Method for manufacturing nickel and cobalt-containing solution from hydroxide containing nickel and cobalt

Patent metadata

Field	Value
Publication number	US-12291762-B2
Application number	US-202017437588-A
Country	US
Kind code	B2
Filing date	Mar 16, 2020
Priority date	Mar 26, 2019
Publication date	May 6, 2025
Grant date	May 6, 2025

Abstract

A method of manufacturing a cobalt-nickel-containing solution including: preparing a crude nickel hydroxide and/or a crude cobalt hydroxide as a starting material, the crude nickel or cobalt hydroxide containing cobalt and nickel and elements except the cobalt and nickel as impurities, the crude nickel hydroxide containing the nickel more than the cobalt, and the crude cobalt hydroxide containing the cobalt more than the nickel; a water-washing process for obtaining a post-water-washing crude hydroxide from the starting material; a leaching process for obtaining a post-leaching solution from the post-water-washing crude hydroxide; a neutralization process of subjecting the post-leaching solution to neutralization and solid-liquid-separation to remove the impurities as a post-neutralization residue containing one or more of iron, silicon, aluminum, and chromium, thereby obtaining a post-neutralization solution; and an extraction process of subjecting the post-neutralization solution to solvent extraction to obtain a post-extraction solution containing cobalt and nickel with the impurities reduced.

First claim

The invention claimed is:

1. A method of manufacturing a cobalt-nickel-containing solution, the method comprising:
preparing at least one of a crude nickel hydroxide and a crude cobalt hydroxide as a starting material,
the crude nickel hydroxide containing cobalt and nickel, and one or more elements of magnesium, calcium, iron, silicon, manganese, zinc, copper, aluminum, and chromium other than the cobalt and nickel as impurities, and containing the nickel more than the cobalt, and
the crude cobalt hydroxide containing cobalt and nickel, and one or more elements of magnesium, calcium, iron, silicon, manganese, zinc, copper, aluminum, and chromium other than the cobalt and nickel as impurities, and containing the cobalt more than the nickel,
a water-washing process of adding water to the starting material, stirring and mixing it to form a slurry, filtering the slurry to obtain a sediment, washing the sediment with water to reduce one or more of the impurities from the sediment, thereby obtaining a post-water-washing crude hydroxide;
a leaching process of subjecting the post-water-washing crude hydroxide to leaching with an acid to obtain a post-leaching solution containing cobalt and nickel;
a neutralization process of adding a pH adjusting agent the post-leaching solution to perform neutralization, and subjecting it to solid-liquid separation to remove a post-neutralization residue, thereby obtaining a post-neutralization solution;
an extraction process of subjecting the post-neutralization solution obtained to solvent extraction with an extractant, thereby obtaining a post-extraction solution containing both cobalt and nickel with the impurities reduced;
a washing process of back-extracting a part of nickel and cobalt contained in a post-extraction organic phase obtained in the extraction process into an aqueous phase to remove one or more of manganese, magnesium, calcium, zinc, and copper as the impurities into a post-washing organic phase as an organic phase, thereby obtaining a post-washing solution as the aqueous phase containing nickel and cobalt with the impurities reduced; and
a back extraction process of further subjecting the post-washing organic phase to back extraction to back-extract manganese, magnesium, calcium, zinc, and copper as the impurities into an aqueous phase and to remove the impurities into a post-back-extraction solution as the aqueous phase, thereby obtaining a post-back-extraction organic phase with the impurities reduced.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ohara Hideki
• Sanjo Shota
• Takano Masatoshi
• Asano Satoshi
• Kobayashi Hiroshi
• SENBA Yusuke
• Watanabe Hiroto

Classifications

• C22B23/043

  Sulfurated acids or salts thereof · CPC title

• C22B3/08

  Sulfuric acid {, other sulfurated acids or salts thereof} · CPC title

• C22B3/38

  containing phosphorus · CPC title

• C01G51/01

  Preparation or separation involving a liquid-liquid extraction, an adsorption or an ion-exchange · CPC title

• C01G53/01

  Preparation or separation involving a liquid-liquid extraction, an adsorption or an ion-exchange · CPC title