Pressure-sensitive adhesive tape

Patent metadata

Field	Value
Publication number	US-12275877-B2
Application number	US-202217869211-A
Country	US
Kind code	B2
Filing date	Jul 20, 2022
Priority date	Jan 21, 2020
Publication date	Apr 15, 2025
Grant date	Apr 15, 2025

Abstract

An adhesive tape with high high-load holding power, initial adhesive strength, and repeelability is provided. An adhesive layer of the adhesive tape contains filler particles and a triblock copolymer with a repeating unit represented by the following general formula (1):

A, B, and C independently denote a repeating unit. A and C independently denote an alkyl methacrylate monomer unit and B denotes an alkyl acrylate monomer unit. p, q, and r independently denote the degree of polymerization of their monomer units respectively. A and C may be the same or may denote an alkyl methacrylate monomer unit with a different chemical structure, and * denotes a bonding arm to another atom. A relationship D50/T between an average particle size D50 of the filler particles and an average thickness T of the adhesive layer ranges from 0.05 to 1.0.

First claim

What is claimed is:

1. An adhesive tape with an adhesive layer, the adhesive layer comprising:
filler particles; and
a triblock copolymer with a repeating unit represented by the following general formula (1):

wherein:
A, B, and C independently denote a repeating unit,
A and C independently denote an alkyl methacrylate monomer unit,
B denotes an alkyl acrylate monomer unit,
p, q, and r independently denote a degree of polymerization of monomer units respectively,
A and C are the same or denote an alkyl methacrylate monomer unit with a different chemical structure,
* denotes a bonding arm to another atom,
a relationship D50/T between an average particle size D50 of the filler particles and an average thickness T of the adhesive layer ranges from 0.05 to 1.0,
the adhesive tape is stretchable and peelable, and
the filler particles have a particle size distribution D90/D10 in a range of from 2.5 to 20.

2. The adhesive tape according to claim 1 , further comprising a substrate layer in contact with one surface of the adhesive layer.

3. The adhesive tape according to claim 1 , wherein the adhesive tape has a peel adhesive strength of 5 N/20 mm or more.

4. The adhesive tape according to claim 1 , wherein the adhesive tape has a cleavage strength in a range of 10 to 200 N/cm 2 .

5. The adhesive tape according to claim 1 , wherein the adhesive layer further contains a tackifier resin.

6. The adhesive tape according to claim 5 , wherein the adhesive layer contains 10 to 150 parts by mass of the tackifier resin per 100 parts by mass of the triblock copolymer.

7. The adhesive tape according to claim 2 , wherein the substrate layer has a breaking stress in a range of 1 to 100 MPa, an elongation at break in a range of 400% to 3000%, and a 50% modulus in a range of 0.1 to 5 MPa.

8. The adhesive tape according to claim 1 , wherein the filler particles are present in an amount ranging from 20 to 50 parts by mass per 100 parts by mass of the triblock copolymer with a repeating unit represented by the general formula (1).

9. The adhesive tape according to claim 1 , wherein the filler particles are encompassed within the adhesive layer until the adhesive tape is stretched and wherein when the adhesive tape is stretched, the filler particles are exposed from the adhesive layer.

10. The adhesive tape according to claim 1 , wherein the filler particles are selected from the group consisting of inorganic filler, organic filler, silicone filler, and combinations thereof.

11. The adhesive tape according to claim 1 , wherein the filler particles are selected from the group consisting of silicone rubber particles, acrylic-modified silicone particles, and combinations thereof.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Watanabe Daisuke
• SUETSUGU Kota
• Yamakami Akira
• KAGIYAMA Yumi

Classifications

• C09J153/00

  Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers · CPC title

• C09J133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C09J133/08

  Homopolymers or copolymers of acrylic acid esters · CPC title

• C09J11/08

  Macromolecular additives · CPC title

• C09J2301/302

  the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C · CPC title