Method of heat treating a cold rolled steel strip

Patent metadata

Field	Value
Publication number	US-12264375-B2
Application number	US-202017596676-A
Country	US
Kind code	B2
Filing date	Jun 11, 2020
Priority date	Jun 17, 2019
Publication date	Apr 1, 2025
Grant date	Apr 1, 2025

Abstract

A method of a heat treating a cold rolled steel strip includes the steps of soaking a cold rolled steel strip above (Ac3−20) for a certain soaking duration thereby obtaining a cold rolled steel strip having an austenitic microstructure; cooling the soaked steel strip to below Ms; heating and heat treating the cooled strip in the temperature range of Bs-Ms; and cooling the heat treated strip to ambient temperature.

First claim

The invention claimed is:

1. A method of heat treating a cold rolled steel strip, which method comprises the steps of:
a) soaking an uncoated cold rolled steel strip within a temperature range of (Ac3−20) to (Ac3+20) for a soaking time t 2 of 1-200 seconds, thereby obtaining a cold rolled steel strip having an austenitic microstructure;
b) cooling of the uncoated soaked steel strip resulting from step a) to a temperature T 4 in the range of Ms-(Ms−200);
c) heating the uncoated cooled steel strip resulting from step b) to a temperature range of Bs-Ms;
d) heat treating the uncoated heated steel strip in the temperature range of Bs-Ms for a period of time t 5 of 30-120 seconds;
d1) optionally a coating step of coating the heat treated steel strip with a protective coating following the heat treating:
e) cooling the heat treated, optionally coated, steel strip to ambient temperature;
such that the heat treated, optionally coated, steel strip has a microstructure (in vol. %) comprising:
polygonal ferrite (PF): 0-10;
polygonal ferrite (PF)+acicular ferrite (AF)+higher bainitic ferrite (HBF): 5-30;
lower bainitic ferrite (LBF)+partitioned martensite (PM): 50-85,
retained austenite (RA): 5-20;
martensite (M): 0-15;
wherein the steel strip has a composition (in mass percent) comprising
C: 0.15-0.28;
Mn: 1.70-3.00;
Si: 0.50-2.00;
Al: 0.01-0.60;
P: less than 0.050;
S: less than 0.020;
N: less than 0.0080;
wherein the sum (Si+Al) is ≥0.60; and
wherein 10C+Mn+Cr≥3.85 and 8.5≤(Mn+Cr)/C≤16;
optionally one or more elements selected from
0<Cr≤1.00;
0<Cu≤0.20;
0<Ni≤0.50;
0<Mo≤0.50;
0<Nb≤0.10;
0<V≤0.10;
0<Ti≤0.10;
0<B≤0.0030;
0<Ca≤0.0050;
0<REM≤0.0100, wherein REM is one or more rare earth metals;
and the remainder being iron and inevitable impurities,
wherein the steel strip resulting from step e) has Tensile strength (TS) of at least 980 Mpa and Total elongation (TE) of at least 13%;
wherein the steel strip resulting from step e) has at least one property selected from the group consisting of:
Yield strength (YS) of at least 550 Mpa,
Hole expansion capacity (HEC) of at least 20%, and
Bending angle (BA) of at least 80°.

2. The method according to claim 1 , wherein step c) involves heat treating the uncoated cooled strip from step b) at a temperature T 4 in the temperature range of Ms-(Ms−200).

3. The method according to claim 1 , wherein in step d) heat treating is performed in the range of Bn-(Ms+50).

4. The method according claim 1 , wherein step b) comprises cooling the soaked steel strip from step a) to the temperature T 4 at a cooling rate sufficient to avoid pearlite formation.

5. The method according to claim 1 , wherein step b) comprises a substep of cooling the soaked steel strip resulting from step a) to a temperature T 3 in the range of 800-550° C. at a cooling rate V 3 of at least 1° C./s.

6. The method according to claim 1 , wherein step b) comprises a substep of cooling the soaked steel strip from a temperature T 3 in the range of 800-550° C. to T 4 at a cooling rate V 4 of at least 15° C./s.

7. The method according to claim 1 , prior to step a) further comprising heating the cold rolled strip to a temperature above (Ac3−20) at a heating rate of at least 0.5° C./s.

8. The method according to claim 1 , wherein in step d) heat treating is performed in the range of Bn-(Ms+50) during a period of time t 5 of 40-100 seconds.

9. The method according to claim 1 , wherein between steps d) and e), or if step d1) is present between steps d) and d1), the steel strip resulting from step d) undergoes further heat treatment in the range of Bs-Bn, for a period of time t 6 of 5-30 seconds.

