotopes. The apparatus and methods enrich and/or separate isotopes or isotopologues present in a substantially monovelocity supersonic beam incident upon a solid surface comprising condensed forms of the isotopologues or the isotopes via the differential condensation of the different isotopologues or isotopes on the surface or the differential reflection of the different isotopologues or isotopes from the surface.

First claim

What is claimed is:

1. A method for enriching isotopologues or isotopes or for separating isotopologues or isotopes, the method comprising:
forming a supersonic beam comprising: a mixture of a first isotopologue of a first molecule and a second, heavier isotopologue of the first molecule; or a first isotope of a first element and a second, heavier isotope of the first element;
directing the supersonic beam onto the surface of a substrate to form a multilayered condensed film having a steady-state composition of the first and second isotopologues or the first and second isotopes, wherein the incident velocity of the supersonic beam and the ratio of the first and second isotopologues, or the ratio of the first and second isotopes, in the supersonic beam are selected such that the condensed film has a phonon density of states that results in preferential condensation of the second isotopologue or the second isotope, relative to the first isotopologue or the first isotope; and
collecting the condensed isotopologues or the condensed isotopes from the condensed film.

2. The method of claim 1 , wherein the supersonic beam comprises the mixture of the first isotopologue of the first molecule and the second, heavier isotopologue of the first molecule and further wherein the incident velocity of the supersonic beam and the ratio of the first and second isotopologues in the supersonic beam are selected such that the condensed film has the phonon density of states and a rovibrational density of states that result in the preferential condensation of the second isotopologue.

3. The method of claim 2 , wherein the molar ratio of the second isotopologue to the first isotopologue in the supersonic beam differs from the naturally occurring molar ratio of the second isotopologue to the first isotopologue.

4. The method of claim 3 , wherein the molar ratio of the second isotopologue to the first isotopologue in the supersonic beam is greater than the naturally occurring molar ratio of the second isotopologue to the first isotopologue.

5. The method of claim 4 , wherein the molar ratio of the second isotopologue to the first isotopologue in the supersonic beam is at least ten times greater than the naturally occurring molar ratio of the second isotopologue to the first isotopologue.

6. The method of claim 4 , wherein the molar ratio of the second isotopologue to the first isotopologue in the supersonic beam is at least one thousand times greater than the naturally occurring molar ratio of the second isotopologue to the first isotopologue.

7. The method of claim 1 , wherein the supersonic beam comprises the mixture of the first isotope of the first atom and the second, heavier isotope of the first atom and the atomic ratio of the second isotope to the first isotope in the supersonic beam differs from the naturally occurring atomic ratio of the second isotope to the first isotope.

8. The method of claim 7 , wherein the atomic ratio of the second isotope to the first isotope in the supersonic beam is greater than the naturally occurring atomic ratio of the second isotope to the first isotope.

9. The method of claim 7 , wherein the atomic ratio of the second isotope to the first isotope in the supersonic beam is at least ten times greater than the naturally occurring atomic ratio of the second isotope to the first isotope.

10. The method of claim 7 , wherein the first and second isotopes are isotopes of silicon.

11. The method of claim 7 , wherein the first and second isotopes are isotopes of carbon.

Assignees

• Univ Chicago

Inventors

• Sibener Steven J
• Brann Michelle R
• Hansknecht Stephen P

Classifications

• B01D59/02 Primary

  Separation by phase transition · CPC title

• B01D59/34 Primary

  Separation by photochemical methods · CPC title