System and method for monitoring a reactor system using optical fiber based sensors

Patent metadata

Field	Value
Publication number	US-12294124-B2
Application number	US-202217659672-A
Country	US
Kind code	B2
Filing date	Apr 19, 2022
Priority date	Aug 20, 2014
Publication date	May 6, 2025
Grant date	May 6, 2025

Abstract

A method of monitoring operation of a reactor system includes causing a chemical reaction to occur within an assembly of the reactor system, and measuring a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly using a sensor system structured to implement distributed sensing. The sensor system includes an optical fiber sensing member provided at least partially within the assembly, wherein the optical fiber sensing member comprises a functionalized optical fiber based sensor device structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

First claim

What is claimed is:

1. A method of monitoring operation of a reactor system, comprising:
causing a chemical reaction to occur within an assembly of the reactor system, wherein the reactor system is structured to operate at a high temperature ranging from 500° C. to 1000° C., the reactor system having a sensor system structured to implement distributed sensing that includes an optical fiber sensing member at least partially provided therein, wherein the optical fiber sensing member includes a monolithic in-fiber sensing element positioned inside the reactor assembly, wherein the monolithic in-fiber sensing element is structured to provide stable sensing at high temperatures ranging from 500° C. to 1000° C.; and
measuring at high temperatures ranging from 500° C. to 1000° C. and at a plurality of sensing locations along the monolithic in-fiber sensing element using a scattering based interrogation approach and without employing a plurality of in-fiber optic components in a core of the optical sensing member a chemical composition of one or more reactants of the chemical reaction with spatial resolution at the plurality of sensing locations, wherein the monolithic in-fiber sensing element is structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants.

2. The method according to claim 1 , wherein the scattering based interrogation approach is a back scattering based interrogation approach.

3. The method according to claim 1 , wherein the reactor system is a solid oxide fuel cell system.

4. The method according to claim 1 , further comprising measuring a temperature at each of the plurality sensing locations using the monolithic in-fiber sensing element.

5. A reactor system structured to operate at a high temperature ranging from 500° C. to 1000° C., comprising:
an assembly structured to enable a chemical reaction to occur therein; and
a sensor system structured to implement distributed sensing and measure a chemical composition of one or more reactants of the chemical reaction with spatial resolution at a plurality of points along a path within the assembly, the sensor system including an optical fiber sensing member including a monolithic in-fiber sensing element positioned inside the assembly, wherein the monolithic in-fiber sensing element is structured to exhibit a change in one or more optical properties in response to changes in the chemical composition of the one or more reactants and is structured to provide stable sensing at high temperatures ranging from 500° C. to 1000° C.;
wherein the sensor system is structured to implement distributed sensing along the path at a plurality of sensing locations along the monolithic in-fiber sensing element using a scattering based interrogation approach and without employing a plurality of in-fiber optic components in a core of the optical fiber sensing member such that the sensing system is configured to measure the chemical composition of the one or more reactants with spatial resolution at the plurality of sensing locations.

6. The reactor system according to claim 5 , wherein the sensor system is further structured to measure a temperature at the plurality of sensing locations.

7. The reactor system according to claim 5 , wherein the scattering based interrogation approach is a back scattering based interrogation approach.

8. The reactor system according to claim 5 , wherein the optical fiber sensing member includes an optical fiber member provided within a packaging assembly.

9. The reactor system according to claim 8 , wherein the packaging assembly comprises a tubing member.

10. The reactor system according to claim 9 , wherein the tubing member comprises a first tubing member provided within a second tubing member.

11. The reactor system according to claim 10 , wherein the first tubing member is an alumina tubing member and the second tubing member is a nickel tubing member.

12. The reactor system according to claim 11 , wherein the tubing member includes a plurality of openings along a length thereof to enable gas to pass through the tubing member.

13. The method according to claim 5 , wherein the reactor system is a solid oxide fuel cell system.

Assignees

• Univ Pittsburgh Commonwealth Sys Higher Education
• United States Depatment Of Energy
• Univ Of Pittsburgh—Of The Commonwealth System Of Higher Education

Inventors

• Chen Peng K
• Poole Jacob Lorenzi
• Ohodnicki Paul R
• Brown Thomas D
• Gerdes Kirk R
• Buric Michael P

Classifications

• H01M8/2425

  High-temperature cells with solid electrolytes · CPC title

• H01M8/02

  Details (electrodes H01M4/86 - H01M4/98) · CPC title

• H01M8/12

  operating at high temperature, e.g. with stabilised ZrO2 electrolyte · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/04455

  of cathode reactants at the inlet or inside the fuel cell · CPC title