10. The method according to claim 9 , wherein the step d1) is performed and comprises a hot dip galvanizing treatment.

11. The method according to claim 1 , wherein the step d1) is performed.

12. The method according to claim 1 , wherein the microstructure comprises in vol. %:
polygonal ferrite (PF): 0-5;
polygonal ferrite (PF)+acicular ferrite (AF)+higher bainitic ferrite (HBF): 10-25;
lower bainitic ferrite (LBF)+partitioned martensite (PM): 55-80;
retained austenite (RA): 7-15;
martensite (M): 0-10;
and/or
wherein the C content in retained austenite (RA) is 0.90 wt. % or more.

13. The method according to claim 1 , wherein the resulting steel strip has:
Yield strength (YS) of at least 550 MPa;
Tensile strength (TS) of at least 980 MPa;
Total elongation (TE) of at least 13%,
Hole expansion capacity (HEC) of at least 20%; and
Bending angle (BA) of at least 80°.

14. The method according to claim 1 , wherein step c) involves heat treating the cooled strip from step b) at a temperature T 4 in the temperature range of (Ms−50)-(Ms−150), wherein the total duration t 4 of step c) is in the range of 1-10 seconds.

15. The method according to claim 1 , wherein step a) comprises soaking the cold rolled steel strip within a temperature range of (Ac3−15)-(Ac3+15), for a soaking time t 2 of 30-150 s.

16. The method according to claim 1 , wherein step b) comprises a substep of cooling the soaked steel strip resulting from step a) to a temperature T 3 in the range of 750-600° C., at a cooling rate V 3 of 2.0-15.0° C./s.

17. The method according to claim 1 , wherein step b) comprises a substep of cooling the soaked steel strip from a temperature T 3 in the range of 750-600° C., to T 4 at a cooling rate V 4 of 20.0-70.0° C./s.

18. The method according to claim 1 , prior to step a) further comprising heating the cold rolled strip to a temperature T 1 in the range of 800-550° C. at a heating rate V 1 of 10.0-30.0° C./s; and further heating the cold rolled strip from the temperature T 1 to a temperature above (Ac3−20) at a heating rate V 2 of 0.5-4.0° C./s.

19. A method of heat treating a cold rolled steel strip, which method comprises the steps of:
a) soaking an uncoated cold rolled steel strip within a temperature range of 833-879° C. for a soaking time t 2 of 1-200 seconds, thereby obtaining a cold rolled steel strip having an austenitic microstructure;
b) cooling of the uncoated soaked steel strip resulting from step a) to a temperature T 4 in the range of Ms-(Ms−200);
c) heating the uncoated cooled steel strip resulting from step b) to a temperature range of Bs-Ms;
d) heat treating the uncoated heated steel strip in the temperature range of Bs-Ms for a period of time t 5 of 30-120 seconds;
d1) optionally a coating step of coating the heat treated steel strip with a protective coating following the heat treating;
e) cooling the heat treated, optionally coated, steel strip to ambient temperature;
such that the heat treated, optionally coated, steel strip has a microstructure (in vol. %) comprising:
polygonal ferrite (PF): 0-10;
polygonal ferrite (PF)+acicular ferrite (AF)+higher bainitic ferrite (HBF): 5-30;
lower bainitic ferrite (LBF)+partitioned martensite (PM): 50-85,
retained austenite (RA): 5-20;
martensite (M): 0-15;
wherein the steel strip has a composition (in mass percent) comprising
C: 0.15-0.28;
Mn: 1.70-3.00;
Si: 0.50-2.00;
Al: 0.01-0.60;
P: less than 0.050;
S: less than 0.020;
N: less than 0.0080;
wherein the sum (Si+Al) is ≥0.60; and
wherein 10C+Mn+Cr≥3.85 and 8.5≤(Mn+Cr)/C≤16;
optionally one or more elements selected from
0<Cr≤1.00;
0<Cu≤0.20;
0<Ni≤0.50;
0<Mo≤0.50;
0<Nb≤0.10;
0<V≤0.10;
0<Ti≤0.10;
0<B≤0.0030;
0<Ca≤0.0050;
0<REM≤0.0100, wherein REM is one or more rare earth metals;
and the remainder being ir

Assignees

• Tata Steel Ijmuiden Bv

Inventors

• Chen Shangping
• Mostert Richard
• Aarnts Maxim Peter
• Van Bohemen Stefanus Matheus Cornelis

Classifications

• C23C2/40

  Plates; Strips · CPC title

• C23C2/06

  Zinc or cadmium or alloys based thereon · CPC title

• C22C38/06

  containing aluminium · CPC title

• C22C38/04

  containing manganese · CPC title

• C22C38/02

  containing silicon · CPC title