Polyester and molded article

Patent metadata

Field	Value
Publication number	US-12258442-B2
Application number	US-202318125227-A
Country	US
Kind code	B2
Filing date	Mar 23, 2023
Priority date	Mar 23, 2022
Publication date	Mar 25, 2025
Grant date	Mar 25, 2025

Abstract

The present disclosure provides a polyester including residues of formulas (i), (ii), (iii), and (iv):

for example, terephthalic acid,

for example, ethylene glycol,

for example, cyclohexanedimethanol, and

for example, tricyclodecane dimethanol,
in which R 1 is an aromatic group, R 2 is a C 2 -C 6 straight-chain hydrocarbon group, * represents a linking bond. Based on 100 mol % of a sum of the residues of the formula (ii), the formula (iii) and the formula (iv), a content of the residue of the formula (iii) ranges from 50 mol % to 85 mol %, and the residue of the formula (iv) ranges from 12 mol % to 40 mol %. The polyester has excellent impact strength, elongation, hardness, and heat resistance, and can be used in applications such as shaped materials of food contacts, automotive molds, commercial housewares, compounders consumers, electronics, device housings, in-store fixtures, electronic packaging, outdoor signs, personal care, cosmetics packaging, sporting equipment tools, and toys and water/sport bottles.

First claim

What is claimed is:

1. A polyester, comprising residues of formula (i), formula (ii), formula (iii) and formula (iv):

wherein R 1 is an aromatic group, R 2 is a C 2 -C 6 straight-chain hydrocarbon group, * represents a linking bond, based on 100 mol % of a sum of the residues of the formula (ii), the formula (iii), and the formula (iv), a content of the residue of the formula (ii) ranges from 5 mol % to 15 mol %, a content of the residue of the formula (iii) ranges from 50 mol % to 85 mol %, and a content of the residue of the formula (iv) ranges from 12 mol % to 40 mol %, a number average molecular weight of the polyester ranges from 20,000 Daltons to 30,000 Daltons, and an inherent viscosity of the polyester is larger than 0.7 dl/g.

2. The polyester of claim 1 , wherein R 1 is

or a combination thereof.

3. The polyester of claim 1 , wherein R 2 is a C 2 -C 4 straight-chain hydrocarbon group.

4. The polyester of claim 3 , wherein R 2 is a C 2 straight-chain hydrocarbon group.

5. The polyester of claim 1 , wherein the number average molecular weight ranges from 25,000 Daltons to 30,000 Daltons.

6. The polyester of claim 1 , wherein based on 100 mol % of the sum of the residues of the formula (ii), the formula (iii) and the formula (iv), the content of the residue of the formula (iii) ranges from 51 mol % to 83 mol %.

7. The polyester of claim 1 , wherein based on 100 mol % of the sum of the residues of the formula (ii), the formula (iii) and the formula (iv), the content of the residue of the formula (iv) ranges from 15 mol % to 35 mol %.

8. A molded article comprising the polyester according to claim 1 .

Assignees

• Chang Chun Plastics Co Ltd

Inventors

• Huang Ching-Jui
• Wang Ping-Chieh
• Chou June-Yen

Classifications

• C08G63/80

  Solid-state polycondensation · CPC title

• C08L67/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds (C08L67/06 takes precedence) · CPC title

• C08G63/183

  Terephthalic acids · CPC title

• C08G63/181 Primary

  Acids containing aromatic rings · CPC title

• C08G63/199 Primary

  Acids or hydroxy compounds containing cycloaliphatic rings · CPC title