Flame retardant masterbatch composition for foams containing a pH moderator

Patent metadata

Field	Value
Publication number	US-12286520-B2
Application number	US-202418435138-A
Country	US
Kind code	B2
Filing date	Feb 7, 2024
Priority date	Dec 1, 2020
Publication date	Apr 29, 2025
Grant date	Apr 29, 2025

Abstract

A masterbatch composition suitable for use as a flame retardant in extruded polymer foams, and process for manufacturing the same, and extruded foams containing same; the composition comprising: (a) 20 to 40 parts by weight base resin comprising styrene homopolymer or copolymer; (b) 1 to 16 parts by weight acid scavenger comprising an epoxy-based compound; (c) 2 to 6 parts by weight antioxidant comprising an alkyl or aryl phosphite; and (d) 45 to 60 parts by weight flame retardant comprising a non-hexabromocyclododecane (HBCD) brominated polymer or copolymer, wherein the amounts of (a), (b), (c), and (d) total 100 parts by weight; and (e) 0.6 to 10 parts by weight of pH moderator, based on 100 parts of (a) base resin plus (e) water soluble pH moderator.

First claim

What is claimed is:

1. A process for manufacturing a masterbatch composition suitable for use as a flame retardant in extruded polymer foams, comprising the steps of:
a) providing a base resin to a mixing device operating at temperature of 150 to 230° C. to form a molten base resin;
b) contacting the molten base resin in the mixing device with:
i) acid scavenger comprising an epoxy-based compound;
ii) antioxidant comprising an alkyl or aryl phosphite;
iii) water soluble pH moderator; and
iv) flame retardant comprising a non-hexabromocyclododecane (HBCD) polymer or copolymer

 to form a molten flame retardant masterbatch composition; and
c) cooling the molten flame retardant masterbatch composition to form a solid flame retardant masterbatch composition,
wherein the masterbatch composition has
(A) 20 to 40 parts by weight of the base resin comprising styrene homopolymer or copolymer;
(B) 1 to 16 parts by weight of the acid scavenger comprising an epoxy-based compound;
(C) 2 to 6 parts by weight of the antioxidant comprising an alkyl or aryl phosphite; and
(D) 45 to 60 parts by weight of the flame retardant comprising a non-hexabromocyclododecane (HBCD) brominated polymer or copolymer;
wherein the amounts of (A), (B), (C), and (D) total 100 parts by weight; and
(E) 0.6 to 10 parts by weight of the water soluble pH moderator, based on 100 parts of (A) base resin plus (E) water soluble pH moderator.

2. The process for manufacturing a masterbatch composition of claim 1 further comprising the step of:
d) pelletizing the solid flame retardant masterbatch composition to form pellets.

3. The process for manufacturing a masterbatch composition of claim 1 wherein in step b) the acid scavenger contacting the molten base resin is epoxidized oil, epoxy cresol novolac resin, or a brominated epoxy compound.

4. The process for manufacturing a masterbatch composition of claim 3 wherein in step b) the molten base resin is contacted sequentially with both epoxidized oil and epoxy cresol novolac resin by separate additions.

5. The process for manufacturing a masterbatch composition of claim 1 wherein at least one of the acid scavenger, the antioxidant, or the water soluble pH moderator contacts the molten base resin in the mixing device prior to the flame retardant contacting the base resin.

6. The process for manufacturing a masterbatch composition of claim 5 wherein the acid scavenger contacts the molten base resin in the mixing device prior to the flame retardant contacting the base resin.

Assignees

• Ddp Specialty Electronic Materials Us Llc

Inventors

• Huang Wenyi
• Kram Shari
• Rickard Mark
• Shankar Ravi B

Classifications

• C08L2203/14

  used for foams · CPC title

• C08L2201/02

  Flame or fire retardant/resistant · CPC title

• C08L25/06

  Polystyrene · CPC title

• C08J2425/06

  Polystyrene · CPC title

• C08J2363/04

  Epoxynovolacs · CPC title