Process for producing lower olefins from oxygenates

Patent metadata

Field	Value
Publication number	US-12264118-B2
Application number	US-202117906230-A
Country	US
Kind code	B2
Filing date	Mar 11, 2021
Priority date	Mar 13, 2020
Publication date	Apr 1, 2025
Grant date	Apr 1, 2025

Abstract

A process for producing lower olefins from oxygenates includes the steps of contacting a feedstock comprising oxygenates with molecular sieve catalyst in fluidized bed reaction zone under effective conditions, to produce product including ethylene and/or propylene; the effective conditions include that in the fluidized bed reaction zone, the weights of catalysts having various carbon deposition amounts are controlled, calculated as the weight of the molecular sieve in the catalysts, to have the following proportions based on the total weight of the catalysts in the fluidized bed reaction zone: the proportion of the weight of the catalyst having a coke deposition amount of less than 3 wt % is 1-20 wt %; the catalyst having a coke deposition amount of from 3 wt % to less than 5 wt % represents 10 to 70 wt %; and the catalyst having a coke deposition amount from 5 wt % to 10 wt % represents 10 to 88 wt %.

First claim

The invention claimed is:

1. A process for producing lower olefins from oxygenates, comprising the steps of contacting a feedstock comprising oxygenates with molecular sieve catalyst in fluidized bed reaction zone under effective conditions, to produce product comprising ethylene and/or propylene;
wherein the effective conditions comprise that in the fluidized bed reaction zone, the weights of catalysts having various carbon deposition amounts are controlled, calculated as the weight of the molecular sieve in the catalysts, to have the following proportions based on the total weight of the catalysts in the fluidized bed reaction zone:
the proportion of the weight of the catalyst having a coke deposition amount of less than 3 wt % is 1-20 wt %, based on the total weight of the catalysts in the fluidized bed reaction zone;
the catalyst having a coke deposition amount of from 3 wt % to less than 5 wt % represents 10 to 70 wt %, based on the total weight of the catalysts; and
the catalyst having a coke deposition amount from 5 wt % to 10 wt % represents 10 to 88 wt %, based on the total weight of the catalysts.

2. The process according to claim 1 , wherein the ratio of the volume of the gas phase in the fluidized bed reaction zone to the volume of the total catalyst in the fluidized bed reaction zone is from 1 to 15.

3. The process according to claim 1 , wherein the feedstock is fed through a distribution device into the reaction zone of the fluidized bed reactor, wherein the coke deposition amounts on the catalyst particles within the height range from the distribution device up to a height at ½ bed height vary to have a maximum difference of less than 8 wt %.

4. The process according to claim 3 , wherein the coke deposition amounts on the catalyst particles within the height range from the distribution device up to a height at ½ bed height vary to have a maximum difference of greater than 0.1 wt %.

5. The process of claim 3 , wherein the spent catalyst is derived from deactivation of the catalyst in the reaction zone, the spent catalyst is introduced into a regenerator through a spent inclined line to be regenerated to form a regenerated catalyst, and the regenerated catalyst is returned to the reaction zone of the fast fluidized bed through a regeneration inclined line; wherein the ratio of the regenerated catalyst to the spent catalyst in the reaction zone is controlled to be 0.01-1; and the coke deposition amount on the regenerated catalyst is 0 to 5 wt %.

6. The process according to claim 1 , wherein the oxygenate feedstock comprises methanol.

7. The process according to claim 1 , wherein the molecular sieve is a silicoaluminophosphate molecular sieve.

8. The process according to claim 1 , wherein the fluidized bed reaction zone is in the form of a dense phase bed, turbulent bed, or fast fluidized bed.

9. The process according to claim 1 , wherein the effective conditions further comprise: a reaction temperature of 400-550° C., and a reaction pressure of 0-1 MPaG.

10. The process according to claim 1 , wherein the difference of the coke deposition amounts between the spent catalyst and the regenerated catalyst is not more than 7 wt %.

11. The process according to claim 1 , wherein the catalyst having a coke deposition amount of less than 3 wt % is uniformly distributed within the fluidized bed reaction zone.

12. The process according to claim 1 , wherein the gas phase and the catalyst within the fluidized bed reaction zone are rapidly separated by a separation device subsequent to the reaction or after leaving the fluidized bed reaction zone.

13. A fluidized bed reactor for carrying out the process according to claim 1 for producing lower olefins from oxygenates, comprising:
a reaction zone, for receiving a methanol feedstock and contacting it with a catalyst to produce an olefin product, wherein the process deactivates, at least in part, the catalyst to produce a spent catalyst;
a gas-solid rapid separation device, for separating the spent catalyst from the reaction zone;
a cyclone separator, for receiving the gas-phase product separated by the gas-solid rapid separation device and a part of the spent catalyst not separated by the gas-solid rapid separation device, so as to carry out a secondary separation;
a stripping zone, for receiving the spent catalyst from the dipleg of the cyclone; and
an external circulation inclined line for catalyst, for returning at least a part of stripped spent catalyst from the stripping zone to the bottom of the reaction zone.

14. The fluidized bed reactor according to claim 13 , further comprising a separation zone between the reaction zone and the gas-solid rapid separation device, for allowing at least a part of the spent catalyst to settle for a preliminary separation from the gas phase.

15. A process for producing lower olefins from oxygenates, comprising the steps of: contacting the oxygenate feedstock with a molecular sieve catalyst in a fluidized bed reaction zone under effective conditions, to produce an ethylene and/or propylene containing product;
wherein the feedstock is fed into the fluidized bed reactor reaction zone through a distributor, wherein the coke deposition amounts on the catalyst particles within the height range from the distributor up to a height at ½ bed height distancing from the distributor vary to have a maximum difference of less than 8 wt %.

16. The process according to claim 15 , wherein the coke deposition amounts on the catalyst particles within the height range from the distributor up to a height at ½ bed height distancing from the distributor vary to have a maximum difference of greater than 0.1 wt %.

17. The process according to claim 15 , wherein a spent catalyst is derived from deactivation of the catalyst in the reaction zone, the spent catalyst is introduced into a regenerator through a spent inclined line to be regenerated to form a regenerated catalyst, and the regenerated catalyst is returned to the reaction zone of the fast fluidized bed through a regeneration inclined line.

18. The process according to claim 17 , wherein a difference of the coke deposition amounts between the spent catalyst and the regenerated catalyst is not more than 7 wt %.

Assignees

• China Petroleum & Chem Corp
• Shanghai Res Inst Petrochemical Tech Sinopec

Inventors

• Qi Guozhen
• Cao Jing
• Li Xiaohong
• Wang Hongtao
• Jin Yongming
• Gao Pan

Classifications

• C07C2529/89

  Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium · CPC title

• B01J8/24

  according to "fluidised-bed" technique (B01J8/20 takes precedence) · CPC title

• B01J8/1827

  the fluidising gas being a reactant · CPC title

• B01D45/16

  generated by the winding course of the gas stream {, the centrifugal forces being generated solely or partly by mechanical means, e.g. fixed swirl vanes} · CPC title

• B01J2208/00991

  Disengagement zone in fluidised-bed reactors · CPC title