Cathode material, and electrochemical device including the same

Patent metadata

Field	Value
Publication number	US-12294085-B2
Application number	US-202418428051-A
Country	US
Kind code	B2
Filing date	Jan 31, 2024
Priority date	Jul 19, 2019
Publication date	May 6, 2025
Grant date	May 6, 2025

Abstract

A cathode material includes a plurality of first particles. Each first particle includes a secondary particle composed of a plurality of third particles, and the first particle includes a first lithium-containing transition metal oxide; and a plurality of second particles. The second particle includes a fourth particle and/or a secondary particle composed of a plurality of fourth particles, and the second particle includes a second lithium-containing transition metal oxide. The electrochemical device including the cathode material is significantly improved in the aspects of energy density, capacity attenuation and service life.

First claim

What is claimed is:

1. A cathode material, comprising:
a plurality of first particles, wherein each first particle comprises a secondary particle composed of a plurality of third particles, each third particle is a first primary particle, the plurality of first particles have an average particle diameter of 8 μm to 20 μm, the plurality of third particles have an average particle diameter of 200 nm to 700 nm, and the each first particle comprises a first lithium-containing transition metal oxide; and
a plurality of second particles, wherein each second particle comprises a fourth particle and/or a secondary particle composed of a plurality of fourth particles, each fourth particle is a second primary particle, the plurality of second particles have an average particle diameter of 3 μm to 5 μm, the plurality of fourth particles have an average particle diameter of 800 nm to 5 μm, and the each second particle comprises a second lithium-containing transition metal oxide;
wherein a peak intensity ratio of the (003) diffraction peak of the X-ray diffraction of the second particles to that of the first particles is 1.03 to 1.6, a difference between full width at half maximum of the (003) diffraction peak of the X-ray diffraction of the first particles and that of the second particles being 0.003° to 0.008°.

2. The cathode material according to claim 1 , wherein the each first particle comprises 150 to 2000 third particles, the each second particle is a secondary particle, and the each second particle comprises 2 to 100 fourth particles.

3. The cathode material according to claim 1 , wherein a ratio of the average particle diameter of the plurality of first particles to the average particle diameter of the plurality of third particles is 20 to 50.

4. The cathode material according to claim 1 , wherein a ratio D s /D p is 0.15 to 0.7, D s is the average particle diameter of the plurality of second particles, and D p is the average particle diameter of the plurality of first particles.

5. The cathode material according to claim 1 , wherein a mass percentage of the second particles in the cathode material is 5% to 50%.

6. The cathode material according to claim 1 , wherein the plurality of first particles have a specific surface area of 0.10 m 2 /g to 1.50 m 2 /g, and the plurality of second particles have a specific surface area of 0.30 m 2 /g to 2.50 m 2 /g.

7. The cathode material according to claim 1 , wherein the first lithium-containing transition metal oxide has the general formula of Li α Ni x Co y M1 z N1 β O 2 , wherein 0.95≤α≤1.05, 0.5≤x<1, 0<y<0.4, 0<z<0.4, 0≤β≤0.05, and x+y+z+β=1, M1 is at least one selected from Mn or Al, and N1 is at least one selected from Mg, Ti, Zr, Nb, Y, Cr, V, Ge, Mo or Sr.

8. The cathode material according to claim 7 , wherein a surface of the first lithium-containing transition metal oxide further comprises a first coating element and a boron element, the first coating element is at least one selected from Al, La, Y, Zr, Ti, Ce or F; and based on the total molar amount of the transition metal elements in the first lithium-containing transition metal oxide, a molar percentage of the first coating element is 0.1% to 0.5%, and a molar percentage of the boron element is 0.1% to 0.5%.

9. The cathode material according to claim 1 , wherein the second lithium-containing transition metal oxide has the general formula of Li a Ni a Co b M2 c N2 d O 2 , wherein 0.95≤n≤1.05, 0.5≤a<1, 0<b<0.4, 0<c<0.4, 0≤d≤0.02, and a+b+c+d=1, M2 is at least one selected from Mn or Al, and N2 is at least one selected from Mg, Ti, Zr, Nb, Y, Cr, V, Ge, Mo or Sr.

