Cotton fabrics containing porous organic cages

Patent metadata

Field	Value
Publication number	US-12264162-B2
Application number	US-202118025282-A
Country	US
Kind code	B2
Filing date	Oct 22, 2021
Priority date	Oct 23, 2020
Publication date	Apr 1, 2025
Grant date	Apr 1, 2025

Abstract

Highly porous nucleophilic organic cages (Nu-POC) were in-situ synthesized on cotton fibers by a condensation reaction between cyanuric chloride and melamine, and the products were employed as a robust wearable and flexible detoxifying protective material (denoted as POCotton) for vaporous pesticides. The covalent growth of Nu-POC particles on surfaces of cotton fibers retained the physical characteristics of Nu-POC to the greatest extend, which include specific surface area and porosity, while the cotton fabrics still remained wearable. The resultant POCotton can repeatedly adsorb fumigant vapors instantly (i.e., equilibrium reached within one minute) and massively (i.e., adsorption capacity at 596.88 mg/g of methyl iodide).

First claim

What is claimed is:

1. A method for detoxifying and/or removing a fumigant vapor from an environment, the method comprising:
contacting the fumigant vapor with a triazine-based nucleophilic porous organic cage grafted on a cotton fiber (POCotton), comprising:
a six-membered triazine ring cage grafted to a cotton fiber according to formula I:

wherein each represents attachment to another triazine ring cage, a cotton fiber, NH 2 or H;
and wherein each represents between 0 and 30 triazine ring cages before termination, to allow the detoxification or removal of the fumigant vapor.

2. The method of claim 1 , wherein the fumigant vapor is a member selected from the group consisting of hydrogen cyanide, naphthalene, nicotine, methyl iodide, methyl bromide, dichloropropene, propylene oxide, dibromochloropropane, organophosphate insecticides, and chloropicrin.

3. The method of claim 1 , wherein the fumigant vapor is a member selected from the group consisting of methyl iodide (MeI) and methyl bromide (MeBr).

4. The method of claim 1 , wherein the fumigant vapor is sequestered by the six-membered triazine ring cage grafted to a cotton fiber.

5. The method of claim 4 , wherein the fumigant vapor is sequestered by the six-membered triazine ring cage grafted to a cotton fiber with a concomitant color change.

6. A method of incorporating novel functional agents into a POCotton-triazine-based nucleophilic porous organic cage grafted on a cotton fiber, comprising:
providing a six-membered triazine ring cage grafted to a cotton fiber according to formula I:

wherein each represents attachment to another triazine ring cage, a cotton fiber, NH 2 , or H;
wherein each represents between 0 and 30 triazine ring cages before termination; and
contacting the six-membered triazine ring cage grafted to a cotton fiber with a functional agent to thereby incorporate the functional agent.

7. The method of claim 6 , wherein the functional agent is a member selected from the group consisting of a photosensitizer, a color indicator, and a reactive agent.

8. The method of claim 7 , wherein the photosensitizer is a member selected from the group consisting of Rose Bengal, sodium 2-anthroquinone sulfate, anthroquinone-2-carboxylic acid, menadione sodium bisulfite, and riboflavin 5-sulfate.

9. The method of claim 7 , wherein the color indicator is a member selected from the group consisting of phenol red, phenolphthalein, bromophenol blue, alizarin yellow R, and p-(4-nitrobenzyl)pyridine.

Assignees

• Univ California

Inventors

• Sun Gang
• Tang Peixin

Classifications

• D06M2200/00

  Functionality of the treatment composition and/or properties imparted to the textile material · CPC title

• D06M2101/06

  cellulosic · CPC title

• D06M13/358

  Triazines · CPC title

• B01D2257/2068

  Iodine · CPC title

• B01D2257/2062

  Bromine compounds · CPC title