Assembly comprising a SOEC/SOFC-type solid oxide stack and a high-temperature sealed coupling system

Patent metadata

Field	Value
Publication number	US-12264397-B2
Application number	US-202017761170-A
Country	US
Kind code	B2
Filing date	Sep 14, 2020
Priority date	Sep 18, 2019
Publication date	Apr 1, 2025
Grant date	Apr 1, 2025

Abstract

An assembly includes a solid-oxide pack of the SOEC/SOFC type and a system for clamping the pack. The assembly furthermore includes a coupling system gastight at high temperature, including a clamping base with a first through internal pipe to enable a tube to pass, a support base located in the pipe and having a second through internal pipe, and a seal, having a C shape, positioned against a first end of the support base. One of the clamping plates includes a through pipe for gas to pass having a support surface for the seal and a threaded countersink for receiving a thread of the clamping base.

First claim

The invention claimed is:

1. An assembly, comprising:
a solid-oxide pack of SOEC/SOFC type operating at high temperature, comprising:
a plurality of electrochemical cells each formed by a cathode, an anode and an electrolyte interposed between the cathode and the anode, and a plurality of intermediate interconnectors each arranged between two adjacent electrochemical cells,
a system for clamping the solid-oxide pack of the SOEC/SOFC type, including a top clamping plate and a bottom clamping plate, between which the solid-oxide pack of the SOEC/SOFC type is clamped, each clamping plate including at least two clamping orifices, the clamping system furthermore including:
at least two clamping rods configured each to extend through a clamping orifice in the top clamping plate and through a corresponding clamping orifice in the bottom clamping plate to allow assembly of the top and bottom clamping plates with each other, and
clamping means at each clamping orifice of the top and bottom clamping plates configured to cooperate with said at least two clamping rods to allow the assembly of the top and bottom clamping plates with each other,

at least one coupling system gastight at high temperature of the solid-oxide pack of the SOEC/SOFC type, mounted in at least one of the top or bottom clamping plates, including:
a clamping base, comprising a thread on its external surface at an end mounted in said at least one of the top or bottom clamping plates, the clamping base comprising a first through internal pipe to provide an inlet and/or outlet tube for gas to pass,
a support base, located in the first internal pipe of the clamping base, a second end of which is configured to be attached to said inlet and/or outlet tube for gas, the support base comprising a second internal through pipe to allow passage of gas coming from said tube and/or from the solid-oxide pack of the SOEC/SOFC type, and
a seal, having a C shape, positioned against a first end, opposite to the second end, of the support base,

wherein said at least one of the top or bottom clamping plates includes at least one through passage pipe for gas, configured to be in fluid communication with the solid-oxide pack of the SOEC/SOFC type and said inlet and/or outlet tube for gas, said at least one passage pipe comprising:
a surface for supporting the seal so that the seal is positioned between the support surface and the first end of the support base, and
a threaded countersink for receiving the thread of the clamping base, and

wherein the seal is formed by a flexible metal joint in a C shape, comprising a core consisting of a metal helical spring and a first metal envelope in which the metal helical spring is embedded.

2. The assembly according to claim 1 , wherein
the clamping base includes a first support surface, located in the first internal pipe, and
the support base includes a second support surface, the first and second support surfaces being in contact with each other in accordance with the contact of a plane-on-plane type, formed in a direction of flow of the gas.

3. The assembly according to claim 1 , wherein the support base includes a housing, on its first end, for at least partially housing the seal.

4. The assembly according to claim 1 , wherein the clamping base and the support base are produced from a same material as said at least one of the top or bottom clamping plates.

5. The assembly according to claim 1 , wherein the flexible metal joint in the shape of a C comprises a second metal envelope in which the first envelope is embedded.

6. The assembly according to claim 1 , comprising a top end plate and a bottom end plate, between which the plurality of electrochemical cells and the plurality of intermediate interconnectors are gripped.

7. The assembly according to claim 1 , wherein said at least one of the top or bottom clamping plates is manufactured by an additive manufacturing technique.

8. The assembly according to claim 1 , wherein said at least one of the top or bottom clamping plates has a thickness of between 20 and 30 mm.

9. A system comprising:
an assembly according to claim 1 , and
a furnace, to which at least one inlet and/or outlet tube for gas is connected, and to which the solid-oxide pack of the SOEC/SOFC type operating at high temperature is coupled for feeding and discharging gases using said at least coupling system gastight at high temperature.

10. The system according to claim 9 , wherein the support base is welded on an end of said at least one inlet and/or outlet tube for gas, in line therewith.

11. The system according to claim 9 , wherein the support base is welded by one of TIG type welding or arc welding.

12. The assembly according to claim 1 , wherein said at least one of the top or bottom clamping plates is manufactured by an additive manufacturing technique from refractory austenitic steel.

13. The assembly according to claim 1 , wherein said at least one of the top or bottom clamping plates has a thickness of an order of 25 mm.

Assignees

• Commissariat Energie Atomique

Inventors

• Planque Michel
• Monnet Thibault

Classifications

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/12

  operating at high temperature, e.g. with stabilised ZrO2 electrolyte · CPC title

• H01M8/0656

  by electrochemical means (H01M8/065 takes precedence) · CPC title

• H01M8/0273

  with sealing or supporting means in the form of a frame · CPC title

• H01M4/9025

  Oxides specially used in fuel cell operating at high temperature, e.g. SOFC · CPC title