Integrated filter material and preparation method and application thereof

Patent metadata

Field	Value
Publication number	US-12280359-B2
Application number	US-202017773427-A
Country	US
Kind code	B2
Filing date	May 10, 2020
Priority date	Nov 12, 2019
Publication date	Apr 22, 2025
Grant date	Apr 22, 2025

Abstract

An integrated filter material, a preparation method and an application. The filter material is composed of a commercial dust removal filter material and a catalyst that is grown on the filter material and that has a function of simultaneously decomposing nitrogen oxides and dioxins. In the preparation method, a precursor solution of manganese and cerium oxides is impregnated on the filter material, and manganese and cerium oxides are grown on the filter material by means of a chemical reaction; and vanadium oxychloride is used as a precursor of vanadium oxide and is impregnated on the filter material, reacts in water, and prepared by drying, hydrothermal and other processes. The composite filter material may remove three kinds of pollutants in flue gas at the same time, and the catalyst is firmly loaded and does not easily fall off.

First claim

What is claimed is:

1. A preparation method of an integrated filter material, comprising the following steps:
a. cutting a filter material a into a disc, immersing the disc in an aqueous solution of a surface dispersant, stirring for 1 h to 2 h, and then drying at 100° C. to 120° C. for 4 h to 6 h to obtain a surface dispersant-modified filter material b;
b. adding distilled water dropwise to the filter material b slowly until the filter material has been fully infiltrated, to determine a saturated water absorption amount of the filter material;
c. calculating a concentration of an aqueous solution of a catalyst precursor according to a required load and the saturated water absorption amount of the filter material, wherein the calculation method is as follows:
(1) calculating a number of moles of each metal component in the catalyst required for an area filter material when the load requirement is met, and calculating the mass of a required metal precursor according to the number of moles of each component; and
(2) concentration of aqueous solution of each component in catalyst precursor=mass of each component of metal precursor/saturated water absorption amount of filter material;
immersing the filter material b obtained in step a in the aqueous solution of the catalyst precursor and taking out the filter material b after thorough stirring for 4 h to 6 h according to the foregoing calculation; further immersing the taken-out filter material in an aqueous solution of oxalic acid and standing for 10 h to 12 h; and then drying to obtain a filter material c;
d. adding acetone dropwise to the filter material c until the filter material has been fully infiltrated, to determine a saturated acetone absorption amount of the filter material;
e. determining a concentration of an acetone solution of vanadium oxytrichloride according to the saturated acetone absorption amount of the filter material c and the required load, wherein the calculation method is as follows: concentration of acetone solution of vanadium oxytrichloride=the number of moles of required V 2 O 5 * relative molecular mass of vanadium oxytrichloride/saturated acetone absorption amount of filter material;
immersing the filter material c obtained in step c in the acetone solution of vanadium oxytrichloride and taking out after standing for 4 to 6 h; and soaking the filter material c in an aqueous solution of sodium hydroxide with a pH value of 7.5 to 8.5, standing for 4 h to 6 h, and drying at 105° C. to 115° C. for 10 h to 12 h to obtain a filter material d; and
f. placing the filter material d in a reactor, pouring absolute ethanol, reacting in a vacuum drying oven at 180° C. to 220° C. for 10 h to 14 h, taking out the filter material after the reactor is cooled, drying at 60° C. to 80° C. for 4 h to 6 h, and then finishing preparation.

2. The preparation method of an integrated filter material according to claim 1 , wherein the filter material in step a is made of a high temperature resistant filter material of a bag dust collector which has a continuous working temperature≥200° C.

3. The preparation method of an integrated filter material according to claim 1 , wherein the surface dispersant in step a is an aqueous solution of alkyl polyglucoside with a mass concentration of 0.1% to 10%.

4. The preparation method of an integrated filter material according to claim 1 , wherein the load in step c is 50 g/m 2 to 150 g/m 2 , the metal precursor is manganese nitrate and cerium nitrate, and a molar ratio of manganese and cerium is (3-8):1.

