Display substrate and display device

Patent metadata

Field	Value
Publication number	US-12262575-B2
Application number	US-202017312030-A
Country	US
Kind code	B2
Filing date	Aug 7, 2020
Priority date	Aug 7, 2020
Publication date	Mar 25, 2025
Grant date	Mar 25, 2025

Abstract

Provided is a display substrate including a base substrate, an anode layer, a light-emitting layer, an electron diffusion layer, a hole block layer and a cathode layer which are sequentially stacked along a direction away from the base substrate, wherein a material of the electron diffusion layer comprises a first luminescent material, and a transport speed of holes generated by the anode layer in the electron diffusion layer is less than a transport speed of the holes in the light-emitting layer.

First claim

What is claimed is:

1. A display substrate, comprising:
a base substrate, and an anode layer, a light-emitting layer, an electron diffusion layer, a hole block layer, and a cathode layer which are sequentially stacked along a direction away from the base substrate,
wherein a material of the electron diffusion layer comprises a first luminescent material, and a transport speed of holes generated by the anode layer in the electron diffusion layer is less than a transport speed of the holes in the light-emitting layer; and
wherein the material of the electron diffusion layer further comprises a first host material and a first sensitizing material; and
a material of the light-emitting layer comprises a second host material, a second sensitizing material, and a second luminescent material, and
wherein a doping proportion of the first sensitizing material is less than that of the second sensitizing material.

2. The display substrate according to claim 1 , wherein a difference between the doping proportion of the second sensitizing material and the doping proportion of the first sensitizing material is greater than 5%.

3. The display substrate according to claim 1 , wherein a doping proportion of the first host material is greater than that of the second host material; and
a doping proportion of the first luminescent material is equal to that of the second luminescent material.

4. The display substrate according to claim 3 , wherein a difference between the doping proportion of the first host material and the doping proportion of the second host material is greater than 5%.

5. The display substrate according to claim 1 , wherein a doping proportion of the first host material is greater than 50%, the doping proportion of the first sensitizing material is greater than 5% and less than or equal to 50%, and a doping proportion of the first luminescent material is greater than 0.5% and less than or equal to 5%; and
a doping proportion of the second host material is greater than 50%, the doping proportion of the second sensitizing material is greater than 5% and less than or equal to 50%, and a doping proportion of the second luminescent material is greater than 0.5% and less than or equal to 5%.

6. The display substrate according to claim 1 , wherein a difference between lowest singlet energy of the first host material and lowest triplet energy of the first host material is greater than or equal to 0.2 eV;
a difference between lowest singlet energy of the first sensitizing material and lowest triplet energy of the first sensitizing material is less than or equal to 0.2 eV;
the lowest singlet energy of the first host material is greater than that of the first sensitizing material, and the lowest singlet energy of the first sensitizing material is greater than that of the first luminescent material, wherein a difference between the lowest singlet energy of the first host material and the lowest singlet energy of the first sensitizing material is greater than or equal to 0.1 eV; and
the lowest triplet energy of the first host material is greater than that of the first sensitizing material, and the lowest triplet energy of the first sensitizing material is greater than the lowest singlet energy of the first luminescent material, wherein a difference between the lowest triplet energy of the first host material and the lowest triplet energy of the first sensitizing material is greater than or equal to 0.1 eV.

7. The display substrate according to claim 1 , wherein an absolute value of a difference between highest occupied molecular orbital energy level of the first host material and highest occupied molecular orbital energy level of the first sensitizing material is less than or equal to 0.2 eV;
a difference between lowest unoccupied molecular orbital energy level of the first host material and lowest unoccupied molecular orbital energy level of the first sensitizing material is less than 0.3 eV; and
a difference between an absolute value of the highest occupied molecular orbital energy level of the first host material and an absolute value of the lowest unoccupied molecular orbital energy level of the first sensitizing material is greater than the lowest singlet energy of the first sensitizing material.

8. The display substrate according to claim 1 , wherein a type of the first host material is identical to that of the second host material;
a type of the first sensitizing material is identical to that of the second sensitizing material; and
a type of the first luminescent material is identical to that of the second luminescent material.

9. The display substrate according to claim 8 , wherein the first host material and the second host material are both carbazole materials;
the first sensitizing material and the second sensitizing material are thermally activated delayed fluorescent materials or multiple resonance type materials; and
the first luminescent material and the second luminescent material are both fluorescent materials.

10. The display substrate according to claim 9 , wherein the first host material and the second host material are both one structure selected from a structure represented by formula (I), a structure represented by formula (II), a structure represented by formula (III), a structure represented by formula (IV), a structure represented by formula (V), and a structure represented by formula (VI);

where N is nitrogen and Si is silicon.

11. The display substrate according to claim 9 , wherein the first sensitizing material and the second sensitizing material are both one structure selected from a structure represented by formula (VII), a structure represented by formula (VIII), a structure represented by formula (IX), and a structure represented by formula (X);

where N is nitrogen and CN is cyano.

12. The display substrate according to claim 9 , wherein the first luminescent material and the second luminescent material are both one structure selected from a structure represented by formula (XI), a structure represented by formula (XII), a structure represented by formula (XIII), and a structure represented by formula (XIV);

where N is nitrogen, and both CH 3 and H 3 C are methyl.

13. The display substrate according to claim 1 , wherein a thickness of the electron diffusion layer ranges from 1 nanometer to 10 nanometers.

14. The display substrate according to claim 1 , further comprising: an electron transport layer, wherein
the electron transport layer is located between the hole block layer and the cathode layer, and an electron mobility of the electron transport layer is greater than or equal to a mobility threshold.

15. The display substrate according to claim 14 , wherein the mobility threshold is 10 −6 cm 2 /V·sec.

16. The display substrate according to claim 15 , wherein a material of the electron transport layer comprises thiophene materials and lithium quinolate; or, the material of the electron transport layer comprises imidazole materials and lithium quinolate; or, the material of the electron transport layer comprises azine derivatives and lithium quinolate.

17. The display substrate according to claim 16 , wherein a doping pr

Assignees

• Boe Technology Group Co Ltd

Inventors

• Sun Haiyan
• Zhang Xiaojin
• Wang Dan
• Lee Changho

Classifications

• H10K85/6572

  comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole · CPC title

• H10K85/654

  comprising only nitrogen as heteroatom (H10K85/652 takes precedence) · CPC title

• H10K85/633

  comprising polycyclic condensed aromatic hydrocarbons as substituents on the nitrogen atom · CPC title

• H10K85/625

  containing at least one aromatic ring having 7 or more carbon atoms, e.g. azulene · CPC title

• H10K85/622

  containing four rings, e.g. pyrene · CPC title