Cross-corrugated packing made from metal foam

Patent metadata

Field	Value
Publication number	US-12285733-B2
Application number	US-202017603567-A
Country	US
Kind code	B2
Filing date	Apr 16, 2020
Priority date	Apr 16, 2019
Publication date	Apr 29, 2025
Grant date	Apr 29, 2025

Abstract

Disclosed is a packing made up of a stack of plates, having been shaped to form corrugations in the plate and assembled to form a cross-corrugated packing block for a mass and/or heat transfer application, wherein the material of the packing plates is an open-pore metal foam, and in that the specific surface area of the packing is greater than 500 m2/m3 and in that the thickness (e) of the plate is less than 2 mm before the shaping operation.

First claim

The invention claimed is:

1. A process for separating air gases by cryogenic distillation in an air separation unit, wherein the air separation unit comprises a system of columns comprising a first column and a second column, the process comprising the steps of:
operating the first column at a first pressure, wherein the first column is thermally connected to the second column that is operating at a second pressure lower than the first pressure,
wherein at least one column within the system of columns operating at a pressure lower than the first pressure contains a packing;
sending a flow of air that is to be separated to the first column;
sending an oxygen-enriched fluid and a nitrogen-enriched fluid from the first column to the second column; and
withdrawing a second nitrogen-enriched fluid from the second column;
withdrawing a second oxygen-enriched fluid from the second column,
wherein the packing is made from a stack of leaves having been shaped to form corrugations in the leaf and assembled to form a packing body for a mass and/or heat transfer application, the material of the packing leaves being a metal foam, the material of the packing leaves is an open-pore metal foam, in that the specific surface area of the packing is greater than 500 m 2 /m 3 , and in that the thickness of the leaf is less than 2 mm before the shaping operation
wherein a length travelled by a liquid produced by air separation progressing by capillary action through the metal foam during a residence time for which the liquid resides in the packing body being greater than ten times a pitch (b) of the corrugation of the leaf.

2. The process as claimed in claim 1 , wherein the system of columns further comprises a third column connected to the second column by a pipe conveying argon-enriched gas, wherein the third column has an operating pressure lower than the first pressure, wherein the process further comprises the step of sending an argon-enriched fluid from the second column to the third column.

3. The process as claimed in claim 1 , wherein the metal foam packing is used in a gas-liquid material exchange column section, where a liquid reflux is less than 20 m 3 /h/m 2 .

4. The process as claimed in claim 1 , wherein the metal foam packing is used in a gas-liquid material exchange column section, wherein a liquid reflux is less than 10 m 3 /h/m 2 .

5. The process as claimed in claim 1 , wherein the length travelled by the liquid produced by air separation progressing by capillary action through the metal foam during the residence time for which the liquid resides in the packing body is greater than 15 times the pitch (b) of the corrugation of the leaf.

6. The process as claimed in claim 1 , wherein the length travelled by the liquid produced by air separation progressing by capillary action through the metal foam during the residence time for which the liquid resides in the packing body is greater than 20 times the pitch (b) of the corrugation of the leaf.

7. The process as claimed in claim 1 , wherein the specific surface area of the packing is greater than 700 m 2 /m 3 .

8. The process as claimed in claim 1 , wherein the thickness of the leaf before it enters the press is less than 0.6 mm before the bending operation.

9. The process as claimed in claim 1 , wherein that the metal foam material consists predominantly of nickel or copper.

10. The process as claimed in claim 1 , wherein the length travelled by the liquid is calculated by the following formula:

l

c
⁢
a
⁢
p

=

σ
L

⁢

r

p
⁢
o
⁢
r
⁢
e

⁢

t

r
⁢
e
⁢
s
⁢
L

μ
L

wherein σ L is a surface tension of the liquid, r pore is a mean pore radius, t resL is the residence time of the liquid, and μ L is viscosity of the liquid.

Assignees

• Lair Liquide Sa Letude Et Lexploitation Des Procedes Georges Claude
• Air Liquide

Inventors

• Frimat David
• Gary Daniel
• Lix Clement
• Rouseau Frederic
• Saulnier Bernard
• Wattiau Mikael

Classifications

• F25J2200/90

  Details relating to column internals, e.g. structured packing, gas or liquid distribution · CPC title

• F25J2200/08

  in a triple pressure main column system · CPC title

• F25J3/04636

  using a hybrid air separation unit, e.g. combined process by cryogenic separation and non-cryogenic separation techniques (F25J3/04733 and F25J3/04757 take precedence) · CPC title

• B01J2219/32408

  Metal · CPC title

• B01J2219/32262

  Dimensions or size aspects · CPC title