Halide production method

US12269752B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-12269752-B2
Application numberUS-202117323920-A
CountryUS
Kind codeB2
Filing dateMay 18, 2021
Priority dateDec 28, 2018
Publication dateApr 8, 2025
Grant dateApr 8, 2025

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  1. Title

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  2. Abstract

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  4. Key dates

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  5. First independent claim

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Abstract

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A method for producing a halide includes heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH 4 ) a MX 3+a and LiZ. The M includes at least one element selected from the group consisting of Y, a lanthanoid, and Sc. The X is at least one element selected from the group consisting of Cl, Br, I, and F. The Z is at least one element selected from the group consisting of Cl, Br, I, and F. Furthermore, 0<a≤3 is satisfied.

First claim

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What is claimed is: 1. A method for producing a halide, the method comprising: heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH 4 ) a MX 3 +a and LiZ, wherein the M includes at least one element selected from the group consisting of Y, a lanthanoid, and Sc, wherein the X is at least one element selected from the group consisting of Cl, Br, I, and F, wherein the Z is at least one element selected from the group consisting of Cl, Br, I, and F, wherein 0<a≤3 is satisfied, and wherein, in the heat-treating, the mixed material is heat-treated at a temperature of greater than or equal to 500° C. and less than or equal to 650° C. 2. The method for producing a halide according to claim 1 , wherein, in the heat-treating, the mixed material is heat-treated for a time period of greater than or equal to 1 hour and less than or equal to 72 hours. 3. The method for producing a halide according to claim 1 , wherein the M is at least one element selected from the group consisting of Y, Sm, and Gd. 4. The method for producing a halide according to claim 1 , wherein 0.5≤a≤3 is satisfied. 5. The method for producing a halide according to claim 4 , wherein a=3. 6. The method for producing a halide according to claim 1 , wherein the X is at least one element selected from the group consisting of Cl, Br, and I, and wherein the Z is at least one element selected from the group consisting of Cl, Br, and I. 7. The method for producing a halide according to claim 1 , the method further comprising: preparing the (NH 4 ) a MX 3 +a, wherein, in the preparing, the (NH 4 ) a MX 3+a is synthesized by a solid-phase reaction between M 2 O 3 and NH 4 X. 8. The method for producing a halide according to claim 7 , further comprising: after the (NH 4 ) a MX 3+a is synthesized, weighing the (NH 4 ) a MX 3+a and the LiZ according to a desired molar ratio; and pulverizing and mixing the (NH 4 ) a MX 3+a and the LiZ to form the mixed material. 9. The method for producing a halide according to claim 1 , further comprising: weighing the (NH 4 ) a MX 3+a and the LiZ according to a desired molar ratio; and pulverizing and mixing the (NH 4 ) a MX 3+a and the LiZ to form the mixed material. 10. The method for producing a halide according to claim 6 , wherein X is different from Z. 11. A method for producing a halide, the method comprising: heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH 4 ) a MX 3+a and LiZ, wherein the X is at least one element selected from the group consisting of Cl, Br, I, and F, wherein the Z is at least one element selected from the group consisting of Cl, Br, I, and F, wherein 0<a≤3 is satisfied, and wherein M is Y. 12. The method for producing a halide according to claim 11 , wherein a=3. 13. The method for producing a halide according to claim 11 , further comprising: weighing the (NH 4 ) a MX 3+a and the LiZ according to a desired molar ratio; and pulverizing and mixing the (NH 4 ) a MX 3+a and the LiZ to form the mixed material. 14. The method for producing a halide according to claim 11 , wherein X is different from Z. 15. A method for producing a halide, the method comprising: heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH 4 ) a MX 3+a and LiZ, wherein the M includes at least one element selected from the group consisting of Y, a lanthanoid, and Sc, wherein the X is at least one element selected from the group consisting of Cl, Br, I, and F, wherein the Z is at least one element selected from the group consisting of Cl, Br, I, and F, and wherein a=3. 16. The method for producing a halide according to claim 15 , further comprising: weighing the (NH 4 ) a MX 3+a and the LiZ according to a desired molar ratio; and pulverizing and mixing the (NH 4 ) a MX 3+a and the LiZ to form the mixed material. 17. The method for producing a halide according to claim 15 , wherein X is different from Z. 18. A method for producing a halide, the method comprising: heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH 4 ) a MX 3+a and LiZ, wherein the M includes at least one element selected from the group consisting of Y, a lanthanoid, and Sc, wherein the X is at least one element selected from the group consisting of Cl, Br, I, and F, wherein the Z is at least one element selected from the group consisting of Cl, Br, I, and F, wherein 0<a≤3 is satisfied, and wherein, in the heat-treating, the mixed material is heat-treated at a temperature of greater than or equal to 500° C. 19. The method for producing a halide according to claim 18 , further comprising: weighing the (NH 4 ) a MX 3+a and the LiZ according to a desired molar ratio; and pulverizing and mixing the (NH 4 ) a MX 3+a and the LiZ to form the mixed material. 20. The method for producing a halide according to claim 18 , wherein X is different from Z.

Assignees

Inventors

Classifications

  • Halides · CPC title

  • Solid materials · CPC title

  • Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

  • Electric properties · CPC title

  • halogen being the only anion, e.g. NaYF4 · CPC title

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What does patent US12269752B2 cover?
A method for producing a halide includes heat-treating a mixed material in an inert gas atmosphere, the mixed material being a mixture of (NH 4 ) a MX 3+a and LiZ. The M includes at least one element selected from the group consisting of Y, a lanthanoid, and Sc. The X is at least one element selected from the group consisting of Cl, Br, I, and F. The Z is at least one element selected from the…
Who is the assignee on this patent?
Panasonic Ip Man Co Ltd, Panasonic Intellectual Property Managemnt Co Ltd
What technology area does this patent fall under?
Primary CPC classification H01M10/0525. Mapped technology areas include Electricity.
When was this patent published?
Publication date Tue Apr 08 2025 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 2 related publications on this page (citations in our corpus or others sharing the same primary CPC).