Poly(phenylene)-based anion exchange polymers and methods thereof
US-10053535-B2 · Aug 21, 2018 · US
US12258440B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12258440-B2 |
| Application number | US-202318493772-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 24, 2023 |
| Priority date | Nov 18, 2014 |
| Publication date | Mar 25, 2025 |
| Grant date | Mar 25, 2025 |
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Embodiments of the invention relate to a novel class of polymers with superior mechanical properties and chemical stability, as compared to known polymers. These polymers are particularly well suited for use in anion exchange membranes (AEMs), including those employed in fuel cells. Novel methods for the manufacture of these polymers are also described.
Opening claim text (preview).
What is claimed is: 1. A polymer according to formula I wherein Ar is an aromatic compound, r is from 100 to 1,000,000, and R 2 comprises a quaternary ammonium group, and wherein the aromatic compound is selected from a group consisting of: 2. The polymer of claim 1 , wherein R 2 comprises R is an alkyl group; and n is from 1 to 20. 3. The polymer of claim 1 , prepared from a bromoalkylated precursor polymer of formula II according to the reaction: wherein R 1 is and R 2 comprises wherein n is from 1 to 20, and R is an alkyl group. 4. The polymer of claim 3 , wherein the bromoalkylated precursor polymer of formula II is prepared according to the reaction: 5. The polymer of claim 1 , wherein the polymer is used in fuel cell, water electrolysis, metal-air battery technologies, or as an antimicrobial coating. 6. A polymer according to formula: wherein x+y=1, and n is from 100 to 1,000,000.
characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title
based on organic materials · CPC title
Coating compositions based on macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain (C09D107/00 - C09D157/00, C09D161/00 take precedence); Coating compositions based on derivatives of such polymers · CPC title
Paints containing biocides, e.g. fungicides, insecticides or pesticides (C09D5/16 takes precedence) · CPC title
Friedel-Crafts-type · CPC title
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