10. The cathode material according to claim 9 , wherein a surface of the second lithium-containing transition metal oxide further comprises a boron element, and based on the total molar amount of the transition metal elements in the second lithium-containing transition metal oxide, a molar percentage of the boron element is 0.1% to 0.5%.

11. An electrochemical device, comprising a cathode, wherein the cathode comprises a cathode material, wherein the cathode material comprises:
a plurality of first particles, wherein each first particle comprises a secondary particle composed of a plurality of third particles, each third particle is a first primary particle, the plurality of first particles have an average particle diameter of 8 μm to 20 μm, the plurality of third particles have an average particle diameter of 200 nm to 700 nm, and the each first particle comprises a first lithium-containing transition metal oxide; and
a plurality of second particles, wherein each second particle comprises a fourth particles and/or a secondary particle composed of a plurality of fourth particles, each fourth particle is a second primary particle, the plurality of second particles have an average particle diameter of 3 μm to 5 μm, the plurality of fourth particles have an average particle diameter of 800 nm to 5 μm, and the each second particle comprises a second lithium-containing transition metal oxide;
wherein a peak intensity ratio of the (003) diffraction peak of the X-ray diffraction of the second particles to that of the first particles is 1.03 to 1.6, a difference between full width at half maximum of the (003) diffraction peak of the X-ray diffraction of the first particles and that of the second particles being 0.003° to 0.008°.

12. The electrochemical device according to claim 11 , wherein the each first particle comprises 150 to 2000 third particles, the each second particle is a secondary particle, and the each second particle comprises 2 to 100 fourth particles.

13. The electrochemical device according to claim 11 , wherein a ratio of the average particle diameter of the plurality of first particles to the average particle diameter of the plurality of third particles is 20 to 50.

14. The electrochemical device according to claim 11 , wherein a ratio D s /D p is 0.15 to 0.7, D s is the average particle diameter of the plurality of second particles, and D p is the average particle diameter of the plurality of first particles.

15. The electrochemical device according to claim 11 , wherein a mass percentage of the second particles in the cathode material is 5% to 50%.

16. The electrochemical device according to claim 11 , wherein the plurality of first particles have a specific surface area of 0.10 m 2 /g to 1.50 m 2 /g, and the plurality of second particles have a specific surface area of 0.30 m 2 /g to 2.50 m 2 /g.

17. The electrochemical device according to claim 11 , wherein the first lithium-containing transition metal oxide has the general formula of Li α Ni x Co y M1 z N1 β O 2 , wherein 0.95≤α≤1.05, 0.5≤x<1, 0<y<0.4, 0<z<0.4, 0≤β≤0.05, and x+y+z+β=1, M1 is at least one selected from Mn or Al, and N1 is at least one selected from Mg, Ti, Zr, Nb, Y, Cr, V, Ge, Mo or Sr, a surface of the first lithium-containing transition metal oxide further comprises a first coating element and a boron element, the first coating element is at least one selected from Al, La, Y, Zr, Ti, Ce or F; and based on the total molar amount of the transition metal elements in the first lithium-containing transition metal oxide, a molar percentage of the first coating element is 0.1% to 0.5%, and a molar percentage of the boron element is 0.1% to 0.5%.

18. The electrochemical device according to claim 17 , wherein the second lithium-containing transition metal oxide has the general formula of Li n Ni a Co b M2 c N2 d O 2 , wherein 0.95≤n≤1.05, 0.5≤a<1, 0<b<0.4, 0<c<0.4, 0≤d≤0.02, and a+b+c+d=1, M2 is at least one selected from Mn or Al, and

Assignees

• Ningde Amperex Technology Ltd

Inventors

• Liu Wenyuan
• Peng Gang
• Lang Ye
• Xu Leimin

Classifications

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/505

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/364 Primary

  as mixtures · CPC title