Method for producing photocatalytic mortar

Patent metadata

Field	Value
Publication number	US-12264102-B2
Application number	US-202217707211-A
Country	US
Kind code	B2
Filing date	Mar 29, 2022
Priority date	Jul 16, 2021
Publication date	Apr 1, 2025
Grant date	Apr 1, 2025

Abstract

A method for producing photocatalytic mortar includes providing a mortar-producing material including a fine aggregate and cement, a reactant mixture including a zinc source and urea, and a microorganism-containing mixture including water and a urease-producing microorganism, subjecting the microorganism-containing mixture and the reactant mixture to microbial induced precipitation in the mortar-producing material, subjecting zinc carbonate crystal-containing mortar produced to curing for the same to undergo hydration, and subjecting cured mortar to hydrothermal synthesis, so that zinc carbonate crystals therein are converted to nano zinc oxide crystals.

First claim

What is claimed is:

1. A method for producing photocatalytic mortar, comprising:
providing a mortar-producing material that includes a fine aggregate and cement, a reactant mixture that includes a zinc source and urea, and a microorganism-containing mixture that includes water and a urease-producing microorganism;
subjecting the microorganism-containing mixture and the reactant mixture to microbial induced precipitation in the mortar-producing material, so as to obtain zinc carbonate crystal-containing mortar;
subjecting the zinc carbonate crystal-containing mortar to a curing process, so that the zinc carbonate crystal-containing mortar undergoes hydration to form cured mortar; and
subjecting the cured mortar to hydrothermal synthesis, so that zinc carbonate crystals in the cured mortar are converted to nano zinc oxide crystals, so as to obtain the photocatalytic mortar containing the nano zinc oxide crystals.

2. The method as claimed in claim 1 , wherein based on a total weight of the zinc source and the mortar-producing material, an amount of the zinc source ranges from 0.1 wt % to 20 wt %.

3. The method as claimed in claim 1 , wherein based on a total weight of the zinc source and the mortar-producing material, an amount of the zinc source ranges from 0.5 wt % to 2.5 wt %.

4. The method as claimed in claim 1 , wherein in the curing process, the zinc carbonate crystal-containing mortar is subjected to dry curing through exposure to air at a temperature of 20±2° C. and a relative humidity of 70±2% for 7 to 28 days.

5. The method as claimed in claim 1 , wherein in the curing process, the zinc carbonate crystal-containing mortar is subjected to wet curing in tap water having a temperature of 23±2° C. for 7 to 28 days.

6. The method as claimed in claim 1 , wherein the hydrothermal synthesis is conducted at a temperature ranging from 60° C. to 150° C. and a pressure ranging from 1.2 kg/cm2 to 3.0 kg/cm2.

7. The method as claimed in claim 1 , wherein the urease-producing microorganism is Sporosarcina Pasteurii.

8. The method as claimed in claim 1 , wherein the cement is silicate cement.

9. The method as claimed in claim 1 , wherein the fine aggregate is quartz sand.

10. The method as claimed in claim 1 , wherein the zinc source is selected from the group consisting of zinc nitrate, a zinc nitrate hydrate, and a combination thereof.

11. The method as claimed in claim 1 , wherein the microorganism-containing mixture is selected from the group consisting of a liquid culture containing the urease-producing microorganism, a suspension containing the urease-producing microorganism, and a combination thereof.

Assignees

• Univ Nat Chung Cheng

Inventors

• Chen Chien-Yen
• Huang Yi-Hsun
• Lin Pin-Yun
• Ye Wei-Fan

Classifications

• B01J35/70

  characterised by their crystalline properties, e.g. semi-crystalline (catalysts comprising carbon B01J21/18; molecular sieves B01J29/00) · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/36

  Mechanical strength · CPC title