Additive manufacturing employing solvent-free polyimide-containing formulations

Patent metadata

Field	Value
Publication number	US-12291603-B2
Application number	US-201816958169-A
Country	US
Kind code	B2
Filing date	Dec 27, 2018
Priority date	Dec 28, 2017
Publication date	May 6, 2025
Grant date	May 6, 2025

Abstract

Formulations usable in additive manufacturing, 3D inkjet printing in particular, of a three-dimensional object that contains a polyimide material, and additive manufacturing utilizing same are provided. The formulations contain a polyimide precursor (e.g., a bismaleimide) and an additional curable material, which is a multifunctional curable material, and are devoid of an organic solvent.

First claim

What is claimed is:

1. A formulation comprising a polyimide precursor and a multifunctional photopolymerizable material, wherein said multifunctional photopolymerizable material is represented by Formula II:

wherein:
X is selected from —O— and —O—C(═O)—;
D is a hydrocarbon chain; and
Rx and Ry are each independently selected from hydrogen, alkyl and cycloalkyl,
wherein a weight ratio of said polyimide precursor and said multifunctional photopolymerizable material in the formulation ranges from 50:50 to 90:10,
the formulation being devoid of an organic solvent and featuring a viscosity of from about 16 to about 20 centipoises at 70° C.

2. The formulation of claim 1 , being devoid of a bis-allyl-nadi-imide compound.

3. The formulation of claim 1 , wherein said polyimide precursor is bismaleimide.

4. The formulation of claim 1 , wherein said polyimide precursor is represented by Formula I:

wherein:
L is a linking moiety; and
R 1 -R 4 are each independently selected from hydrogen, alkyl and cycloalkyl.

5. The formulation of claim 1 , wherein an amount of the multifunctional photopolymerizable material is less than 25 weight percent of the total weight of the formulation.

6. The formulation of claim 1 , usable in additive manufacturing of a three-dimensional object which comprises, in at least a portion thereof, a polyimide-containing material, wherein said additive manufacturing is three-dimensional inkjet printing, the formulation being such that a layer formed thereby during said additive manufacturing undergoes curing within no more than 1 minute.

7. The formulation of claim 1 , wherein said multifunctional photopolymerizable material features a viscosity at room temperature of less than 15 centipoises or less than 10 centipoises; and/or a flash point at least 10° C. higher than a temperature of applied to the formulation during the method.

8. A method of additive manufacturing of a three-dimensional object which comprises, in at least a portion thereof, a polyimide-containing material, the method comprising sequentially forming a plurality of layers in a configured pattern corresponding to the shape of the object, thereby forming the object,
wherein said formation of each of at least a few of said layers comprises dispensing a modeling material formulation which comprises a polyimide precursor and a multifunctional photopolymerizable material;
and exposing each of the dispensed layers to a curing condition to thereby form a cured modeling material comprising said polyimide-containing material,
and wherein:
said modeling material formulation which comprises said polyimide precursor is devoid of an organic solvent; and
said multifunctional photopolymerizable material is represented by Formula II:

wherein:
X is selected from —O— and —O—C(═O)—;
D is a hydrocarbon chain; and
Rx and Ry are each independently selected from hydrogen, alkyl and cycloalkyl,
wherein a weight ratio of said polyimide precursor and said multifunctional photopolymerizable material in the formulation ranges from 50:50 to 90:10.

9. The method of claim 8 , wherein said at least one modeling material formulation which comprises said polyimide precursor is devoid of a bis-allyl-nadi-imide compound.

10. The method of claim 8 , wherein a viscosity of said modeling material formulation containing said polyimide precursor is from about 16 to about 20 centipoises at 70° C.

11. The method of claim 8 , wherein said polyimide precursor is bismaleimide.

12. The method of claim 8 , wherein an amount of said multifunctional photopolymerizable material in said modeling material formulation comprising said polyimide precursor is less than 25 weight percents of the total weight of said formulation.

13. The method of claim 8 , wherein said multifunctional photopolymerizable material features at least one of:
a viscosity at room temperature of less than 15 centipoises or less than 10 centipoises; and
a flash point at least 10° C. higher than a temperature of applied to the formulation during the method.

14. The method of claim 8 , further comprising subjecting the object to thermal treatment.

15. The method of claim 14 , wherein said thermal treatment comprises exposing the object to heat for at least one hour at a temperature of at least 100° C.

Assignees

• Stratasys Ltd

Inventors

• Kuno Lev
• Pokrass Mariana
• Shpayzer Elena

Classifications

• B29K2105/0002

  monomers or prepolymers · CPC title

• B29K2079/08

  PI, i.e. polyimides or derivatives thereof · CPC title

• B29C64/112

  using individual droplets, e.g. from jetting heads · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title