5. The preparation method of an integrated filter material according to claim 1 , wherein drying conditions of the filter material c obtained in step c are as follows:
drying at 70° C. to 110° C. for 4 h to 6 h, then drying at 180° C. to 200° C. for 10 h to 14 h, and turning the filter material over every 2 h to 4 h.

6. The preparation method of an integrated filter material according to claim 1 , wherein the concentration of the oxalic acid solution in step c is 1.2 times to 1.5 times a concentration of the metal salt solution.

7. The preparation method of an integrated filter material according to claim 1 , wherein the use amount of V 2 O 5 in step e is 3% to 8% of the total mass of MnO 2 and CeO 2 .

8. An integrated filter material, wherein the filter material is prepared by the following methods:
a. cutting a filter material a into a disc, immersing the disc in an aqueous solution of a surface dispersant, stirring for 1 h to 2 h, and then drying at 100° C. to 120° C. for 4 h to 6 h to obtain a surface dispersant-modified filter material b;
b. adding distilled water dropwise to the filter material b slowly until the filter material has been fully infiltrated, to determine a saturated water absorption amount of the filter material;
c. calculating a concentration of an aqueous solution of a catalyst precursor according to a required load and the saturated water absorption amount of the filter material, wherein the calculation method is as follows:
(1) calculating a number of moles of each metal component in the catalyst required for an area filter material when the load requirement is met, and calculating the mass of a required metal precursor according to the number of moles of each component; and
(2) concentration of aqueous solution of each component in catalyst precursor=mass of each component of metal precursor/saturated water absorption amount of filter material;
immersing the filter material b obtained in step a in the aqueous solution of the catalyst precursor and taking out the filter material b after thorough stirring for 4 h to 6 h according to the foregoing calculation; further immersing the taken-out filter material in an aqueous solution of oxalic acid and standing for 10 h to 12 h; and then drying to obtain a filter material c;
d. adding acetone dropwise to the filter material c until the filter material has been fully infiltrated, to determine a saturated acetone absorption amount of the filter material;
e. determining a concentration of an acetone solution of vanadium oxytrichloride according to the saturated acetone absorption amount of the filter material c and the required load, wherein the calculation method is as follows: concentration of acetone solution of vanadium oxytrichloride=the number of moles of required V 2 O 5 * relative molecular mass of vanadium oxytrichloride/saturated acetone absorption amount of filter material;
immersing the filter material c obtained in step c in the acetone solution of vanadium oxytrichloride and taking out after standing for 4 to 6 h; and soaking the filter material c in an aqueous solution of sodium hydroxide with a pH value of 7.5 to 8.5, standing for 4 h to 6 h, and drying at 105° C. to 115° C. for 10 h to 12 h to obtain a filter material d; and
f. placing the filter material d in a reactor, pouring absolute ethanol, reacting in a vacuum drying oven at 180° C. to 220° C. for 10 h to 14 h, taking out the filter material after the reactor is cooled, drying at 60° C. to 80° C. for 4 h to 6 h, and then finishing preparation, wherein the load in step c is 50 g/m 2 to 150 g/m 2 , the metal precursor is manganese nitrate and cerium nitrate, and a molar ratio of manganese and cerium is (3-8):1.

Assignees

• Nanjing University Of Technology
• Nanjing Gekof Institute Of Environmental Protection Tech & Equipment Co Ltd
• 1 Nanjing Tech Univ

Inventors

• Xu Haitao
• Zhi Xiaohuan
• Mei Chaoqiang
• Li Mingbo
• Song Jing

Classifications

• B01J37/0236

  Drying, e.g. preparing a suspension, adding a soluble salt and drying · CPC title

• B01J37/0228

  in several steps · CPC title

• B01J37/0219

  the coating containing organic compounds · CPC title

• B01J31/36

  of vanadium, niobium or tantalum · CPC title

• B01J31/061

  Chiral polymers · CPC title