Aqueous polymer dispersion and aqueous coating composition comprising the same

Patent metadata

Field	Value
Publication number	US-12286550-B2
Application number	US-201616461824-A
Country	US
Kind code	B2
Filing date	Dec 19, 2016
Priority date	Dec 29, 2016
Publication date	Apr 29, 2025
Grant date	Apr 29, 2025

Abstract

An aqueous polymer dispersion and an aqueous coating composition comprising the aqueous polymer dispersion, and the aqueous coating composition providing the resulting coatings with good anti-corrosion property.

First claim

What is claimed is:

1. An aqueous polymer dispersion wherein the polymer comprises as polymerized units, based on the weight of the polymer,
(a) from 30% to 50% by weight of styrene,
(b) from 0.2% to 3.0% by weight of phosphoethyl (meth)acrylate,
(c) from 0.2% to 1.2% by weight of a ureido monomer having the following structure:

(d) from 0.5% to 2.5% by weight of a polymerizable surfactant having the following structure:

wherein R 1 is

 m 1 is 1, 2, or 3; and n is an integer in the range of from 3 to 50;
(e) from 30% to 40% by weight of 2-ethylhexyl acrylate; and
(f) from 15% to 30% by weight total of methacrylic acid and cyclohexyl methacrylate;
wherein an aqueous metal protective coating composition derived from the aqueous polymer dispersion exhibits:
a change in Krebs Units (KU) of 10 KU or less after heat aging at 50° C. for 7 days; and
less than 5% rust and a blister rating of “2F” or better as measured in accordance with ASTM D714-02(2009) at a dry film thickness of 50±10 micrometers after 240 hours of exposure to salt spray (5% sodium chloride fog) in accordance with ASTM B-117-11 when coated onto cold rolled steel.

2. The aqueous polymer dispersion of claim 1 wherein the polymer has a glass transition temperature of from 20° C. to 60° C.

3. The aqueous polymer dispersion of claim 1 wherein the polymer comprises as polymerized units, based on the weight of the polymer, from 0.5% to 2.0% by weight of the phosphorous-containing (meth)acrylate.

4. The aqueous polymer dispersion of claim 1 wherein the polymer comprises as polymerized units, based on the weight of the polymer, from 0.5% to 1.0% by weight of the ureido monomer.

5. An aqueous metal protective coating composition comprising the aqueous polymer dispersion of claim 1 .

6. A coated metal substrate prepared by:
applying the aqueous metal protective coating composition of claim 5 to a metal substrate, and
drying the applied aqueous metal protective coating composition or allowing the applied aqueous metal protective coating composition to dry.

7. A method of improving the corrosion resistance of a metal substrate, the method comprising:
applying the aqueous metal protective coating composition of claim 5 to a metal substrate, and
drying the applied aqueous metal protective coating composition or allowing the applied aqueous metal protective coating composition to dry, thereby forming a coating film,
wherein the coating film exhibits less than 5% rust and a blister rating of “2F” or better as measured in accordance with ASTM D714-02(2009) at a dry film thickness of 50±10 micrometers after 240 hours of exposure to salt spray (5% sodium chloride fog) in accordance with ASTM B-117-11.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Shu Shujun
• Wang Yujiang
• Zheng Baoqing
• Tang Jia

Classifications

• C08F220/1808

  C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate · CPC title

• C08F220/1806

  C6-(meth)acrylate, e.g. (cyclo)hexyl (meth)acrylate or phenyl (meth)acrylate · CPC title

• C09D133/064

  containing anhydride, COOH or COOM groups, with M being metal or onium-cation · CPC title

• C09D125/14

  with unsaturated esters · CPC title

• C08F2800/20

  as weight or mass percentages · CPC title