Spherical composite powder

Patent metadata

Field	Value
Publication number	US-12269041-B2
Application number	US-202017024949-A
Country	US
Kind code	B2
Filing date	Sep 18, 2020
Priority date	Sep 19, 2019
Publication date	Apr 8, 2025
Grant date	Apr 8, 2025

Abstract

An example method of preparing spherical composite powders is provided. The method includes introducing one or more starting material powders into an agitation mill. The method includes introducing a process control agent into the agitation mill, the process control agent including at least two immiscible liquids. The method includes agitating and milling the one or more starting material powders and the process control agent with the agitation mill to produce substantially spherical composite powders.

First claim

The invention claimed is:

1. A method of preparing spherical composite powders, the method comprising:
introducing one or more starting material powders into an agitation mill that includes one or more milling balls;
introducing a process control agent into the agitation mill, the process control agent including at least two immiscible liquids; and
agitating and milling the one or more starting material powders with the one or more milling balls and the process control agent with the agitation mill to produce spherical composite powders within emulsion droplets formed by the at least two immiscible liquids.

2. The method of claim 1 , wherein the agitation mill is a ball mill, and the method comprises introducing one or more milling balls as a milling media into the ball mill.

3. The method of claim 2 , wherein the one or more starting material powders and the process control agent are introduced into a milling vial of the ball mill.

4. The method of claim 1 , wherein the at least two immiscible liquids are different from each other.

5. The method of claim 1 , wherein the at least two immiscible liquids are selected from water and oil, acetonitrile and hexane, acetonitrile and heptane, acetic acid and pentane, or acetic acid and hexane.

6. The method of claim 4 , wherein a first of the at least two immiscible liquids is polar, and a second of the at least two immiscible liquids is non-polar.

7. The method of claim 1 , wherein the agitation mill is at least one of a shaker mill, a planetary mill, or an attritor mill.

8. The method of claim 1 , comprising selecting the at least two immiscible liquids and the relative percentages of the at least two immiscible liquids prior to agitation and milling.

9. The method of claim 1 , comprising varying a liquid-to-solid mass ratio between the one or more starting materials and the at least two immiscible liquids.

10. The method of claim 1 , comprising introducing a surfactant into the agitation mill to tune a surface energy of the at least two immiscible liquids forming the emulsion droplets during agitation and interacting with the one or more starting material powders.

11. The method of claim 1 , wherein a volume of one of the at least two immiscible liquids that forms the emulsion droplets is equal to a volume of the one or more starting material powders in the agitation mill.

12. The method of claim 1 , wherein a volume of one of the at least two immiscible liquids that forms the emulsion droplets is greater than a volume of the one or more starting material powders in the agitation mill.

13. The method of claim 1 , wherein the one or more starting material powders are inorganic precursor powders.

14. The method of claim 1 , wherein the one or more starting material powders are organic precursor powders.

15. The method of claim 1 , wherein the one or more starting material powders are a combination of inorganic and organic precursor powders.

Assignees

• New Jersey Inst Technology

Inventors

• Dreizin Edward
• Schoenitz Mirko
• Mursalat Mehnaz

Classifications

• C06B33/00

  Compositions containing particulate metal, alloy, boron, silicon, selenium or tellurium with at least one oxygen supplying material which is either a metal oxide or a salt, organic or inorganic, capable of yielding a metal oxide · CPC title

• C06B21/0066

  by granulation, e.g. flaking · CPC title

• B02C17/18

  Details · CPC title

• B02C23/06

  Selection or use of additives to aid disintegrating · CPC title

• B02C23/36 Primary

  the crushing or disintegrating zone being submerged in liquid · CPC title