Making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies and battery cells

Patent metadata

Field	Value
Publication number	US-12294051-B2
Application number	US-202217654648-A
Country	US
Kind code	B2
Filing date	Mar 14, 2022
Priority date	Dec 2, 2014
Publication date	May 6, 2025
Grant date	May 6, 2025

Abstract

A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery by providing a high degree of lithium ion conductivity while being highly resistant to the initiation and/or propagation of lithium dendrites. Such an electrolyte is also itself manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner. An automated machine based system, apparatus and methods assessing and inspecting the quality of such vitreous solid electrolyte sheets, electrode sub-assemblies and lithium electrode assemblies can be based on spectrophotometry and can be performed inline with fabricating the sheet or web (e.g., inline with drawing of the vitreous Li ion conducting glass) and/or with the manufacturing of associated electrode sub-assemblies and lithium electrode assemblies and battery cells.

First claim

What is claimed is:

1. A Li ion conductive vitreous sulfide glass sheet in the form of a mother-sheet having a high-quality center portion, with uniform thickness and smooth liquid-like surfaces, and lower quality peripheral edge portions, which generally extend along its lengthwise dimension.

2. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the low-quality peripheral edge portions are removed by slicing.

3. The Li ion conductive vitreous sulfide glass sheet of claim 2 , wherein the low-quality peripheral edge portions are removed by laser cutting.

4. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the high-quality center portion accounts for at least 50% of the mother-sheet's footprint/area.

5. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the high-quality center portion accounts for at least 60% of the mother-sheet's footprint/area.

6. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the high-quality center portion accounts for at least 70% of the mother-sheet's footprint/area.

7. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the high-quality center portion accounts for at least 80% of the mother-sheet's footprint/area.

8. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the high-quality center portion accounts for at least 90% of the mother-sheet's footprint/area.

9. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the major opposing surfaces of the high-quality center portion of the mother-sheet has an average surface roughness R a <1.0 mm.

10. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the high-quality center portion of the mother-sheet has thin uniform thickness≤100 mm.

11. The Li ion conductive vitreous sulfide glass sheet of claim 1 , wherein the mother-sheet is fabricated as a mother-web having a high-quality center portion and once the lower quality edge portions of the mother-web are sliced off the glass sheet is rolled to form a supply roll.

Assignees

• Polyplus Battery Co Inc

Inventors

• Visco Steven J
• Nimon Yevgeniy S
• De Jonghe Lutgard C
• Katz Bruce D
• Nimon Vitaliy

Classifications

• H01M50/437

  Glass · CPC title

• H01M50/406

  Moulding; Embossing; Cutting · CPC title

• H01M50/403

  Manufacturing processes of separators, membranes or diaphragms · CPC title

• H01M50/46

  Separators, membranes or diaphragms characterised by their combination with electrodes · CPC title

• G01N21/8422

  Investigating thin films, e.g. matrix isolation method · CPC title