Inkjet ink and primer fluid set

Patent metadata

Field	Value
Publication number	US-12286547-B2
Application number	US-202017757019-A
Country	US
Kind code	B2
Filing date	Dec 9, 2020
Priority date	Dec 18, 2019
Publication date	Apr 29, 2025
Grant date	Apr 29, 2025

Abstract

The present disclosure provides an inkjet ink and primer fluid set containing an aqueous primer composition and aqueous inkjet inks. The aqueous primer composition forms a coating on a print substrate. The inkjet inks contain a polymeric binder that interacts with the primer composition. This fluid set is particularly suitable for printing on non-porous plastic substrate.

First claim

What is claimed is:

1. An inkjet ink and primer fluid set comprising:
a) an aqueous primer composition comprising a multivalent cation salt and a polymeric binder, wherein said composition forms a coating with a dry thickness of from 0.4 to 5.0 micron upon application onto a non-porous plastic substrate, and said coating results in a haze increase of less than 10 on said substrate, said multivalent cation salt is present at an amount less than 20 wt %, based on the total weight of the primer composition, and said polymeric binder is not soluble in water, is stable in the presence of said multivalent cation, and is selected from the group consisting of urethane polymer, acrylic polymer and vinyl polymer;
(b) aqueous inkjet inks, wherein at least one of the inks comprising a pigment dispersion, a first polymeric binder and a second polymeric binder, and wherein said first polymeric binder forms an aggregation with said aqueous primer composition, and said second polymeric binder does not form an aggregation with said aqueous primer composition.

2. The fluid set of claim 1 , wherein said aqueous inkjet inks comprising a white ink and non-white colored inks.

3. The fluid set of claim 1 , wherein said aqueous primer composition further comprising silica particles.

4. The fluid set of claim 1 , wherein said coating results in a haze increase of less than 5 on said substrate.

5. The fluid set of claim 1 , wherein said pigment dispersion is dispersed by an anionic polymeric dispersant.

6. The fluid set of claim 5 , wherein said anionic polymeric dispersant is polyurethane.

7. The fluid set of claim 5 , wherein said anionic polymeric dispersant is acrylic polymer.

8. The fluid set of claim 5 , wherein said anionic polymeric dispersant is different from said first polymeric binder and second polymeric binder.

9. A method of digitally printing an image onto a non-porous plastic substrate comprising the steps of:
(a) providing an inkjet printer that is responsive to digital data signals;
(b) providing a non-porous plastic substrate;
(c) applying an aqueous primer composition comprising a multivalent cation salt and a polymeric binder onto the non-porous plastic substrate to form a coating with a dry thickness of from 0.4 to 5.0 micron, wherein said coating results in a haze increase of less than 10 on said substrate, said multivalent cation salt is present at an amount less than 20 wt %, based on the total weight of the primer composition, and said polymeric binder is not soluble in water, is stable in the presence of said multivalent cation, and is selected from the group consisting of urethane polymer, acrylic polymer and vinyl polymer;
(d) loading the printer with aqueous inkjet inks, wherein at least one of the inks comprising a pigment dispersion, a first polymeric binder and a second polymeric binder, and wherein said first polymeric binder forms an aggregation with said aqueous primer composition, and said second polymeric binder does not form an aggregation with said aqueous primer composition; and
(e) printing onto the primer coated substrate of step (c) using the aqueous inkjet inks in response to digital signals.

10. The method of claim 9 , wherein said aqueous inkjet inks comprising a white ink and non-white colored inks.

11. The method of claim 10 , wherein said digital signals cause said white ink to be printed before said non-white colored inks.

12. The method of claim 10 , wherein said digital signals cause said white ink to be printed after said non-white colored inks.

13. The method of claim 9 , wherein said aqueous primer composition further comprising silica particles.

14. The method of claim 9 , wherein said coating results in a haze increase of less than 5 on said substrate.

15. The method of claim 9 , wherein said pigment dispersion is dispersed by an anionic polymeric dispersant.

16. The method of claim 15 , wherein said anionic polymeric dispersant is polyurethane.

17. The method of claim 15 , wherein said anionic polymeric dispersant is acrylic polymer.

18. The method of claim 9 , wherein said anionic polymeric dispersant is different from said first polymeric binder and second polymeric binder.

Assignees

• Dupont Electronics Inc

Inventors

• Li Xiaoqing
• Huh Ji Yeon
• Kirkpatrick Cullen

Classifications

• C09D11/40

  Ink-sets specially adapted for multi-colour inkjet printing · CPC title

• C09D11/38

  characterised by non-macromolecular additives other than solvents, pigments or dyes · CPC title

• C09D11/322

  Pigment inks · CPC title

• C09D11/54 Primary

  Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink · CPC title

• C09D11/102

  containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds · CPC title