Resin composition, and film for lid materials

Patent metadata

Field	Value
Publication number	US-12264267-B2
Application number	US-202017441735-A
Country	US
Kind code	B2
Filing date	Mar 18, 2020
Priority date	Mar 25, 2019
Publication date	Apr 1, 2025
Grant date	Apr 1, 2025

Abstract

The purpose is to provide a resin composition and a film for lid material which excel in sealability and adhesiveness to plastic containers, especially containers made of polyethylene terephthalate, polylactic acid, polystyrene, or polypropylene, and are suitably usable as sealant layers of lid materials for containers. Provided is a resin composition including: an ethylene-vinyl acetate copolymer (A) by 60-95 parts by weight, the ethylene-vinyl acetate copolymer (A) having a vinyl acetate content (VA) of 3-13% by weight, and having a ratio Qw between a weight-average molecular weight (Mw) and a number-average molecular weight (Mn) of 1.5-4.5; and a tackifier resin (B) by 5-40 parts by weight, where a total amount of (A) and (B) is 100 parts by weight.

First claim

The invention claimed is:

1. A resin composition comprising:
an ethylene-vinyl acetate copolymer (A) in an amount of not less than 60 parts by weight and not more than 95 parts by weight, the ethylene-vinyl acetate copolymer (A) having a vinyl acetate content (VA) of not less than 3% by weight and not more than 13% by weight, and having a ratio Qw between a weight-average molecular weight (Mw) and a number-average molecular weight (Mn) of 1.5 or more and 4.5 or less; and
a tackifier resin (B) in an amount of not less than 5 parts by weight and not more than 40 parts by weight,
where a total amount of (A) and (B) is 100 parts by weight, and
the ethylene-vinyl acetate copolymer (A) satisfies a relational expression: Qw<−1.9×ln VA+9.0, where ln VA represents a natural logarithm of the vinyl acetate content VA.

2. The resin composition as set forth in claim 1 , wherein an ethylene-vinyl acetate copolymer component in the resin composition is a single component.

3. A resin composition, comprising:
a resin composition recited in claim 1 ; and
a thermoplastic block copolymer (C) in an amount of not less than 0.5 parts by weight and not more than 5 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the thermoplastic block copolymer (C) containing at least one of olefin and diolefin as a constitutional unit and containing aromatic vinyl hydrocarbon as a constitutional unit.

4. A resin composition, comprising:
a resin composition recited in claim 1 ; and
an ethylene-α-olefin copolymer (D) in an amount of not less than 5 parts by weight and not more than 100 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the ethylene-α-olefin copolymer (D) having a density that is measured based on JIS K6922-1 (1998) and falls within a range of 860 kg/m3 or more and 910 kg/m3 or less.

5. A resin composition, comprising:
a resin composition recited in claim 1 ; and
low density polyethylene (E) in an amount of not less than 1 part by weight and not more than 50 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the low density polyethylene (E) having a number-average molecular weight that falls within a range of 500 to 18000, and having a melting point that is measured based on JIS K6924-2 and falls within a range of 98° C. or more and 120° C. or less.

6. A resin composition, comprising:
a resin composition recited in claim 1 ; and
a saponified ethylene-vinyl acetate copolymer (F) in an amount of not less than 1 part by weight and not more than 100 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the saponified ethylene-vinyl acetate copolymer (F) having a melting point that is measured based on JIS K6924-2 and is 90° C. or more and 120° C. or less.

7. A resin composition, comprising:
a resin composition recited in claim 1 ;
a thermoplastic block copolymer (C) in an amount of not less than 0.5 parts by weight and not more than 5 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the thermoplastic block copolymer (C) containing at least one of olefin and diolefin as a constitutional unit and containing aromatic vinyl hydrocarbon as a constitutional unit; and
an ethylene-α-olefin copolymer (D) in an amount of not less than 5 parts by weight and not more than 100 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the ethylene-α-olefin copolymer (D) having a density that is measured based on JIS K6922-1 (1998) and falls within a range of 860 kg/m3 or more and 910 kg/m3 or less.

8. A resin composition, comprising:
a resin composition recited in claim 1 ;
a thermoplastic block copolymer (C) in an amount of not less than 0.5 parts by weight and not more than 5 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the thermoplastic block copolymer (C) containing at least one of olefin and diolefin as a constitutional unit and containing aromatic vinyl hydrocarbon as a constitutional unit; and
low density polyethylene (E) in an amount of not less than 1 part by weight and not more than 50 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the low density polyethylene (E) having a number-average molecular weight that falls within a range of 500 to 18000, and having a melting point that is measured based on JIS K6924-2 and falls within a range of 98° C. or more and 120° C. or less.

9. A resin composition, comprising:
a resin composition recited in claim 1 ;
a thermoplastic block copolymer (C) in an amount of not less than 0.5 parts by weight and not more than 5 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the thermoplastic block copolymer (C) containing at least one of olefin and diolefin as a constitutional unit and containing aromatic vinyl hydrocarbon as a constitutional unit; and
a saponified ethylene-vinyl acetate copolymer (F) in an amount of not less than 1 part by weight and not more than 100 parts by weight relative to 100 parts by weight of the resin composition recited in claim 1 , the saponified ethylene-vinyl acetate copolymer (F) having a melting point that is measured based on JIS K6924-2 and is 90° C. or more and 120° C. or less.

10. The resin composition as set forth in claim 1 , wherein the tackifier resin (B) is at least one resin selected from the group consisting of an aliphatic petroleum resin, an aromatic petroleum resin, an alicyclic hydrogenated petroleum resin, and a copolymer-based petroleum resin.

11. An adhesive agent for a sealant, said adhesive agent comprising a resin composition recited in claim 1 .

12. The adhesive agent as set forth in claim 11 , which is used for a container that is made of at least one material selected from the group consisting of polyethylene terephthalate, polystyrene, polypropylene, and polylactic acid.

13. A film for a lid material for a container, said film comprising at least two layers which include a layer containing a resin composition recited in claim 1 and a supportive base layer.

Assignees

• Tosoh Corp

Inventors

• Hemmi Takashi
• Morishita Isao
• Kouda Shingo

Classifications

• C09K2200/0622

  Polyvinylalcohols, polyvinylacetates · CPC title

• B32B2270/00

  Resin or rubber layer containing a blend of at least two different polymers · CPC title

• B32B2435/02

  for containers · CPC title

• B32B27/18

  characterised by the use of special additives · CPC title

• B32B27/302

  comprising aromatic vinyl (co)polymers, e.g. styrenic (co)polymers · CPC title