Catalyst material and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-12285748-B2
Application number	US-202318389921-A
Country	US
Kind code	B2
Filing date	Dec 20, 2023
Priority date	Jul 20, 2018
Publication date	Apr 29, 2025
Grant date	Apr 29, 2025

Abstract

A method of manufacturing a catalyst material includes the steps of: providing a body having an open-porous foam structure and comprising at least a first metal or alloy; providing particles, each of which particles comprising at least a second metal or alloy; distributing the particles on the body; forming a structural connection between each of at least a subset of the particles and the body; and forming an oxide film on at least the subset of the particles and the body, wherein the oxide film has a catalytically active surface.

First claim

What is claimed is:

1. A catalyst material comprising:
a body having an open-porous foam structure and comprising at least a first metal or alloy;
particles comprising at least a second metal or alloy, wherein each of at least a subset of the particles and the body are structurally connected by means of sintering bridges and the sintering bridges comprise alloys of the metals present in the particles as well as the body, intermetallic phases of those metals or mixed crystals thereof; and
an oxide film formed on at least the subset of the particles, wherein the oxide film has a catalytically active surface.

2. The catalyst material according to claim 1 , wherein the oxide film is formed on at least the subset of the particles and the body.

3. The catalyst material according to claim 2 , wherein the oxide film formed on the particles and the body is different.

4. The catalyst material according to claim 1 , wherein the oxide film and the metals form an oxidic structure with a continuous interface of gradual composition, and the oxidic structure comprises islands, areas and/or closed layers of stoichiometrically distinct chemical compositions.

5. The catalyst material according to claim 1 , wherein the oxide film comprises at least one metal oxide capable of changing its oxidation state, at least one metal oxide having weakly bonded lattice oxygen atoms, at least one metal oxide having strongly bonded lattice oxygen atoms, and/or spinel structures MAl 2 O 4 .

6. The catalyst material according to one of the claim 1 , wherein the material has a surface roughness of R Z >50 μm.

7. The catalyst material according to claim 1 , wherein the first metal or alloy comprises Ni and the second metal or alloy comprises NiCrAl, or the first metal or alloy comprises Cu and the second metal or alloy comprises CuMn, or the first metal or alloy comprises Ni and the second metal or alloy comprises Al, or the first metal or alloy comprises Fe and the second metal or alloy comprises FeCrAl, or the first metal or alloy comprises Ni and the second metal or alloy comprises Inconel 600, or the first metal or alloy comprises Ni and the second metal or alloy comprises Inconel 625, or the first metal or alloy comprises Ni and the second metal or alloy comprises NiFeCrAl.

8. The catalyst material according to claim 1 , wherein the catalyst material further comprises a coating.

9. The catalyst material according to claim 8 , wherein the coating is as porous coating traversable by reactant molecules by pore diffusion, and the porous coating mechanically protects the oxide film.

10. The catalyst material according to claim 9 , wherein the coating comprises zeolites.

11. The catalyst material according to claim 8 , wherein the coating is applied as a washcoat.

12. The catalyst material according to claim 8 , wherein the coating is catalytically active and the oxide film acts as a reservoir supplying catalytically active metals/ions to the coating.

Assignees

• Alantum Europe Gmbh
• Fraunhofer Ges Forschung

Inventors

• Torkuhl Lars
• Kolvenbach Robin
• Bae Jungsuk
• Tillmann Andreas
• Gerstle Alexandra
• Walther Gunnar
• Büttner Tilo
• Böhm Hans-Dietrich
• Kieback Bernd
• Weissgärber Thomas
• Boden Arne

Classifications

• B01J21/005 Primary

  Spinels · CPC title

• B01J37/344

  of electromagnetic wave energy · CPC title

• B01J37/0221

  of particles · CPC title

• B01J37/0217

  Pretreatment of the substrate before coating · CPC title

• B01J23/26

  Chromium · CPC title